Polycrystalline diamond compact including a polycrystalline diamond table containing aluminum carbide therein and applications therefor
View Patent ↗Embodiments of the invention relate to polycrystalline diamond compacts (“PDCs”) comprising a polycrystalline diamond (“PCD”) table including at least a portion having aluminum carbide disposed interstitially between bonded-together diamond grains thereof, and methods of fabricating such PDCs. In an embodiment, a PDC includes a substrate, and a PCD table bonded to the substrate. The PCD table includes a plurality of bonded-together diamond grains defining a plurality of interstitial regions. The PCD table further includes aluminum carbide disposed in at least a portion of the plurality of interstitial regions.
1. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from a back surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of bonded-together diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including:
a thermally-stable first region extending inwardly from the upper surface and spaced from the substrate by a standoff, the thermally-stable first region including aluminum carbide disposed in at least a portion of the plurality of interstitial regions thereof, the aluminum carbide occupying substantially all of the plurality of interstitial regions of the thermally-stable first region; and
a second region extending inwardly from the back surface and about which the thermally-stable first region extends, the second region including a metallic constituent disposed in at least a portion of the plurality of interstitial regions thereof, the second region exhibiting a coercivity of about 115 Oe to about 250 Oe and a specific magnetic saturation of greater than 0 G·cm 3 / g to about 15 G·cm 3 /g.
2. The polycrystalline diamond compact of claim 1 wherein at least a portion of the plurality of bonded-together diamond grains exhibit diamond-to-diamond bonding therebetween.
3. The polycrystalline diamond compact of claim 1 wherein at least a portion of the plurality of bonded-together diamond grains are bonded together with the aluminum carbide.
4. The polycrystalline diamond compact of claim 1 wherein the metallic constituent comprises at least one member selected from the group consisting of iron, nickel, cobalt, and alloys thereof.
5. The polycrystalline diamond compact of claim 1 wherein the metallic constituent comprises a metallic catalyst and the bonded-together diamond grains in the second region exhibit relatively more diamond-to-diamond bonding therebetween than the bonded-together diamond grains in the thermally-stable first region.
6. The polycrystalline diamond compact of claim 1 wherein the substrate comprises a cemented carbide substrate.
7. The polycrystalline diamond compact of claim 1 wherein the substrate comprises an aluminum-based substrate bonded to the polycrystalline diamond table and a cemented carbide substrate bonded to the aluminum-based substrate.
8. The polycrystalline diamond compact of claim 1 wherein the thermally-stable first region extends from the upper surface to an intermediate depth of about 0.20 mm to about 1.5 mm.
9. The polycrystalline diamond compact of claim 8 wherein the intermediate depth is about 0.65 mm to about 0.90 mm.
10. The polycrystalline diamond compact of claim 1 wherein the polycrystalline diamond table is integrally formed with the substrate.
11. The polycrystalline diamond compact of claim 1 wherein the polycrystalline diamond table comprises a pre-sintered polycrystalline diamond table.
12. The polycrystalline diamond compact of claim 1 wherein the polycrystalline diamond table comprises a residual amount of metallic catalyst.
13. The polycrystalline diamond compact of claim 12 wherein the metallic catalyst was used to initially sinter the polycrystalline diamond table.
14. The polycrystalline diamond compact of claim 1 wherein the thermally-stable first region exhibits a generally annular geometry.
15. The polycrystalline diamond compact of claim 1 wherein the coercivity is about 115 Oe to about 175 Oe and the specific magnetic saturation is about 5 G·cm 3 /g to about 15 G·cm 3 /g.
16. The polycrystalline diamond compact of claim 1 wherein the coercivity is about 155 Oe to about 175 Oe and the specific magnetic saturation is about 10 G·cm 3 /g to about 15 G·cm 3 /g.
17. A rotary drill bit, comprising:
a bit body configured to engage a subterranean formation; and
a plurality of polycrystalline diamond cutting elements affixed to the bit body, at least one of the polycrystalline diamond cutting elements including:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from a back surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of bonded-together diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including:
a thermally-stable first region extending inwardly from the upper surface and spaced from the substrate by a standoff, the thermally-stable first region including aluminum carbide disposed in at least a portion of the plurality of interstitial regions thereof, the aluminum carbide occupying substantially all of the plurality of interstitial regions of the thermally-stable first region; and
a second region extending inwardly from the back surface and about which the thermally-stable first region extends, the second region including a metallic constituent disposed in at least a portion of the plurality of interstitial regions thereof, the second region exhibiting a coercivity of about 115 Oe to about 250 Oe and a specific magnetic saturation of greater than 0 G·cm 3 / g to about 15 G·cm 3 /g.
18. The rotary drill bit of claim 17 wherein the thermally-stable first region exhibits a generally annular geometry.
19. The rotary drill bit of claim 17 wherein the coercivity is about 115 Oe to about 175 Oe and the specific magnetic saturation is about 5 G·cm 3 /g to about 15 G·cm 3 /g.
20. The rotary drill bit of claim 17 wherein the coercivity is about 155 Oe to about 175 Oe and the specific magnetic saturation is about 10 G·cm 3 /g to about 15 G·cm 3 /g.
21. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from a back surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of bonded-together diamond grains defining a plurality of interstitial regions and exhibiting diamond-to-diamond bonding therebetween, the polycrystalline diamond table further including:
a thermally-stable first region extending inwardly from the upper surface and spaced from the substrate by a standoff, the thermally-stable first region including aluminum carbide disposed in at least a portion of the plurality of interstitial regions thereof, the aluminum carbide occupying substantially all of the plurality of interstitial regions of the thermally-stable first region, the thermally-stable first region further including a residual amount of metallic catalyst present in an amount of about 0.8 weight % to about 1.5 weight %; and
a second region extending inwardly from the back surface and about which the thermally-stable first region extends, the second region including a metallic constituent disposed in at least a portion of the plurality of interstitial regions thereof, the second region exhibiting a coercivity of about 115 Oe to about 250 Oe and a specific magnetic saturation of greater than 0 G·cm 3 /g to about 15 G·cm 3 /g.
22. The polycrystalline diamond compact of claim 21 wherein the thermally-stable first region exhibits a generally annular geometry.
23. The polycrystalline diamond compact of claim 21 wherein the coercivity is about 115 Oe to about 175 Oe and the specific magnetic saturation is about 5 G·cm 3 /g to about 15 G·cm 3 /g.
24. The polycrystalline diamond compact of claim 21 wherein the coercivity is about 155 Oe to about 175 Oe and the specific magnetic saturation is about 10 G·cm 3 /g to about 15 G·cm 3 /g.
25. The polycrystalline diamond compact of claim 21 wherein the residual amount of metallic catalyst is about 0.86 weight % to about 1.47 weight %.
26. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from a back surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of bonded-together diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including:
a thermally-stable first region extending inwardly from the upper surface and spaced from the substrate by a standoff, the thermally-stable first region exhibiting a generally annular geometry, the thermally-stable first region including aluminum carbide disposed in at least a portion of the plurality of interstitial regions thereof; and
a second region extending inwardly from the back surface and about which the thermally-stable first region extends, the second region including a metallic constituent disposed in at least a portion of the plurality of interstitial regions thereof, the second region exhibiting a coercivity of about 115 Oe to about 250 Oe and a specific magnetic saturation of greater than 0 G·cm 3 /g to about 15 G·cm 3 /g.
27. The polycrystalline diamond compact of claim 26 wherein the metallic constituent comprises at least one member selected from the group consisting of iron, nickel, cobalt, and alloys thereof.
28. The polycrystalline diamond compact of claim 26 wherein the thermally-stable first region extends from the upper surface to an intermediate depth of about 0.20 mm to about 1.5 mm.
29. The polycrystalline diamond compact of claim 28 wherein the intermediate depth is about 0.65 mm to about 0.90 mm.
30. The polycrystalline diamond compact of claim 26 wherein the polycrystalline diamond table is integrally formed with the substrate.
31. The polycrystalline diamond compact of claim 26 wherein the polycrystalline diamond table comprises a pre-sintered polycrystalline diamond table.
32. The polycrystalline diamond compact of claim 26 wherein the polycrystalline diamond table comprises a residual amount of metallic catalyst.
33. A rotary drill bit, comprising:
a bit body configured to engage a subterranean formation; and
a plurality of polycrystalline diamond cutting elements affixed to the bit body, at least one of the polycrystalline diamond cutting elements including:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from a back surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of bonded-together diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including:
a thermally-stable first region extending inwardly from the upper surface and spaced from the substrate by a standoff, the thermally-stable first region exhibiting a generally annular geometry, the thermally-stable first region including aluminum carbide disposed in at least a portion of the plurality of interstitial regions thereof; and
a second region extending inwardly from the back surface and about which the thermally-stable first region extends, the second region including a metallic constituent disposed in at least a portion of the plurality of interstitial regions thereof, the second region exhibiting a coercivity of about 115 Oe to about 250 Oe and a specific magnetic saturation of greater than 0 G·cm 3 /g to about 15 G·cm 3 /g.
34. The rotary drill bit of claim 33 wherein the metallic constituent comprises at least one member selected from the group consisting of iron, nickel, cobalt, and alloys thereof.
35. The rotary drill bit of claim 33 wherein the thermally-stable first region extends from the upper surface to an intermediate depth of about 0.20 mm to about 1.5 mm.
36. The rotary drill bit of claim 35 wherein the intermediate depth is about 0.65 mm to about 0.90 mm.
37. The rotary drill bit of claim 33 wherein the polycrystalline diamond table is integrally formed with the substrate.
38. The rotary drill bit of claim 33 wherein the polycrystalline diamond table comprises a pre-sintered polycrystalline diamond table.
39. The rotary drill bit of claim 33 wherein the polycrystalline diamond table comprises a residual amount of metallic catalyst.