Green luminescent materials
View Patent ↗There is provided a green luminescent material having Formula I or Formula II R 1 and R 2 can be the same or different and can be hydrogen, alkoxy, tertiary alkyl, or cycloalkyl. R 3 and R 4 are the same or different and can be fluorine, aryl, or alkyl. There is also provided an organic electronic device containing the green luminescent material.
1. An organic electronic device comprising a first electrical contact, a second electrical contact and a photoactive layer therebetween, the photoactive layer comprising a green luminescent material having Formula II, or a mixture of compounds having Formula I and Formula II
wherein:
R 1 and R 2 are the same or different and are selected from the group consisting of hydrogen, alkoxy, tertiary alkyl, and cycloalkyl,
R 3 and R 4 are the same or different and are selected from the group consisting of fluorine, aryl, and alkyl,
wherein:
R 1 and R 2 are the same or different and are selected from the group consisting of alkoxy, tertiary alkyl, and cycloalkyl,
R 3 and R 4 are the same or different and are selected from the group consisting of fluorine, aryl, and alkyl.
2. The device of claim 1 , wherein, in Formula I, at least one of R 1 and R 2 is not hydrogen.
3. The device of claim 1 , wherein at least one of R 1 and R 2 is an alkoxy group selected from the group consisting of methoxy and ethoxy.
4. The device of claim 1 , wherein at least one of R 1 and R 2 is a tertiary alkyl group selected from the group consisting of t-butyl and neopentyl.
5. The device of claim 1 , wherein at least one of R 1 and R 2 is a cycloalkyl selected from the group consisting of cyclohexyl, 1-methylcyclohexyl, and 1-adamantyl.
6. The device of claim 1 , wherein the luminescent material of Formula I and II are selected from the group consisting of compounds G1 through G12, for the respective Formula:
Com-
pound
Formula
R 1
R 2
R 3
R 4
G1
I
H
H
i-propyl
t-butyl
G2
I
t-butyl
H
i-propyl
t-butyl
G3
I
t-butyl
t-butyl
i-propyl
t-butyl
G4
I
1-
1-
i-propyl
t-butyl
methylcyclohexyl
methyl-
cyclohexyl
G5
II
1-
1-
i-propyl
t-butyl
methylcyclohexyl
methyl-
cyclohexyl
G6
I
methoxy
methoxy
i-propyl
t-butyl
G7
I
1-adamantyl
1-adamantyl
i-propyl
t-butyl
G8
II
1-adamantyl
1-adamantyl
i-propyl
t-butyl
G9
I
t-butyl
t-butyl
F
F
G10
I
1-adamantyl
1-adamantyl
phenyl
phenyl
G11
I
1-adamantyl
1-adamantyl
t-butyl
3-biphenyl
G12
I
1-adamantyl
1-adamantyl
t-butyl
phenyl.
7. The device of claim 1 , wherein the photoactive layer further comprises a host material.
8. The device of claim 7 wherein the host material comprises at least one diarylanthracene.
9. The device of claim 8 wherein the diarylanthracene has the formula:
where:
A 1 and A 2 are the same or different at each occurrence and are selected from the group consisting of H, an aromatic group, and an alkenyl group, or A may represent one or more fused aromatic rings;
p and q are the same or different and are an integer from 1-3.
10. The device of claim 9 wherein at least one of A 1 and A 2 comprises a naphthyl group.
11. The device of claim 10 wherein the host is selected from the group consisting of
and combinations thereof.
12. The device of claim 1 , wherein R 1 and R 2 are the same.
13. The device of claim 1 , wherein the compounds having Formula I and Formula II are isomers.