Particulate superabsorbent polymer composition having improved performance properties
The present invention relates to a particulate superabsorbent polymer composition which absorbs water, aqueous liquids, and blood, and a process to make the superabsorbent polymers, wherein a superabsorbent polymer is surface treated with a neutralized multivalent metal salt solution having a pH value similar as that of human skin. The present invention also relates to particulate superabsorbent polymer composition having high Gel Bed Permeability and high Absorbency Under Load.
1. A particulate superabsorbent polymer composition comprising a polymer comprising:
a) from about 55 wt % to about 99.9 wt % of polymerizable unsaturated acid group containing monomers;
b) from 0 wt % to 40 wt % of polymerized, ethylenically unsaturated monomers copolymerizable with a);
c) from about 0.001 wt % to about 5.0 wt % based on the weight of a) of an internal crosslinking agent, wherein the components a), b) and c) are polymerized into a hydrogel which is granulated into particulate superabsorbent polymer having a surface;
d) from about 0.001 wt % to about 5.0 wt % based on the dry particulate superabsorbent composition weight of surface crosslinking agent applied to the surface of the particulate superabsorbent polymer; and
e) from 0.01 wt % to about 5 wt % based on the dry particulate superabsorbent composition weight of a neutralized multivalent metal salt applied to the surface of the particulate superabsorbent polymer, wherein said neutralized multivalent metal salt further comprises an organic acid or its salt, wherein the molar ratio of said organic acid to the multivalent metal is between about 0.75:1 to about 1.5:1, and wherein the neutralized multivalent metal is in the form of an aqueous solution having a pH value from about 5.5 to about 7
wherein the superabsorbent polymer composition has a degree of neutralization of from about 50 mol % to about 80 mol %; and the particulate superabsorbent polymer composition have a Gel Bed Permeability of from about 30 Darcy to about 100 Darcy as measured by the Free-Swell Gel Bed Permeability Test as set forth herein; a Centrifuge Retention Capacity of from about 25 g/g to about 50 g/g as measured by the Centrifuge Retention Capacity Test as set forth herein, and an absorbency under load at 0.9 psi from about 16 g/g to 24 g/g as measured by the Absorbency Under Load Test (AUL(0.9 psi)) as set forth herein.
2. The particulate superabsorbent polymer composition according to claim 1 wherein the Centrifuge Retention Capacity is from about 27 g/g to about 35 g/g.
3. The particulate superabsorbent polymer composition according to claim 1 wherein the Centrifuge Retention Capacity is from about 30 g/g to about 35 g/g.
4. The particulate superabsorbent polymer composition according to claim 1 wherein said neutralized multivalent metal salt has a pH value from about 6 to 7.
5. The particulate superabsorbent polymer composition according to claim 1 wherein said neutralized multivalent metal salt is a water-soluble aluminum salt.
6. The particulate superabsorbent polymer composition according to claim 1 wherein said organic acid is a hydroxyl mono-carboxylic acid.
7. The particulate superabsorbent polymer composition according to claim 1 wherein said organic acid is selected from lactic acid, glycolic acid, gluconic acid, or 3-hydroxypropionic acid.
8. A particulate superabsorbent polymer composition comprising a polymer comprising:
a) from about 55 wt % to about 99.9 wt % of polymerizable unsaturated acid group containing monomers;
b) from 0 wt % to 40 wt % of polymerized, ethylenically unsaturated monomers copolymerizable with a);
c) from about 0.001 wt % to about 5.0 wt % based on the weight of a) of an internal crosslinking agent, wherein the components a), b) and c) are polymerized into a hydrogel which is granulated into particulate superabsorbent polymer having a surface;
d) from about 0.001 wt % to about 5.0 wt % based on the dry particulate superabsorbent composition weight of surface crosslinking agent applied to the surface of the particulate superabsorbent polymer; and
e) from about 0.01 wt % to about 5 wt % based on the dry particulate superabsorbent composition weight of aluminum salt applied to the surface of the particulate superabsorbent polymer, wherein said aluminum salt further comprises a deprotonated hydroxyl mono-carboxylic acid or its salt, and wherein the aluminum salt is in the form of an aqueous solution having a pH value from about 5.5 to about 7
wherein said aluminum salt solution comprises aluminum cations and anions of a deprotonated hydroxyl mono-carboxylic acid with a molar ratio of carboxylic anions to aluminum cations between about 0.75:1 to about 1.5:1, wherein the superabsorbent polymer composition has a degree of neutralization of from about 50 mol % to about 80 mol %; and the particulate superabsorbent polymer composition have a Gel Bed Permeability of from about 30 Darcy to about 100 Darcy as measured by the Free-Swell Gel Bed Permeability Test set forth herein; a Centrifuge Retention Capacity of from about 25 g/g to about 50 g/g as measured by the Centrifuge Retention Capacity Test set forth herein, and an absorbency under load at 0.9 psi from about 16 g/g to 24 g/g as measured by the Absorbency Under Load Test (AUL(0.9 psi)) set forth herein.
9. The particulate superabsorbent polymer composition according to claim 8 wherein the Centrifuge Retention Capacity is from about 27 g/g to about 35 g/g.
10. The particulate superabsorbent polymer composition according to claim 8 wherein the Centrifuge Retention Capacity is from about 30 g/g to about 35 g/g.
11. The particulate superabsorbent polymer composition according to claim 8 wherein said neutralized multivalent metal salt has a pH value from about 6 to 7.
12. A process for the production of a particulate superabsorbent polymer composition comprising the following steps:
a) providing a particulate superabsorbent polymer;
b) preparing a neutralized multivalent metal salt wherein said neutralized multivalent metal salt further comprises a deprotonated organic acid or its salt, wherein the molar ratio of said organic acid to multivalent metal is between about 0.75:1 to about 1.5:1, and wherein the neutralized multivalent metal is in the form of an aqueous solution having a pH value from about 5.5 to about 7;
c) applying the neutralized multivalent metal salt solution on the surface of the particulate superabsorbent polymer wherein
wherein the particulate superabsorbent polymer composition has a degree of neutralization of from about 50 mol % to about 80 mol %; and the particulate superabsorbent polymer composition has the characteristics of a Gel Bed Permeability of from about 30 Darcy to about 100 Darcy as measured by the Free-Swell Gel Bed Permeability Test set forth herein; a Centrifuge Retention Capacity from about 25 g/g to about 50 g/g as measured by the Centrifuge Retention Capacity Test set forth herein, and an absorbency under load at 0.9 psi from about 16 g/g to 24 g/g as measured by the Absorbency Under Load Test (AUL(0.9 psi)) set forth herein.
13. The process according to claim 12 wherein said neutralized multivalent metal salt is aluminum salt.
14. The process according to claim 12 wherein said deprotonated organic acid is a hydroxyl mono-carboxylic acid.
15. The process according to claim 12 wherein said deprotonated organic acid is selected from lactic acid, glycolic acid, gluconic acid, or 3-hydroxypropionic acid.
16. The process according to claim 12 wherein the amount of the neutralized multivalent metal salt is from 0.01 wt % to about 5 wt % based on the dry particulate superabsorbent composition.
17. The process according to claim 12 wherein said aqueous solution has a pH value from about 6 to 7.
18. A process for the production of a particulate superabsorbent polymer composition comprising the following steps:
a) providing a particulate superabsorbent polymer;
b) bringing the superabsorbent polymer into contact with an aqueous solution of comprising a multivalent cation and an anion of a deprotonated organic acid with a molar ratio of organic acid to multivalent cation between about 0.75:1 to about 1.5:1;
wherein said aqueous solution has a pH value from about 5.5 to about 7; and said organic acid is a hydroxyl mono-carboxylic acid
wherein the particulate superabsorbent polymer composition has a degree of neutralization of from about 50 mol % to about 80 mol %; and the particulate superabsorbent polymer composition has the characteristics of a Gel Bed Permeability of from about 30 Darcy to about 100 Darcy as measured by the Free-Swell Gel Bed Permeability Test set forth herein; a Centrifuge Retention Capacity from about 25 g/g to about 50 g/g as measured by the Centrifuge Retention Capacity Test set forth herein, and an absorbency under load at 0.9 psi from about 16 g/g to 24 g/g as measured by the Absorbency Under Load Test (AUL(0.9 psi)) set forth herein.
19. The process according to claim 18 wherein said multivalent cation is aluminum cation A1 3+ .
20. The process according to claim 18 wherein said organic acid is selected from lactic acid, glycolic acid, gluconic acid, or 3-hydroxypropionic acid.
21. The process according to claim 18 wherein said aqueous solution has a pH value from about 6 to 7.
22. An absorbent article comprising the particulate superabsorbent polymer composition of claim 1 .
23. The particulate superabsorbent polymer composition according to claim 1 further comprising from about 0.01 wt % to about 0.5 wt % based on the dry particulate superabsorbent polymer composition of a thermoplastic polymer that is selected from polyolefin, polyethylene, linear low density polyethylene, ethylene acrylic acid copolymer, styrene copolymers, ethylene alkyl methacrylate copolymer, polypropylene, maleated polypropylene, ethylene vinyl acetate copolymer, polyamide, polyester, blends thereof, or copolymers thereof to form a thermoplastic coated particulate superabsorbent polymer.
24. The particulate superabsorbent polymer composition according to claim 23 wherein the thermoplastic polymer comprises maleated polypropylene.
25. The particulate superabsorbent polymer composition according to claim 1 having a water content of up to about 10 wt % of the superabsorbent polymer composition.
26. The particulate superabsorbent polymer composition according to claim 8 further comprising from about 0.01 wt % to about 0.5 wt % based on the dry particulate superabsorbent polymer composition of a thermoplastic polymer that is selected from polyolefin, polyethylene, linear low density polyethylene, ethylene acrylic acid copolymer, styrene copolymers, ethylene alkyl methacrylate copolymer, polypropylene, maleated polypropylene, ethylene vinyl acetate copolymer, polyamide, polyester, blends thereof, or copolymers thereof to form a thermoplastic coated particulate superabsorbent polymer.
27. The particulate superabsorbent polymer composition according to claim 26 wherein the thermoplastic polymer comprises maleated polypropylene.
28. The particulate superabsorbent polymer composition according to claim 8 having a water content of up to about 10 wt % of the superabsorbent polymer composition.