Methods of forming at least a portion of earth-boring tools
View Patent ↗Methods of forming at least a portion of an earth-boring tool include providing particulate matter comprising a hard material in a mold cavity, melting a metal and the hard material to form a molten composition comprising a eutectic or near-eutectic composition of the metal and the hard material, casting the molten composition to form the at least a portion of an earth-boring tool within the mold cavity, and adjusting a stoichiometry of at least one hard material phase of the at least a portion of the earth-boring tool. Methods of forming a roller cone of an earth-boring rotary drill bit include forming a molten composition, casting the molten composition within a mold cavity, solidifying the molten composition to form the roller cone, and converting an eta-phase region within the roller cone to at least one of WC and W 2 C.
1. A method of forming at least a portion of an earth-boring tool, comprising:
providing particulate matter comprising a hard material in a mold cavity;
melting a metal and the hard material to form a molten composition comprising a eutectic or near-eutectic composition of the metal and the hard material;
casting the molten composition to form the at least a portion of an earth-boring tool within the mold cavity; and
adjusting a stoichiometry of at least one hard material phase of the at least a portion of the earth-boring tool.
2. The method of claim 1 , wherein adjusting a stoichiometry of at least one hard material phase of the at least a portion of the earth-boring tool comprises converting at least one of an M 6 C phase and an M 12 C phase to at least one of an MC phase and an M 2 C phase, wherein M is at least one metal element and C is carbon.
3. The method of claim 2 , wherein converting at least one of an M 6 C phase and an M 12 C phase to at least one of an MC phase and an M 2 C phase comprises converting W x Co y C to WC, wherein x is from about 0.5 to about 6 and y is from about 0.5 to about 6.
4. The method of claim 1 , wherein melting a metal and a hard material to form a molten composition comprises melting a mixture comprising from about 40% and about 90% cobalt or cobalt-based alloy by weight and from about 0.5% to about 3.8% carbon by weight, wherein a balance of the mixture is at least substantially comprised of tungsten.
5. The method of claim 1 , wherein melting a metal and a hard material to form a molten composition comprises melting a mixture comprising from about 55% to about 85% cobalt or cobalt-based alloy by weight and from about 0.85% to about 3.0% carbon by weight, wherein a balance of the mixture is at least substantially comprised of tungsten.
6. The method of claim 1 , wherein melting a metal and a hard material to form a molten composition comprises melting a mixture comprising from about 65% to about 78% cobalt or cobalt-based alloy by weight and from about 1.3% to about 2.35% carbon by weight, wherein a balance of the mixture is at least substantially comprised of tungsten.
7. The method of claim 1 , wherein melting a metal and a hard material to form a molten composition comprises melting a mixture comprising about 69% cobalt or cobalt-based alloy by weight, about 1.9% carbon by weight, and about 29.1% tungsten by weight.
8. The method of claim 7 , wherein melting a metal and a hard material to form a molten composition comprises melting about 75% cobalt or cobalt-based alloy by weight, about 1.53% carbon by weight, and about 23.47% tungsten by weight.
9. The method of claim 1 , further comprising pressing the at least a portion of the earth-boring tool after casting the molten composition to form the at least a portion of the earth-boring tool within the mold cavity.
10. The method of claim 1 , further comprising treating at least a surface region of the at least a portion of the earth-boring tool to provide residual compressive stresses within the at least a surface region of the at least a portion of the earth-boring tool.
11. The method of claim 10 , wherein treating at least a surface region of the at least a portion of the earth-boring tool comprises subjecting the at least a surface region of the at least a portion of the earth-boring tool to a peening process.
12. A method of forming a roller cone of an earth-boring rotary drill bit, comprising:
forming a molten composition comprising a eutectic or near-eutectic composition of cobalt and tungsten carbide;
casting the molten composition within a mold cavity;
solidifying the molten composition within the mold cavity to form the roller cone; and
converting an eta-phase region within the roller cone to at least one of WC and W 2 C.
13. The method of claim 12 , wherein forming a molten composition comprises forming a molten composition comprising about 69% cobalt or cobalt-based alloy by weight, about 1.9% carbon by weight, and about 29.1% tungsten by weight.
14. The method of claim 12 , further comprising pressing the roller cone after casting the molten composition within the mold cavity.
15. The method of claim 12 , further comprising treating at least a surface region of the roller cone to provide residual compressive stresses within the at least a surface region of the roller cone.
16. The method of claim 15 , wherein treating at least a surface region of the roller cone comprises subjecting the at least the surface region of the roller cone to a peening process.