Ductile expanded polyesters having high impact resistance
View Patent ↗This invention relates to expanded polyester materials comprised of polyester/acrylic elastomer blend having an improved ductility and impact resistance, while the compression strength, shear strength/modulus of polyesters remain almost unchanged or unworsened. Addition of a non-reactive/reactive acrylic mixture serving as the blend partner improves the melt strength in an expanding process and leads to a better impact resistance of expanded aromatic polyester materials. All expanded polyester materials are produced with help of a reactive process.
1. An expanded polyester material comprising a polymer blend material which comprises:
a) polyester selected from the group consisting of one or more of PET, PBT and PEN; and
b) 2 to 20 wt % of an ethylene-acrylate copolymer mixture which comprises
1) 60-85 wt % of a non-reactive ethylene acrylate resin selected from the group consisting of ethylene butyl acrylate (EBA), ethylene ethyl acrylate (EEA), ethylene methyl acrylate (EMA) and any combination thereof; and
2) 15-40 wt % of a reactive ethylene acrylate resin selected from the group consisting of ethylene-acrylic ester-maleic anhydride terpolymer (EEAMA), ethylene-ethyl acrylate-glycidyl methacrylate terpolymer (EEA-GMA), ethylene-butyl acrylate-glycidyl methacrylate terpolymer (EBA-GMA) and any combination thereof; said expanded polyester material having a density below 110 kg/m 3 , a shear elongation at break higher than 20% and a compression strength greater than 0.90 MPa, and wherein said ethylene-acrylate copolymer mixture does not contain pyromellitic acid anhydride (PMDA).
2. The expanded polyester material of claim 1 , wherein said polyester is a virgin resin.
3. The expanded polyester material of claim 1 , wherein said material is expanded by decompression induced by a change in thermodynamic state.
4. The expanded polyester material of claim 3 , wherein said change in thermodynamic state results from a change in pressure or temperature or by a uniaxial or biaxial deformation, elongation or stretching of the melt mixture.
5. An article comprising the expanded polyester material of claim 1 which is thermal insulation, acoustic insulation, structural insulation, a building material, a wall panel, a floor panel, a ceiling panel, a roof panel or a support.
6. An article comprising the expanded polyester material of claim 1 .
7. An article comprising the expanded polyester material of claim 1 which is a highly loaded structure.
8. The article of claim 7 which is a windmill blade, a wagon part, an aviation part, an automotive component, or a construction component.
9. The expanded polyester material of claim 1 , wherein said polyester is a post-consumer resin.