IP Library Granted Patent US 8,945,507
Granted Patent B2
US 8,945,507 · App. 13/091,471 · Granted Feb 3, 2015

Systems and methods for operating a gasifier

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Quick Facts
Patent No.
US 8,945,507
App. No.
13/091,471
Granted
Feb 3, 2015
Kind
B2
Abstract

Systems and methods for operating a gasifier are provided. The method can include combusting a first start-up fuel to produce a first combustion gas. A temperature within the gasifier can be increased from a starting temperature to at least an auto-ignition temperature of a second start-up fuel by introducing the first combustion gas to the gasifier. A second start-up fuel can be introduced directly to the gasifier after the temperature within the gasifier is at least the auto-ignition temperature of the second start-up fuel. At least a portion of the second start-up fuel can be combusted within the gasifier to produce a second combustion gas. The second combustion gas can produce sufficient heat to increase the temperature within the gasifier to a hydrocarbon feedstock gasification temperature. A hydrocarbon feedstock can be introduced to the gasifier. At least a portion of the hydrocarbon feedstock can be gasified within the gasifier to produce a syngas.

Claims (40)

1. A method for operating a gasifier, comprising:

combusting a first start-up fuel to produce a first combustion gas;

increasing a temperature within a gasifier from a starting temperature to at least an auto-ignition temperature of a second start-up fuel by introducing the first combustion gas to the gasifier;

introducing the second start-up fuel directly to the gasifier after the temperature within the gasifier is at least the auto-ignition temperature of the second start-up fuel;

combusting at least a portion of the second start-up fuel within the gasifier to produce a second combustion gas, wherein the second combustion gas produces sufficient heat to increase the temperature within the gasifier to a hydrocarbon feedstock gasification temperature;

introducing a hydrocarbon feedstock to the gasifier; and

gasifying at least a portion of the hydrocarbon feedstock within the gasifier to produce a syngas.

2. The method of claim 1 , further comprising maintaining a sufficient amount of an oxidant within the gasifier to combust at least a portion of the second start-up fuel, wherein the oxidant concentration in the second combustion gas is maintained below about 1 mol%.

3. The method of claim 1 , further comprising maintaining a sufficient amount of an oxidant within the gasifier to combust a portion of the hydrocarbon feedstock, wherein the oxidant concentration in the syngas is maintained below about 1 mol%.

4. The method of claim 1 , wherein the second start-up fuel is introduced to the gasifier downstream relative to the first combustion gas.

5. The method of claim 1 , further comprising circulating particulates through the gasifier.

6. The method of claim 1 , further comprising circulating particulates through the gasifier prior to introducing the first combustion gas thereto, wherein circulation of the particulates is maintained during introduction of the second start-up fuel and introduction of the hydrocarbon feedstock.

7. The method of claim 6 , wherein the particulates comprise sand, ash, ceramic, limestone, or any combination thereof.

8. The method of claim 1 , further comprising stopping introduction of the first combustion gas after introduction of the second start-up fuel begins.

9. The method of claim 1 , further comprising stopping introduction of the second start-up fuel after introduction of the hydrocarbon feedstock begins.

10. The method of claim 1 , wherein the auto-ignition temperature of the second start-up fuel ranges from about 200° C. to about 560° C., and wherein the hydrocarbon feedstock gasification temperature is about 700° C. or more.

11. The method of claim 1 , wherein the gasifier is heated to the hydrocarbon feedstock gasification temperature before the hydrocarbon feedstock is introduced to the gasifier.

12. The method of claim 1 , wherein the second start-up fuel comprises one or more hydrocarbons having from 1 to about 25 carbon atoms.

13. The method of claim 1 , wherein the second start-up fuel is diesel, and wherein the diesel has an auto-ignition temperature ranging from about 305° C. to about 325° C.

14. A method for operating a gasifier, comprising:

circulating particulates through a gasifier;

increasing a temperature within the gasifier from an initial temperature to an intermediate temperature by introducing a first combustion gas to the gasifier, wherein the first combustion gas is produced by combusting a first start-up fuel, and wherein the intermediate temperature is sufficient to auto-ignite a second start-up fuel;

introducing the second start-up fuel directly to the gasifier after the gasifier is at the intermediate temperature, wherein the second start-up fuel is introduced to the gasifier downstream relative to the first combustion gas;

combusting at least a portion of the second start-up fuel within the gasifier to increase the temperature within the gasifier to an operating temperature, wherein the operating temperature is sufficient to gasify a hydrocarbon feedstock;

stopping introduction of the first combustion gas after introduction of the second start-up fuel begins;

introducing the hydrocarbon feedstock to the gasifier after the gasifier is at the operating temperature;

gasifying at least a portion of the hydrocarbon feedstock within the gasifier to produce a syngas; and

stopping introduction of the second start-up fuel after introduction of the hydrocarbon feedstock begins.

15. The method of claim 14 , wherein the intermediate temperature ranges from about 200° C. to about 560° C., and wherein the operating temperature is about 700° C. or more.

16. The method of claim 14 , further comprising maintaining a sufficient amount of an oxidant within the gasifier to combust the at least a portion of the second start-up fuel, wherein the oxidant is introduced to the gasifier as a component of the first combustion gas, directly to the gasifier, as a component of the second start-up fuel, combined with one or more inert gases, or any combination thereof, and wherein the oxidant concentration in the second combustion gas is maintained below about 1 mol%.

17. The method of claim 14 , further comprising increasing a pressure within the gasifier from an initial pressure to an operating pressure as the temperature within the gasifier is increased from the initial temperature to the operating temperature.

18. The method of claim 14 , wherein the first combustion gas is produced within a start-up burner having a turn down ratio of about 3 or less.

19. A system for gasifying a hydrocarbon feedstock, comprising:

a gasifier having a riser disposed therein;

a start-up burner for combusting a first start-up fuel to produce a first combustion gas;

a transfer line in fluid communication with a combustion gas outlet of the start-up burner and a combustion gas inlet of the riser for introducing the first combustion gas to the gasifier;

a second start-up fuel nozzle disposed on the riser and adapted to introduce a second start-up fuel to the gasifier;

a hydrocarbon feed line in fluid communication with the riser downstream of the combustion gas inlet and upstream of the second start-up fuel nozzle; and

a particulate recycle line in fluid communication with the riser at a location downstream of the combustion gas inlet and upstream of the hydrocarbon feed line.

20. The system of claim 19 , further comprising a first oxidant supply line in fluid communication with the riser upstream of the combustion gas inlet and a second oxidant supply line in fluid communication with the riser downstream of the combustion gas inlet and upstream of the hydrocarbon feed line, wherein the combustion gas inlet of the riser, the second start-up fuel nozzle, and the hydrocarbon feed line are all in fluid communication with the riser between a first and second end thereof.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Jun 30, 2025
From: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
To: KELLOGG BROWN & ROOT LLC
Reel/Frame 071570/0242 →
SECURITY INTEREST Recorded Apr 25, 2018
From: KELLOGG BROWN & ROOT LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 046022/0413 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2011
From: ABUGHAZALEH, JOHN
To: KELLOGG BROWN & ROOT LLC
Reel/Frame 026163/0409 →