Reflective mask blank for EUV lithography
View Patent ↗A reflective mask blank for EUV lithography having a low-reflective layer which has a low reflectivity with respect to wavelengths of EUV light and a mask pattern inspection light and which satisfies a predetermined reflectivity (405 nm: <40%, 600 to 650 nm: 30 to 50%, 800 to 900 nm: >50%, 1,000 to 1,200 nm: <90%) in a wavelength region (400 to 1,200 nm) required for the mask production process and the pattern transcription process. A reflective mask blank for EUV lithography having a reflective layer for reflecting EUV light, an absorbing layer for absorbing EUV light and a low-reflective layer with respect to a mask pattern inspection light (wavelength: 190 to 260 nm), which are formed in this order on a substrate, wherein the low-reflective layer contains at least tantalum (Ta), oxygen (O) and hydrogen (H), and the low-reflective layer has a Ta+O total content that is between 85 and 99.9 at % and an H content that is between 0.1 and 15 at %.
1. A reflective mask blank for EUV lithography, comprising:
a substrate;
a reflective layer which reflects EUV light;
an absorbing layer which absorbs EUV light; and
a low-reflective layer with respect to a mask pattern inspection light in a range of 190 nm to 260 nm,
wherein the reflective layer, absorbing layer and the low-reflective layer are formed over the substrate in an order of the reflective layer, the absorbing layer and the low-reflective layer, the low-reflective layer comprises Ta, O and H, and the low-reflective layer has a total content of Ta and O in a range between 85 and 99. 9 at % and a hydrogen content in a range between 0.1 and 15 at %.
2. The reflective mask blank for EUV lithography according to claim 1 , wherein the low-reflective layer has a Ta:O composition ratio in a range between 1:8 and 3:1.
3. The reflective mask blank for EUV lithography according to claim 1 , wherein the surface roughness of the low-reflective layer is 0.5 nm or less.
4. The reflective mask blank for EUV lithography according to claim 1 , wherein the low-reflective layer has an amorphous surface structure.
5. The reflective mask blank for EUV lithography according to claim 1 , wherein the low-reflective layer has a film thickness in a range between 3 and 30 nm.
6. The reflective mask blank for EUV lithography according to claim 1 , wherein the absorbing layer comprises Ta as a main component.
7. The reflective mask blank for EUV lithography according to claim 1 , wherein the absorbing layer comprises Ta as a main component and at least one element selected from the group consisting of Hf, Si, Zr, Ge, B, N and H.
8. The reflective mask blank for EUV lithography according to claim 1 , wherein the absorbing layer has an oxygen content of less than 25 at %.
9. The reflective mask blank for EUV lithography according to claim 1 , wherein the absorbing layer and the low-reflective layer have a total film thickness in a range between 30 and 200 nm.
10. The reflective mask blank for EUV lithography according to claim 1 , further comprising a protection layer formed between the reflective layer and the absorbing layer such that the protection layer protects the reflective layer at the time of forming a pattern in the absorbing layer, wherein with respect to the mask pattern inspection light, the protection layer and the low-reflective layer have a contrast of the reflection light at a surface of the protection layer with the reflection light at a surface of the low-reflective layer which is 60% or more.
11. The reflective mask blank for EUV lithography according to claim 1 , wherein the hydrogen content of the low-reflective layer is at least 1 at % higher than a hydrogen content of the absorbing layer.
12. The reflective mask blank for EUV lithography according to claim 1 , wherein with respect to the mask pattern inspection light, the low-reflective layer has a reflectivity at a surface of the low-reflective layer which is 15% or less.
13. The reflective mask blank for EUV lithography according to claim 1 , wherein the low-reflective layer is formed by sputtering a Ta target in an atmosphere comprising O, H and at least one inert gas selected from the group consisting of He, Ar, Ne, Kr and Xe.
14. A reflective mask for EUV lithography, produced by a process comprising patterning the absorbing layer and the low-reflective layer of a reflective mask blank for EUV lithography according to claim 1 .
15. A method for producing a semiconductor integrated circuit, comprising:
exposing light to a substrate with a reflective mask for EUV lithography according to claim 14 .
16. A reflective mask blank for EUV lithography, comprising:
a substrate;
a reflective layer which reflects EUV light;
an absorbing layer which absorbs EUV light; and
a low-reflective layer with respect to a mask pattern inspection light having a wavelength in a range of 190 nm to 260 nm,
wherein the reflective layer, the absorbing layer and the low-reflective layer are formed over the substrate in an order of the reflective layer, the absorbing layer and the low-reflective layer, the low-reflective layer comprises Ta, O, N and H, and the low-reflective layer has a total content of Ta, O and N in a range between 85 and 99. 9 at % and a hydrogen content in a range between 0.1 and 15 at %.
17. The reflective mask blank for EUV lithography according to claim 16 , wherein the low-reflective layer has a Ta:(O+N) composition ratio in a range of 1:8 to 3:1.
18. The reflective mask blank for EUV lithography according to claim 16 , wherein the surface roughness of the low-reflective layer is 0.5 nm or less.
19. The reflective mask blank for EUV lithography according to claim 16 , wherein the low-reflective layer has an amorphous surface structure.
20. The reflective mask blank for EUV lithography according to claim 16 , wherein the low-reflective layer has a film thickness which is between 3 and 30 nm.
21. The reflective mask blank for EUV lithography according to claim 16 , wherein the absorbing layer comprises Ta as a main component.
22. The reflective mask blank for EUV lithography according to claim 16 , wherein the absorbing layer comprises Ta as a main component and at least one element selected from the group consisting of Hf, Si, Zr, Ge, B, N and H.
23. The reflective mask blank for EUV lithography according to claim 16 , wherein the absorbing layer has an oxygen content of less than 25 at %.
24. The reflective mask blank for EUV lithography according to claim 16 , wherein the absorbing layer and the low-reflective layer have a total film thickness in a range between 30 and 200 nm.
25. The reflective mask blank for EUV lithography according to claim 16 , further comprising a protection layer formed between the reflective layer and the absorbing layer such that the protection layer protects the reflective layer at the time of forming a pattern in the absorbing layer, wherein with respect to the mask pattern inspection light, the protection layer and the low-reflective layer have a contrast of the reflection light at a surface of the protection layer with the reflection light at a surface of the low-reflective layer which is 60% or more.
26. The reflective mask blank for EUV lithography according to claim 16 , wherein the hydrogen content of the low-reflective layer is at least 1 at % higher than a hydrogen content of the absorbing layer.
27. The reflective mask blank for EUV lithography according to claim 16 , wherein with respect to the mask pattern inspection light, the low-reflective layer has a reflectivity at a surface of the low-reflective layer which is 15% or less.
28. The reflective mask blank for EUV lithography according to claim 16 , wherein the low-reflective layer is formed by sputtering a Ta target in an atmosphere comprising O, N, H and at least one inert gas selected from the group consisting of He, Ar, Ne, Kr and Xe.
29. A reflective mask for EUV lithography, produced by a process comprising patterning the absorbing layer and the low-reflective layer of a reflective mask blank for EUV lithography according to claim 16 .
30. A method for producing a semiconductor integrated circuit, comprising:
exposing light to a substrate with a reflective mask for EUV lithography according to claim 29 .
31. A method for producing a reflective mask blank for EUV lithography, comprising:
forming over a substrate a reflective layer which reflects EUV light, an absorbing layer which absorbs EUV light and a low-reflective layer with respect to a mask pattern inspection light having a wavelength in a range of 190 nm to 260 nm in an order of the reflective layer, the absorbing layer and the low-reflective layer,
wherein the forming of the low-reflective layer comprises sputtering a Ta target in an atmosphere comprising O, H and at least one inert gas selected from the group consisting of He, Ar, Ne, Kr and Xe.
32. A method for producing a reflective mask blank for EUV lithography, comprising:
forming over a substrate a reflective layer which reflects EUV light, an absorbing layer which absorbs EUV light and a low-reflective layer with respect to a mask pattern inspection light having a wavelength in a range of 190 nm to 260 nm in an order of the reflective layer, the absorbing layer and the low-reflective layer,
wherein the forming of the low-reflective layer comprises sputtering a Ta target in an atmosphere comprising O, N, H and at least one inert gas selected from the group consisting of He, Ar, Ne, Kr and Xe.