Insecticidal and/or herbicidal composition having improved activity based on spiroheterocyclically substituted tetramic acid derivatives
View Patent ↗The present invention relates to boosting the action of crop protection compositions comprising in particular spiroheterocyclically substituted tetramic acid derivatives of the formula (I) by addition of ammonium or phosphonium salts and optionally penetrants, to the corresponding compositions, to processes for their preparation and to their use in crop protection as insecticides and/or acaricides and/or for preventing unwanted vegetation.
1. A composition comprising a compound of formula (I) and a salt of formula (III′):
wherein in formula (I),
W represents hydrogen, chlorine, bromine, methyl, ethyl, methoxy or ethoxy,
X represents chlorine, bromine, iodine, methyl, ethyl, methoxy, ethoxy, propoxy, cyclopropyl or trifluoromethyl,
Y and Z independently of one another represent hydrogen, fluorine, chlorine, bromine, iodine, methyl, ethyl, methoxy, cyclopropyl, trifluoromethyl, trifluoromethoxy or trifluoroethoxy,
A represents methyl, ethyl or propyl,
G represents hydrogen (a), or represents
in which
L represents oxygen,
M represents oxygen,
R 2 represents C 1 -C 10 -alkyl, C 2 -C 10 -alkenyl or C -C 4 -alkoxy-C 2 -C 4 -alkyl, each of which is optionally mono- to trisubstituted by fluorine or chlorine, or
represents cyclopentyl or cyclohexyl,
or represents phenyl or benzyl, each of which is optionally mono- or disubstituted by fluorine, chlorine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy,
and,
wherein in the salt of formula (III′)
D represents nitrogen or phosphorus,
R 26 , R 27 , R 28 and R 29 independently of one another represent hydrogen or, in each case, optionally substituted C 1 -C 8 -alkyl, or mono- or polyunsaturated, optionally substituted C 1 -C 8 -alkylene, the optional substituents being selected from the group consisting of halogen, nitro, cyano and combinations thereof,
n represents 1, 2, 3 or 4, and
R 30 represents an organic or inorganic anion.
2. The composition of claim 1 , further comprising at least one penetrant.
3. A method of controlling harmful insects, spider mites, unwanted vegetation, or any combination thereof, comprising applying an effective amount of the composition of claim 1 , to the insects, their habitat, the spider mites, their habitat, the unwanted vegetation, or any combination thereof.
4. A spray liquor, comprising water and the composition of claim 1 .
5. The spray liquor of claim 4 , further comprising a penetrant.
6. A method of protecting crops, comprising applying the composition of claim 1 to the crops.
7. The composition of claim 1 , wherein in the salt of formula (III′), D represents nitrogen.
8. (Withdrawn, Currently amended) The composition of claim 1 , wherein in the salt of formula (III′), D represents phosphorus.
9. The composition of claim 1 , wherein the salt of formula (III′) is ammonium sulphate, diammonium hydrogenphosphate, or a combination thereof.
10. The composition of claim 1 , wherein in the compound of formula (I), G represents hydrogen.