Nanoparticle separation methods and compositions
Methods of separating one type of nanoparticle from another type of nanoparticle in a mixture including more than one type of nanoparticle are disclosed. The methods may include suspending a mixture of the various types of nanoparticles in a liquid and modifying a characteristic of the liquid. Thereafter, a force may be applied to the nanoparticles within the mixture causing one type of nanoparticles to separate from another type of nanoparticles. The applied force may be the force of gravity, or it may be an induced force such as a centrifugal force applied with a centrifuge or similar apparatus. Upon the occurrence physical separation, sub-populations of nanoparticles may be removed from the suspension or segregated. Alternatively the methods may include modifying a type of nanoparticle in suspension. Alternative embodiments include nanoparticles modified in suspension to provide for separation from other types of nanoparticles.
1. A method of separating a mixture of more than one type of nanoparticle according to nanoparticle type, the method comprising:
suspending the mixture of more than one type of nanoparticle in a suspension liquid having a viscosity;
modifying the viscosity of the suspension liquid by adding a second liquid having a different viscosity to the suspension liquid to create a modified suspension liquid;
applying a force to the mixture of more than one type of nanoparticle suspended in the modified suspension liquid, causing physical separation of the nanoparticles by type; and
removing a selected portion of the separated nanoparticles from the modified suspension liquid.
2. The method of separating a mixture of more than one type of nanoparticle according to nanoparticle type of claim 1 further comprising modifying the temperature of the suspension liquid.
3. The method of separating a mixture of more than one type of nanoparticle according to nanoparticle type of claim 1 further comprising modifying the pressurization of the suspension liquid.
4. The method of separating a mixture of more than one type of nanoparticle according to nanoparticle type of claim 3 wherein the suspension liquid is water.
5. The method of separating a mixture of more than one type of nanoparticle according to nanoparticle type of claim 1 wherein the suspension liquid is selected to not contaminate one or more of the nanoparticle types.
6. The method of separating a mixture of more than one type of nanoparticle according to nanoparticle type of claim 1 further comprising utilizing a first portion of the separated nanoparticles as a taggant and recycling a second portion of the separated nanoparticles.