Methods of forming polycrystalline compacts
View Patent ↗Methods of forming a polycrystalline compact for use in an earth-boring tool include sintering a plurality of hard particles with catalyst material to form a polycrystalline material that includes a plurality of inter-bonded particles of hard material integrally formed with the catalyst material and introducing at least a portion of the polycrystalline material to a reactive material to remove at least a portion of the catalyst material contained within the polycrystalline material. The reactive material may include at least one of a molten glass, an ionic compound, a leaching liquor, and a chemical plasma. The reactive material may be introduced to the polycrystalline material at a temperature of greater than or equal to a melting point thereof.
1. A method of forming a polycrystalline compact for use in an earth-boring tool, comprising:
at least partially melting at least one of a silicate glass, an alkali metal salt, and a rare earth element to form a reactive material;
introducing the reactive material to a polycrystalline compact comprising a plurality of interstitial spaces between inter-bonded crystals of a polycrystalline material throughout which interstitial spaces a catalyst material is dispersed; and
removing at least a portion of the catalyst material with the reactive material from at least a portion of the plurality of interstitial spaces.
2. The method of claim 1 , further comprising, before introducing the reactive material to the polycrystalline compact, forming a mask over at least a portion of at least one surface of the polycrystalline compact, the mask comprising a material impervious to the reactive material.
3. The method of claim 1 , wherein at least partially melting at least one of a silicate glass, an alkali metal salt, and a rare earth element to form a reactive material comprises at least partially melting at least one of a borosilicate glass, an aluminosilicate glass, a phosphosilicate glass, and a borophosphosilicate glass to form the reactive material.
4. The method of claim 1 , wherein at least partially melting at least one of a silicate glass, an alkali metal salt, and a rare earth element to form a reactive material comprises heating the at least one of the silicate glass, the alkali metal salt, and the rare earth element to a temperature of greater than or equal to a melting point thereof.
5. The method of claim 1 , wherein at least partially melting at least one of a silicate glass, an alkali metal salt, and a rare earth element to form a reactive material comprises at least partially melting an alkali salt comprising at least one of lithium, sodium, potassium, rubidium, cesium, francium, calcium, silica, and aluminum to form the reactive material.
6. The method of claim 1 , wherein introducing the reactive material to a polycrystalline compact comprises introducing a reactive material comprising a molten lithium salt to the polycrystalline compact comprising a plurality of interstitial spaces between inter-bonded crystals of a polycrystalline material throughout which interstitial spaces, a catalyst material comprising cobalt is dispersed.
7. The method of claim 1 , wherein introducing the reactive material to a polycrystalline compact comprises introducing a molten silicate glass to the polycrystalline compact comprising a plurality of interstitial spaces between inter-bonded crystals of a polycrystalline material throughout which interstitial spaces, a catalyst material comprising cobalt is dispersed.
8. The method of claim 7 , wherein introducing a molten silicate glass to the polycrystalline compact comprising a plurality of interstitial spaces between inter-bonded crystals of a polycrystalline material throughout which interstitial spaces, a catalyst material comprising cobalt is dispersed comprises introducing the molten silicate glass to the polycrystalline compact at a temperature of less than about 1000° C.
9. The method of claim 1 , wherein introducing the reactive material to a polycrystalline compact comprising a plurality of interstitial spaces between inter-bonded crystals of a polycrystalline material throughout which interstitial spaces, a catalyst material is dispersed comprises introducing the alkali metal salt to a polycrystalline compact comprising a catalyst material at a temperature of less than or equal to 400° C.
10. A method of forming a polycrystalline compact for use in an earth-boring tool, comprising:
at least partially melting a rare earth element to form a reactive material; and
introducing the reactive material to a polycrystalline compact comprising a catalyst material disposed in interstitial spaces between inter-bonded crystals of a polycrystalline material to remove at least a portion of the catalyst material, wherein at least partially melting a rare earth element to form a reactive material comprises at least partially melting a plurality of rare earth elements to form a binary eutectic liquid.
11. The method of claim 10 , wherein at least partially melting a plurality of rare earth elements to form a binary eutectic liquid comprises at least partially melting the plurality of rare earth elements to form at least one of a cobalt-germanium eutectic, cobalt-neodymium eutectic, cobalt-yttrium eutectic, cobalt-cerium eutectic, and cobalt-gadolinium eutectic.
12. A method of forming a polycrystalline compact cutting element for an earth-boring tool, comprising:
forming a cutting element comprising a polycrystalline material and a catalyst material disposed in interstitial spaces between inter-bonded crystals of the polycrystalline material; and
removing at least a portion of the catalyst material from the interstitial spaces by exposing at least a portion of the polycrystalline material to a chemical plasma comprising an inert gas or an oxidizing agent, wherein removing at least a portion of the catalyst material from the interstitial spaces by exposing at least a portion of the polycrystalline material to a chemical plasma comprises introducing at least one surface of the polycrystalline material to a chemical plasma comprising at least one of argon, nitrogen, helium, xenon, krypton, and radon.
13. The method of claim 12 , wherein introducing at least one surface of the polycrystalline material to a chemical plasma comprising at least one of argon, nitrogen, helium, xenon, krypton, and radon comprises introducing at least one surface of the polycrystalline material to the chemical plasma at a temperature of between about 300° C. and about 750° C.
14. A method of forming a polycrystalline compact cutting element for an earth-boring tool, comprising:
forming a cutting element comprising a polycrystalline material and a catalyst material disposed in interstitial spaces between inter-bonded crystals of the polycrystalline material; and
removing at least a portion of the catalyst material from the interstitial spaces by exposing at least a portion of the polycrystalline material to a chemical plasma comprising an inert gas or an oxidizing agent, wherein removing at least a portion of the catalyst material from the interstitial spaces by exposing at least a portion of the polycrystalline material to a chemical plasma comprises introducing at least one surface of the polycrystalline material to a chemical plasma comprising at least one of oxygen, ozone, fluorine, chlorine, and a peroxide.