Method of reducing chatter
View Patent ↗A method for reducing chatter in an extrusion process, which includes the steps of preparing an extrusion composition by combining a polymer composition with a chatter-reducing formulation, and extruding the extrusion composition to provide a substantially continuous extrudate. The chatter-reducing formulation comprises an alkyltin mercaptide and dibutyltin dilaurate. The resultant extrudate exhibits reduced chatter, which is categorized according to the Reed Scale as less than or equal to 2.
1. A method for reducing chatter in an extrusion process, comprising:
preparing an extrusion composition comprising a polymer composition;
extruding the extrusion composition through an extruder and a calibrator to provide a substantially continuous extrudate;
detecting at least one of chatter marks, jerking, and vibration of the extrudate as the extrudate exits the calibrator; and
adding a chatter reducing formulation that comprises alkyltin mercaptide to the extrusion composition in response to detecting the at least one of chatter marks, jerking and vibration.
2. The method of claim 1 , wherein the chatter reducing formulation further comprises dibutyltin dilaurate.
3. The method of claim 2 , wherein the alkyltin mercaptide comprises a mixture of two or more alkyltin mercaptides.
4. The method of claim 2 , wherein the weight ratio of alkyltin mercaptide to dibutyltin dilaurate in the chatter-reducing formulation is from about 95:5 to about 75:25.
5. The method of claim 2 , wherein the alkyltin mercaptide and dibutyltin dilaurate are simultaneously added to the polymer composition.
6. The method of claim 2 , wherein the alkyltin mercaptide and dibutyltin dilaurate are added sequentially to the polymer composition.
7. The method of claim 2 , wherein an admixture of the alkyltin mercaptide and dibutyltin dilaurate is added to the polymer composition.
8. The method of claim 2 , wherein the alkyltin mercaptide comprises a blend of mono- and di-alkyl-substituted tin mercaptides which are represented by the following structures:
where R 1 and R 2 represent an alkyl group, and X 1 , X 2 , and X 3 , independently represent a mercaptan or a sulfide sulfur.
9. The method of claim 8 , wherein the alkyl group is selected from: methyl, butyl, octyl, and dodecyl group.
10. The method of claim 8 , wherein the mercaptan is selected from: a straight chain alkyl mercaptan, 2-ethylhexyl thioglycolate, 2-mercaptoethyl tallate, and any mixture or combination thereof.
11. The method of claim 8 , wherein the ratio of mono- to di-alkyl-substituted tin mercaptides is greater than 50:50.
12. The method of claim 8 , wherein the ratio of mono- to di-alkyl-substituted tin mercaptides is less than 50:50.
13. The method of claim 2 , wherein the chatter-reducing formulation is provided in an amount ranging from about 1.0 parts to about 1.6 parts by weight per hundred parts resin.
14. The method of claim 2 , wherein the polymer composition comprises a halogen-containing polymer or copolymer.
15. The method of claim 2 , wherein the polymer composition comprises a polyvinylchloride polymer or copolymer.
16. The method of claim 1 , further comprising causing the extrudate to achieve a Reed Scale Level of less than or equal to 2.
17. The method of claim 1 , further comprising causing the extrudate to achieve a Reed Scale Level of less than or equal to 1.
18. The method of claim 2 , further comprising causing the extrudate to achieve a Reed Scale Level of less than or equal to 2.
19. The method of claim 2 , further comprising causing the extrudate to achieve a Reed Scale Level of less than or equal to 1.