Process of treating a lignocellulosic material
A process of treating a lignocellulosic material includes a pre-extraction step in which hemicellulose is extracted from the lignocellulosic material. In one embodiment, the pre-extraction step involves contacting the lignocellulosic material with an aqueous solution under conditions that release acidic material from the lignocellulosic material into the aqueous solution, and the aqueous solution includes a basic material that at least partly neutralizes the acidic material so that the aqueous solution at the end of the pre-extraction step has a pH within a range of from 4.5 to 11. The process also includes a pulping step, after the pre-extraction step, in which the lignocellulosic material is separated into pulp. The process further includes an adsorption step, after the pulping step, in which hemicellulose is adsorbed on the pulp.
1. A process of treating a lignocellulosic material comprising:
in a pre-extraction step, extracting hemicellulose from the lignocellulosic material, by contacting the lignocellulosic material with a solution of a basic material in water; then
in a pulping step, separating the lignocellulosic material into pulp; then
in an adsorption step, adsorbing the hemicellulose on the pulp; then
recovering a sugar rich extract following the adsorption step; and then
subjecting the pulp to a delignification process to remove lignin from the pulp
wherein the adsorbed hemicellulose increases the selectivity of the delignification process at least about 10% compared to the same process without the hemicellulose pre-extraction and adsorption steps.
2. The process of claim 1 wherein the selectivity of the delignification process is increased at least about 20%.
3. The process of claim 1 wherein the pre-extraction step achieves the extraction of at least about 15% of the hemicellulose from the lignocellulosic material as measured on a dry material weight basis.
4. The process of claim 1 wherein the delignification process is an oxygen delignification process.
5. The process of claim 1 wherein the lignocellulosic material is wood.
6. The process of claim 1 wherein the pulping step comprises cooking the lignocellulosic material in a pulping liquor containing an alkali material to separate the lignocellulosic material into pulp, and wherein the effective alkali charge as Na2O during the cooking is 12% to 13%.
7. The process of claim 6 wherein the effective alkali charge as Na2O during the cooking is 12%.
8. The process of claim 1 wherein the pulping step comprises cooking the lignocellulosic material in a pulping liquor containing an alkali material to separate the lignocellulosic material into pulp, and wherein the total pulp yield after the pre-extraction and pulping steps is higher than the yield of the same process without the pre-extraction step.
9. The process of claim 8 wherein the basic material used in the pre-extraction step comprises alkali metal carbonate.
10. The process of claim 8 wherein the basic material used in the pre-extraction step comprises alkali metal borate.
11. The process of claim 8 wherein the total pulp yield is about 1% higher.
12. The process of claim 8 wherein the lignocellulosic material is wood.
13. The process of claim 1 wherein in the adsorption step, the hemicellulose is adsorbed on the pulp for a time of at least 5 minutes before the subsequent delignification process.
14. The process of claim 13 wherein in the adsorption step, the hemicellulose is adsorbed on the pulp for a time of from 10 minutes to 100 minutes before the subsequent delignification process.