Electrophotographic photoreceptor, process cartridge, and image forming apparatus
View Patent ↗To provide an electrophotographic photoreceptor including the outermost surface layer formed from a cured film of a composition containing a compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule and a chain transfer agent having a sulfur atom in a molecule, in which the reaction rate of the compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule is about 90% to about 100% and the charge mobility of the cured film at an electric field intensity of 1.0×10 5 v/cm is from about 5.0×10 −7 cm 2 /Vs to about 1.0×10 −4 cm 2 /Vs.
1. An electrophotographic photoreceptor, comprising an outermost surface layer formed from a cured film of a composition containing a component (A) and a component (B), wherein:
the component (A) is a compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule; and
the component (B) is a chain transfer agent having one or more thiol groups or a disulfide group;
a reaction ratio of the compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule being about 90% to about 100%; and
a charge mobility of the cured film at an electric field intensity of 1.0×10 5 v/cm being from about 5.0×10 −7 cm 2 /Vs to about 1.0×10 −4 cm 2 /Vs.
2. The electrophotographic photoreceptor according to claim 1 , wherein, in the cured film, the reaction ratio is from about 95% to about 100% and the charge mobility at an electric field intensity of 1.0×10 5 V/cm is from about 5.0×10 −6 cm 2 /Vs to about 1.0×10 −5 cm 2 /Vs.
3. The electrophotographic photoreceptor according to claim 1 , wherein, in the cured film, the reaction ratio is from about 98% to about 100% and the charge mobility at an electric field intensity of 1.0×10 5 V/cm is from about 2.0×10 −6 cm 2 /Vs to about 5.0×10 −6 cm 2 /Vs.
4. The electrophotographic photoreceptor according to claim 1 , wherein the compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule is a compound having two or more of the chain polymerizable functional groups in a molecule.
5. The electrophotographic photoreceptor according to claim 1 , wherein the compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule is a compound represented by the following Formula (A):
wherein, in Formula (A),
Ar 1 to Ar 4 each independently represents a substituted or unsubstituted aryl group,
Ar 5 represents a substituted or unsubstituted aryl group or a substituted or unsubstituted arylene group,
D represents a group containing at least one selected from the group consisting of an acryloyl group, a methacryloyl group, and a vinylphenyl group at a terminal,
c1 to c5 each independently represent 0, 1, or 2,
k represents 0 or 1, and
a total number of D is 1 or more.
6. The electrophotographic photoreceptor according to claim 5 , wherein:
D represents —(CH 2 ) d —(O—CH 2 —CH 2 ) e —O—CO—C(R′) ═CH 2
where
R′ represents a hydrogen atom or a methyl group,
d represents an integer of 1 to 5, and
e represents 0 or 1; and
the total number of D is 4 or more.
7. The electrophotographic photoreceptor according to claim 5 , wherein the terminal of D is a methacryloyl group.
8. The electrophotographic photoreceptor according to claim 1 , wherein the chain transfer agent is a compound having one or more thiol groups.
9. The electrophotographic photoreceptor according to claim 1 , wherein the chain transfer agent is a compound having two or more thiol groups.
10. The electrophotographic photoreceptor according to claim 1 , wherein the chain transfer agent is contained in a proportion of about 0.1 parts by weight to about 30 parts by weight based on 100 parts by weight of the compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule.
11. The electrophotographic photoreceptor according to claim 1 , wherein the chain transfer agent is contained in a proportion of about 1 part by weight to about 15 parts by weight based on 100 parts by weight of the compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule.
12. The electrophotographic photoreceptor according to claim 1 , wherein the chain transfer agent is contained in a proportion of about 2 parts by weight to about 10 parts by weight based on 100 parts by weight of the compound having a chain polymerizable functional group and a charge transportable skeleton in a molecule.
13. The electrophotographic photoreceptor according to claim 1 , wherein the cured film further contains a compound having no chain polymerizable reactive groups and having a charge transportable skeleton.
14. A process cartridge, comprising the electrophotographic photoreceptor according to claim 1 , the process cartridge being detachably attached to an image forming apparatus.
15. An image forming apparatus, comprising:
electrophotographic photoreceptor according to claim 1 ;
a charging unit that charges the electrophotographic photoreceptor;
an electrostatic latent image formation unit that forms an electrostatic latent image on the charged electrophotographic photoreceptor;
a development unit that accommodates a developer containing a toner and develops the electrostatic latent image formed on the electrophotographic photoreceptor as a toner image with the developer; and
a transfer unit that transfers the toner image onto a transfer apparatus.
16. The electrophotographic photoreceptor according to claim 1 , wherein the chain transfer agent is a compound selected from the group consisting of 1-propanethiol, 1-butanethiol, 1-decanethiol, 1-dodecanethiol, 1-heptanethiol, 1-octadecanethiol, 2-dodenacethiol, t-dodecyl mercaptan, thiobenzoic acid, thioglycolic acid, ammonium thioglycolate, monoethanolamine thioglycolate, β-mercapto propionic acid, methyl-3-mercapto propionate, 2-ethylhexyl-3-mercapto propionate, n-octyl-3-mercapto propionate, methoxy butyl-3-mercapto propionate, stearyl-3-mercapto propionate, 1,10-decanedithiol, 1,2-benzenedithiol, 1,2-ethanedithiol, 1,2-propanedithiol, 2-methy1-2-octyl-1, 3-propane dithiol, mercaptopropionic acid 2- ethylhexyl ester, mercaptopropionic acid trimethylolpropane ester, mercaptopropionic acid pentaerythritol ester, tris-[(3-mercapto propionyloxy-ethyl)]-isocyanurate, tetraethylene glycol bis(3-mercapto propionate), dipentaerythritol hexakis(3-mercapto propionate), tetraethylthiuram disulfide, tetraethylthiuram disulfide, and diethyldithiocarbamic acid ester.
17. The electrophotographic photoreceptor according to claim 1 , wherein the chain transfer agent comprises a disulfide group.
18. The electrophotographic photoreceptor according to claim 17 , wherein the chain transfer agent is a compound selected from the group consisting of tetraethylthiuram disulfide, tetraethylthiuram disulfide, and diethyldithiocarbamic acid ester.