Grease composition
View Patent ↗A grease composition for use in resin lubrication wherein at least one amine salt of an unsaturated or saturated fatty acid is incorporated in a grease base material which includes a base oil and a thickener, preferably wherein at least one fatty acid amine salt of the following general formula (1) is incorporated: RCOO − R′ NH 3 + wherein either (i) R is an unsaturated hydrocarbon group having from 15 to 21 carbon atoms, and R′ is a saturated or unsaturated linear or branched hydrocarbon group having from 8 to 22 carbon atoms; or (ii) R is a linear saturated hydrocarbon group having from 5 to 21 carbon atoms, and R′ is an unsaturated hydrocarbon group having from 16 to 18 carbon atoms. The grease composition of the present invention improves the lubricity between resin and resin or resin. and another material such as a metal.
1. A grease composition comprising:
a base oil;
a thickener; and
an unsaturated or saturated fatty acid amine salt having the general formula (1):
RCOO − R′NH 3 + (1)
wherein either (i) R is an unsaturated hydrocarbon group having from 15 to 21 carbon atoms, and R′ is a saturated or unsaturated linear or branched hydrocarbon group having from 8 to 22 carbon atoms;
or (ii) R is a linear saturated hydrocarbon group having from 5 to 21 carbon atoms, and R′ is an unsaturated hydrocarbon group having from 16 to 18 carbon atoms;
wherein the total amount of the unsaturated or saturated fatty acid amine salt is in the range of from 1 to 5% by mass relative to the total amount of the grease composition.
2. A grease composition according to claim 1 , wherein the base oil is selected from mineral oils, synthetic oils, animal and plant oils, and mixtures thereof.
3. A grease composition according to claim 2 , wherein the thickener is selected from the group consisting of lithium salts, lithium 12 hydroxy soaps, calcium soaps, sodium soaps, barium soaps, barium complex soaps, calcium complex soaps, aluminium complex soaps, lithium complex soaps, bentone, clay, silica, tricalcium phosphate, calcium sulphonate complexes, polyureas, sodium terephthalamate, and mixtures thereof.
4. A grease composition according to claim 3 , wherein the unsaturated fatty acid is selected from the group consisting of palmitoylic acid, oleic acid, vaccenic acid, linolic acid, linolenic acid, elaeostearic acid, eicosadienic acid, eicosatrienic acid, arichidonic acid and erucic acid.
5. A grease composition according to claim 3 , wherein the saturated fatty acid is selected from the group consisting of caproic acid, caprylic acid, pelargonic acid, capric acid, lauric acid, linderic acid, myristic acid, tsuzuic acid, physetoleic acid, myristoleic acid, pentadecylic acid, palmitic acid, margaric acid, stearic acid, petroselinic acid, elaidic acid, tuberculostearic acid, arachidinic acid and behenic acid.
6. A grease composition according to claim 5 , further comprising an additive selected from the group consisting of anti-oxidants, rust inhibitors, oiliness agents, extreme pressure agents, anti-wear agents, solid lubricants, metal deactivators, polymers and mixtures thereof.