Adjuvant composition and agrochemical formulation containing same
View Patent ↗An adjuvant composition is provided which comprises: (a) at least one water-soluble electrolyte; (b) at least one electrolyte-tolerant surfactant; (c) antifoam component which is at least one mixture selected from the group consisting of (1) at least one branched silicone resin (i), at least one silicone fluid (ii), at least one particulate metal oxide (iii) and, optionally, at least one catalyst (iv) for catalyzing the condensation of siloxy groups, (2) the equilibration reaction product of mixture (1), and (3) mixture (1) in which at least a portion of particulate metal oxide (iii) is pre-hydrophobized; (d) optionally, at least one additional bioinert material; and, (e) water.
1. An adjuvant composition comprising:
(a) at least one water-soluble electrolyte;
(b) at least one electrolyte-tolerant surfactant;
(c) antifoam component which is at least one mixture selected from the group consisting of
(1) at least one branched silicone resin (i) of the general formula M a T b D a Q d wherein M is SiO 1/2 (R 1 ) 3 , T is SiO 3/2 R 2 , D is SiO 2/2 (R 3 ) e , Q is SiO. 4/2 , R 1 , R 2 and R 3 each independently is a monovalent hydrocarbon radical of from 1 to 18 carbon atoms, a is >0.1, b is 0 to 1000, C is 0 to 1,000 and d is 1-1000, at least one silicone fluid (ii) which is a polydimethylsiloxane-containing polymer, at least one particulate metal oxide (iii) which is at least one member selected from the group consisting of fumed, precipitated or plasmatic forms of titania, alumina, silica, alumina-silica, zirconia, zirconia-silica and pre-hydrophobized forms thereof and, optionally, at least one catalyst (iv) for catalyzing the condensation of siloxy groups,
(2) the equilibration reaction product of mixture (1), and
(3) mixture (1) in which at least a portion of particulate metal oxide (iii) is pre-hydrophobized;
(d) optionally, at least one additional bioinert material; and,
(e) water,
wherein: (a) water-soluble electrolyte (a) is present at from 5 to 60 weight percent; (b) electrolyte-tolerant surfactant (b) is present at from 1 to 30 weight percent; and, (c) antifoam component (c) is present at from 0.0001 to 1.0 weight percent, and in antifoam component (c), branched silicone resin (i) is present at from 1 to 35 weight percent, silicone fluid (ii) is present at from 50 to 99 weight percent and particulate metal oxide (iii) is present at from 0.1 to 15 weight percent.
2. The adjuvant composition of claim 1 wherein:
(a) water-soluble electrolyte (a) is at least one member selected from the group consisting of ammonium sulfate, ammonium nitrate, ammonium phosphate, urea ammonium nitrate and calcium chloride; and,
(b) electrolyte-tolerant surfactant (b) is at least one member selected from the group consisting of alkyl polyglucosides, ethoxylated alkylamines, betaines, N-acyl sarcosinates, N-acyl glutamates, alkyl phosphates, alkylether phosphates and quaternary ammonium surfactants.
3. The adjuvant composition of claim 2 wherein: (c) in antifoam component (c), branched silicone resin (i) is an MQ resin having an M:Q ratio of from 0.1:1 to 1.5:1, silicone fluid (ii) is a polydimethyl silicone fluid and particulate metal oxide (iii) is particulate silica.
4. The adjuvant composition of claim 1 including bioinert material (d), bioinert material (d) being at least one member selected from the group consisting of solvent, wetting agent, dispersant, emulsifier, penetrant, preservative, antifreeze agent, evaporation inhibitor, colorant, pH modifier, buffering agent, thixotropic agent and viscosity modifier.
5. The adjuvant composition of claim 1 wherein:
(a) water-soluble electrolyte (a) is present at from 10 to 50 weight percent;
(b) electrolyte-tolerant, high foaming surfactant (b) is present at from 1 to 20 weight percent; and,
(c) antifoam component (c) is present at from 0.001 to 0.5 weight percent, and in antifoam component (c), branched silicone resin (i) is present at from 5 to 25 weight percent, silicone fluid (ii) is present at from 65 to 94 weight percent and particulate metal oxide (iii) is present at from 1 to 10 weight percent.
6. The adjuvant composition of claim 2 wherein:
(a) water-soluble electrolyte (a) is present at from 10 to 50 weight percent;
(b) electrolyte-tolerant, high foaming surfactant (b) is present at from 1 to 20 weight percent; and,
(c) antifoam component (c) is present at from 0.001 to 0.5 weight percent, and in antifoam component (c), branched silicone resin (i) is present at from 5 to 25 weight percent, silicone fluid is present at from 65-94 weight percent and particulate metal oxide (iii) is present at from 1 to 10 weight percent.
7. The adjuvant composition of claim 3 wherein:
(a) water-soluble electrolyte (a) is present at from 10 to 50 weight percent;
(b) electrolyte-tolerant, high foaming surfactant (b) is present at from 1 to 20 weight percent; and,
(c) antifoam component (c) is present at from 0.001 to 0.5 weight percent, and in antifoam component (c), branched silicone resin (i) is present at from 5 to 25 weight percent, silicone fluid (ii) is present at from 65 to 94 weight percent and particulate metal oxide (iii) is present at from 1 to 10 weight percent.
8. An agricultural formulation comprising the adjuvant composition of claim 1 and (f) at least one agrochemical.
9. The agricultural formulation of claim 8 wherein agrochemical (f) is a water-soluble herbicide.
10. The agricultural formulation of claim 8 wherein agrochemical (f) is at least one member selected from the group consisting of glyphosate, glufosinate, imazapyr, imazethapyr, dicamba, fomesafen and 2,4-dichlorophenoxyacetic acid.
11. An agricultural formulation comprising the adjuvant composition of claim 2 and (f) at least one agrochemical.
12. The agricultural formulation of claim 11 wherein agrochemical (f) is a water-soluble herbicide.
13. The agricultural formulation of claim 11 wherein agrochemical (0 is at least one member selected from the group consisting of glyphosate, glufosinate, imazapyr, imazethapyr, dicamba, fomesafen and 2,4-dichlorophenoxyacetic acid.
14. The adjuvant composition of claim 1 wherein the silicone fluid (ii) comprises a mixture of at least two silicone fluids of different viscosities.
15. The adjuvant composition of claim 1 wherein the metal oxide is pre-hydrophobized.
16. The adjuvant composition of claim 1 comprising a catalyst selected from the group consisting of alkali metal hydroxides, alkali metal silanolates, alkali metal alkoxides, quaternary ammonium hydroxides, quaternary ammonium silanolates, quaternary phosphonium hydroxides, and metal salts of organic acids.
17. The adjuvant composition of claim 1 comprising a catalyst selected from the group consisting of potassium hydroxide, sodium hydroxide, cesium hydroxide, potassium silanolate, potassium ethoxide, betahydroxyethyltrimethyl ammonium hydroxide, benzyltrimethyl ammonium hydroxide, tetramethyl ammonium hydroxide, dibutyltin laurate, stannous acetate and stannous octanoate.
18. The adjuvant composition of claim 1 wherein the surfactant is alkylpolyglucoside.