Wood-plastic composite with improved thermal and weathering resistance and method of making the same
View Patent ↗Thermoplastic compositions containing a natural filler and, more specifically, thermoplastic compositions containing a natural filler and having improved thermal and weathering resistance. The wood-plastic composites utilize a cellulose filler, such as wood flour, and vegetal fibers, such as Curauá fiber, as a reinforcement filler. The issues with regard to thermal degradation of cellulose during processing are reduced through the use of specific additives designed to improve its performance during processing. Additionally, other additives are included to improve the UV resistance. Specific combinations of thermal stabilizer and UV additive are provided that enhance the thermal resistance and weathering resistance of the compositions as compared to prior art systems.
1. A wood-plastic polymer composition comprising:
a blend of
a) from 40 to 90 wt % of a thermoplastic resin;
b) from 10 to 60 wt % of a wood filler;
c) from 0.1 to 0.8 wt % of a thermal stabilizer comprising a blend of 1,3,5-Tris(4-tert-butyl-3-hydroxy-2,6-dimethyl benzyl)-1,3,5-triazine-(1H,3H,5H)-trione and Tris (2,4-di-t-butylphenyl)phosphite; and
d) from 0.01 to 1.0 wt % of an ultraviolet stabilizer comprising a blend of an ultraviolet absorber and a hindered amine light stabilizer,
wherein the wood-plastic polymer composition has an oxidation induction time of at least 90 minutes.
2. The composition of claim 1 , wherein the thermoplastic resin is selected from polypropylene homopolymer, polypropylene copolymer, ethylene propylene diene monomer (EPDM), maleated propylene diene monomer (m-EPDM), ethylene-polypropylene copolymer, maleated ethylene-polypropylene copolymer (m-EP copolymers), a thermoplastic elastomer, a thermoplastic rubber, ethylene/vinyl acetate copolymer (EVA), a poly(4-methyl-1-pentene) homopolymer, poly(4-methyl-1-pentene/1-decene) copolymer, very low density polyethylene (VLDPE), (m) low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), crosslinked polyethylene (XLPE), crosslinked polypropylene (XLPP), nylon-6, nylon-6,6, nylon-4, nylon-4,6, nylon-12, nylon-6,10, nylon-6,9, nylon-6,12, nylon-9T, copolymer of nylon-6,6 and nylon-6, polyamide copolymers, polyamide blends, or a combination including at least one of the foregoing resins.
3. The composition of claim 1 , wherein the wood filler comprises wood flour, vegetal fibers, or a combination including wood flour and vegetal fibers.
4. The composition of claim 1 , wherein the ultraviolet absorber is selected from benzophenones and benzotriazoles.
5. The composition of claim 1 , wherein the thermoplastic resin comprises from 1 to 30 wt % of a polyamide blended with a polyolefin or from 1 to 30 wt % of a polyolefin blended with a polyamide.
6. The composition of claim 5 , wherein the polyamide is selected from nylon-6, nylon-6,6, nylon-4, nylon-4,6, nylon-12, nylon-6,10, nylon-6,9, nylon-6,12, nylon-9T, copolymer of nylon-6,6 and nylon-6, polyamide copolymers, polyamide blends and combinations thereof.
7. The composition of claim 5 , wherein the polyolefin is selected from polypropylene homopolymer, polypropylene copolymer, ethylene propylene diene monomer (EPDM), maleated propylene diene monomer (m-EPDM), ethylene-polypropylene copolymer, maleated ethylene-polypropylene copolymer (m-EP copolymers), a thermoplastic elastomer, a thermoplastic rubber, ethylene/vinyl acetate copolymer (EVA), a poly(4-methyl-1-pentene) homopolymer, poly(4-methyl-1-pentene/ 1 -decene) copolymer, very low density polyethylene (VLDPE), (m) low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), crosslinked polyethylene (XLPE), crosslinked polypropylene (XLPP) and combinations thereof.
8. The composition of claim 1 , further comprising a compatibilizer.
9. The composition of claim 1 , wherein the delta E of the wood-plastic polymer composition is 11.4 or less.
10. An article of manufacture comprising the composition of claim 1 .
11. A method for forming a wood-plastic polymer composition comprising the steps of:
blending
a) from 40 to 90 wt % of a thermoplastic resin,
b) from 10 to 60 wt % of a wood filler;
c) from 0.1 to 0.8 wt % of a thermal stabilizer comprising a blend of 1,3,5-Tris(4-tert-butyl-3-hydroxy-2,6-dimethyl benzyl)-1,3,5-triazine-(1H,3H,5H)-trione and Tris (2,4-di-t-butylphenyl)phosphite; and
d) from 0.01 to 1.0 wt % of an ultraviolet stabilizer comprising a blend of an ultraviolet absorbers and a hindered amine light stabilizer; and
molding the polymer composition,
wherein the wood-plastic polymer composition has an oxidation induction time of at least 90 minutes.
12. The method of claim 11 , wherein the thermoplastic resin selected from polypropylene homopolymer, polypropylene copolymer, ethylene propylene diene monomer (EPDM), maleated propylene diene monomer (m-EPDM), ethylene-polypropylene copolymer, maleated ethylene-polypropylene copolymer (m-EP copolymers), a thermoplastic elastomer, a thermoplastic rubber, ethylene/vinyl acetate copolymer (EVA), a poly(4-methyl-1-pentene) homopolymer, poly(4-methyl-1-pentene/1-decene) copolymer, very low density polyethylene (VLDPE), (m) low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), crosslinked polyethylene (XLPE), crosslinked polypropylene (XLPP), nylon-6, nylon-6,6, nylon-4, nylon-4,6, nylon-12, nylon-6,10, nylon-6,9, nylon-6,12, nylon-9T, copolymer of nylon-6,6 and nylon-6, polyamide copolymers, polyamide blends, or a combination including at least one of the foregoing resins.
13. The method of claim 11 , wherein the wood filler comprises wood flour, vegetal fibers, or a combination including wood flour and vegetal fibers.
14. The method of claim 11 , wherein the ultraviolet absorber is selected from benzophenones and benzotriazoles.
15. The method of claim 11 , wherein the thermoplastic resin comprises from 1 to 30 wt % of a polyamide blended with a polyolefin or from 1 to 30 wt % of a polyolefin blended with a polyamide.
16. The method of claim 15 , wherein the polyamide is selected from nylon-6, nylon-6,6, nylon-4, nylon-4,6, nylon-12, nylon-6,10, nylon-6,9, nylon-6,12, nylon-9T, copolymer of nylon-6,6 and nylon-6, polyamide copolymers, polyamide blends and combinations thereof.
17. The method of claim 15 , wherein the polyolefin is selected from polypropylene homopolymer, polypropylene copolymer, ethylene propylene diene monomer (EPDM), maleated propylene diene monomer (m-EPDM), ethylene-polypropylene copolymer, maleated ethylene-polypropylene copolymer (m-EP copolymers), a thermoplastic elastomer, a thermoplastic rubber, ethylene/vinyl acetate copolymer (EVA), a poly(4-methyl-1-pentene) homopolymer, poly(4-methyl-1-pentene/1-decene) copolymer, very low density polyethylene (VLDPE), (m) low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), linear low density polyethylene (LLDPE), crosslinked polyethylene (XLPE), crosslinked polypropylene (XLPP) and combinations thereof.