Aqueous fluoropolymer dispersion stabilized with amine oxide surfactant and process for making coagulated fluoropolymer resin
View Patent ↗An aqueous fluoropolymer dispersion comprising an aqueous medium, fluoropolymer particles, and an amine oxide surfactant. Coagulated fluoropolymer resin is produced from the dispersion by adding an acidic reagent in sufficient amount to cause coagulation and separation of the coagulated fluoropolymer resin from the aqueous medium. Another particulate component such as particular polymer, filler, pigment, solid lubricant, etc., may be added to the dispersion and co-coagulated to form a mixture of coagulated fluoropolymer resin and particulate component.
1. A process for producing a coagulated fluoropolymer resin comprising:
providing an aqueous fluoropolymer dispersion comprising an aqueous medium, fluoropolymer particles having a number average particle size of about 10 to about 400 nm, and a surfactant for stabilization of the aqueous fluoropolymer dispersion which is selectively destabilized by the addition of an acidic reagent;
adding an acidic reagent into said dispersion in sufficient amount to coagulate said fluoropolymer particles to produce coagulated fluoropolymer resin; and
separating coagulated fluoropolymer resin from said aqueous medium.
2. The process of claim 1 wherein said acidic reagent is added into said dispersion in sufficient amount to reduce the pH to less than about 7.
3. The process of claim 1 further comprising agitating said dispersion.
4. The process of claim 1 further comprising drying said coagulated fluoropolymer resin.
5. The process of claim 1 further comprising adding a particulate component to said aqueous dispersion prior to adding said acidic reagent, said acidic reagent causing co-coagulation of said fluoropolymer particles and said particulate component.
6. The process of claim 5 wherein said particulate component is added to said dispersion as a dispersion or a slurry in an aqueous medium.
7. The process of claim 1 wherein said surfactant for stabilization of the aqueous fluoropolymer dispersion is an amine oxide.
8. The process of claim 7 wherein said amine oxide surfactant is of the formula:
(R 1 )(R 2 )(R 3 )N→O
wherein R 1 is a radical of the formula:
R 4 —(C═O) a —X—(C═O) b —(CH 2 ) n —
wherein R 4 is a saturated or unsaturated, branched or unbranched, cyclic or acyclic, alkyl, hydroxyalkyl, ether or hydroxyether radical having 1 to 20 carbon atoms, X is an O, NH or NR 5 , a and b are 0 or 1 with the proviso that a+b=1, and n is 2-6;
wherein R 2 and R 3 are independently selected from saturated or unsaturated, branched or unbranched, cyclic or acyclic, alkyl, hydroxyalkyl, ether or hydroxyether radical having 1 to 10 carbon atoms, said radical optionally having halogen substitutions;
R 5 is selected from saturated or unsaturated, branched or unbranched, cyclic or acyclic, alkyl, hydroxyalkyl, ether or hydroxyether radical having 1 to 10 carbon atoms optionally substituted with halogen or an N-oxylamino group; and
wherein that R 2 and R 3 may be joined by a chemical bond to form a ring.
9. The process of claim 8 wherein R1 is a radical of the formula
R 4 —(C═O) a —X—(C═O) b —(CH 2 ) n —
wherein R 4 comprises alkyl having 1-20 carbon atoms, X is N, a and b are 0 or 1 with the proviso that a+b=1, and n is 2-4.
10. The process of claim 8 wherein R1 is a radical of the formula:
R 4 —(C═O) a —X—(C═O) b —(CH 2 ) n —
wherein R 4 comprises alkyl having 5-20 carbon atoms, X is N, a and b are 0 or 1 with the proviso that a+b=1, and n is 3.
11. The process of claim 8 wherein R 2 and R 3 are independently selected from saturated or unsaturated, branched or unbranched, cyclic or acyclic, alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms.
12. The process of claim 8 wherein R 2 and R 3 are each independently selected from alkyl or hydroxyalkyl radicals having 1 to 2 carbon atoms.
13. The process of claim 1 wherein the fluoropolymer solids content in said aqueous fluoropolymer dispersion is about 10 to about 70 wt %.
14. The process of claim 1 wherein said surfactant for stabilization of the aqueous fluoropolymer dispersion is present in said fluoropolymer dispersion in an amount of about 0.05 to about 15 wt % based on the weight of fluoropolymer solids.
15. The process of claim 1 wherein said fluoropolymer of said aqueous fluoropolymer dispersion comprises a polymer selected from homopolymers and copolymers of tetrafluoroethylene.
16. The process of claim 1 wherein said fluoropolymer of said aqueous fluoropolymer dispersion is selected from polytetrafluoroethylene and modified polytetrafluoroethylene.
17. The process of claim 1 wherein said fluoropolymer of said aqueous fluoropolymer dispersion is a melt-processible copolymer comprising at least about 40-98 mol % tetrafluoroethylene units and about 2-60 mol % of at least one other monomer.
18. The process of claim 17 wherein said at least one other monomer comprises at least one perfluorinated monomer.
19. The process of claim 8 wherein if R 2 , R 3 R 4 and R 5 of the amine oxide surfactant have halogen substitutions, said halogen substitutions are limited such that no more than 70% of the atoms attached to carbon atoms of the radical are halogen atoms.