Antioxidant additive for biodiesel fuels
View Patent ↗A synergistic combination antioxidant mixture that provides excellent characteristics for biodiesel fuel compositions, when incorporated therein.
1. A composition comprising
(a) a biodiesel fuel and
(b) an antioxidizing effective amount of a mixture of
(i) at least one aromatic diamine selected from N,N′-di-isopropyl-p-phenylenediamine; N,N′-di-sec-butyl-p-phenylenediamine; N,N′-bis(1,4-dimethylpentyl)-p-phenylenediamine; N,N′-bis(1-ethyl-3-methylpentyl)-p-phenylenediamine; N,N′-bis(1-methylheptyl)-p-phenylenediamine; N,N′-dicyclohexyl-p-phenylenediamine; N,N′-dioctyl-p-phenylenediamine;
(ii) at least one hindered phenol selected from 2,6-di-tert-butylphenol; 4-methyl-2,6-di-tert-butylphenol; 2,4,6-tri-tert-butylphenol; 2-tert-butylphenol; 2,6-diisopropylphenol; 2-methyl-6-tert-butylphenol; 2,4-dimethyl-6-tert-butylphenol; 4-ethyl-2,6-di-tert-butylphenol; 2-methyl-6-styrylphenol; 2,6-di-styryl-4-nonylphenol; 2-tert-butyl-4,6-dimethylphenol; 2,6-di-tert-butyl-4-ethylphenol; 2,6-di-tert-butyl-4-n-butylphenol; 2,6-di-tert-butyl-4-iso-butylphenol; 2,6-di-cyclopentyl-4-methylphenol; 2-(α-methylcyclohexyl)-4,6-dimethylphenol; 2,6-di-octadecyl-4-methylphenol; 2,4,6-tri-cyclohexylphenol; and
(iii) at least one polyhydroxy phenol of general formula (III)
wherein R is selected from the group consisting of H, alkyl, COOH and COOR 4 wherein R 4 is propyl, octyl or dodecyl;
wherein the mixture of aromatic amine, hindered phenol and polyhydroxy phenol have a ratio of from about 1:4 to about 4:1 by weight of aromatic amine to hindered phenol plus polyhydroxy phenol.
2. The composition according to claim 1 wherein the at least one hindered phenol is selected from 4-methyl-2,6-di-tert-butylphenol; 2,4,6-tri-tertbutylphenol; 2-methyl-6-tert-butylphenol; 2,4-dimethyl-6-tert-butylphenol; 2-tert-butyl-4,6-dimethylphenol; 2,6-di-tert-butyl-4-ethylphenol and 2,6-di-tert-butyl-4-n-butylphenol.
3. The composition of claim 1 wherein the mixture (b) has a ratio of aromatic amine (i) to hindered phenol (ii) plus polyhydroxy phenol (iii) of about 1 to about 1 by weight.
4. The composition of claim 1 wherein the mixture (b) has a ratio of aromatic amine (i) to hindered phenol (ii) plus polyhydroxy phenol (iii) of from about 1:1 to about 4:1 by weight.
5. The composition of claim 2 wherein the mixture (b) has a ratio of aromatic amine (i) to hindered phenol (ii) plus polyhydroxy phenol (iii) of about 1 to about 1 by weight.
6. The composition of claim 1 wherein the mixture (b) has a ratio of aromatic amine (i) to hindered phenol (ii) plus polyhydroxy phenol (iii) of from about 1:1 to about 4:1 by weight.
7. The composition of claim 1 wherein the aromatic diamine of the mixture (b) is a blend of N-(1,4-dimethylbutyl)-N′-phenyl-1,4-phenylenediamine and N-(1,3-dimethylbutyl)-N′-phenyl-1,4 phenylenediamine), and the sterically hindered phenol of the mixture (b) is 2,6-di-tertbutyl-4-methyl phenol.
8. The composition of claim 1 wherein the mixture (b) is present in the biodiesel fuel in an amount of about 1 to about 10,000 ppm.
9. The composition of claim 8 wherein the mixture (b) is present in the biodiesel fuel in an amount from about 50 to about 5,000 ppm.
10. The composition of claim 9 wherein the mixture (b) is present in the biodiesel fuel in an amount from about 100 to about 2,000 ppm.
11. The composition of claim 1 further comprising at least one other component selected from dispersants/detergents, octane improvers, carrier fluids, demulsifiers, antifoam agents, anti-icing additives, biocides, combustion improvers, alkali or alkaline-earth metal detergents, drag reducers, metal deactivators, lubricity additives, dyes, markers, odor masks, odorants and stability improvers.
12. The composition of claim 2 wherein the mixture (b) is present in the biodiesel fuel in an amount of about 1 to about 10,000 ppm.
13. The composition of claim 12 wherein the mixture (b) is present in the biodiesel fuel in an amount from about 50 to about 5,000 ppm.
14. The composition of claim 13 wherein the mixture (b) is present in the biodiesel fuel in an amount from about 100 to about 2,000 ppm.
15. The composition of claim 2 further comprising at least one other component selected from dispersants/detergents, octane improvers, carrier fluids, demulsifiers, antifoam agents, anti-icing additives, biocides, combustion improvers, alkali or alkaline-earth metal detergents, drag reducers, metal deactivators, lubricity additives, dyes, markers, odor masks, odorants and stability improvers.
16. The composition of claim 1 wherein the biodiesel fuel comprises methyl esters of soybean oil, mustard seed oil, rapeseed oil, canola oil or tallow.
17. The composition of claim 2 wherein the biodiesel fuel comprises, methyl esters of soybean oil, mustard seed oil, rapeseed oil, canola oil or tallow.