Process for the manufacture of P
View Patent ↗The invention relates to a process for the production of P 4 O 6 of high purity by reacting oxygen, or a mixture of oxygen and an inert gas, with gaseous or liquid phosphorus to generate said reaction product in a reaction unit. The reaction product is kept in the reaction unit at an average temperature in the range of 1600 and 2000 K by removing the heat created by the exothermic reaction of phosphorus and oxygen. A residence time of at least 1 second of the reaction product passing the reaction unit is maintained. The reaction product is then conventionally cooled in a quenching unit connected with the reaction unit. The final reaction product contains P 4 O 6 with a very low content of elemental phosphorus.
1. A process for the production of P 4 O 6 by reacting oxygen, or a mixture of oxygen and an inert gas, with gaseous or liquid phosphorus in a molar ratio of phosphorus (P 4 ) to oxygen (O 2 ) of 1:2.7 to 1:3.3 to generate the reaction product in a reaction unit, keeping the obtained reaction product in said reaction unit at an average temperature in the range of 1600 and 2000 K by removing the heat created by the exothermic reaction of phosphorus and oxygen, and maintaining a residence time of at least 1 second of the reaction product passing the reaction unit, then forwarding the reaction product to one or more quenching unit(s) where it is quenched to a temperature of below 700 K where no essential decomposition of the reaction product occurs.
2. The process according to claim 1 , wherein the reaction product comprises 85 to 95% by weight of P 4 O 6 and byproducts.
3. The process according to claim 1 , wherein the residence time takes between 1 and 60 seconds.
4. The process according to claim 1 , wherein the residence time is at least 8 seconds.
5. The process according to claim 1 , wherein the residence time is maintained by adjusting the volumetric flow rate of the reaction product which passes the reaction unit to the volume of the reaction unit.
6. The process according to claim 1 , wherein the temperature of the reaction product in the reaction unit is maintained at a temperature between 1650 to 1850 K.
7. The process according to claim 1 , wherein the reaction product is quenched to a temperature below 350K.
8. The process according to claim 1 , wherein the quenching is performed by adding liquid reaction product or liquid P.sub.4O.sub.6 as a coolant to the reaction product to be quenched.
9. The process according to claim 2 , wherein the byproducts are unwanted phosphorus oxides that are removed by means of a further step of distillation.
10. The process according to claim 9 , wherein the purified reaction product comprises more than 99% by weight of P 4 O 6 .