Curable composition and cured product thereof
View Patent ↗The present invention provides a curable composition mainly comprising an organic polymer containing a reactive silyl group, which is free from toxic organotin catalysts so as to be environmentally friendly and maintains good surface properties after being cured. The curable composition of the present invention comprises: (A) an organic polymer having a silyl group cross-linkable by siloxane bond formation; (B) a carboxylic acid and/or a carboxylate metal salt; (C) an amine compound; and (D) a phosphorus compound having an aryl group and a melting point of 23° C. or higher.
1. A curable composition comprising:
(A) an organic polymer having a reactive silyl group;
(B) a carboxylic acid and/or a carboxylate metal salt;
(C) an amine compound having two or more amino groups and no reactive silyl group; and
(D) a phosphorus compound having an aryl group and a melting point of 23° C. or higher.
2. The curable composition according to claim 1 ,
wherein an amount of an organotin compound is less than 0.02% by weight of the composition.
3. The curable composition according to claim 1 ,
wherein the phosphorous compound (D) has two or more aryl groups.
4. The curable composition according to claim 1 ,
wherein the phosphorous compound (D) has an aryl group to which a t-butyl group is bonded.
5. The curable composition according to claim 1 ,
wherein the phosphorus compound (D) contains a phosphorus atom having an oxidation number of +3 or +5.
6. The curable composition according to claim 1 ,
wherein the organic polymer (A) has, as a chain skeleton, at least one polymer selected from the group consisting of a polyoxyalkylene polymer, a saturated hydrocarbon polymer, and a (meth)acrylate ester polymer.
7. The curable composition according to claim 6 ,
wherein the polyoxyalkylene polymer is a polyoxypropylene polymer.
8. The curable composition according to claim 1 ,
wherein the organic polymer (A) has a chain skeleton containing a group represented by the formula (1):
—NR 1 —C(═O)— (1)
wherein R 1 is a hydrogen atom or a substituted or unsubstituted organic group.
9. The curable composition according claim 1 ,
wherein the organic polymer (A) is a mixture of a polyoxyalkylene polymer and a (meth)acrylate ester polymer.
10. The curable composition according to claim 1 ,
wherein the component (B) is (B-1) a carboxylic acid including a quaternary carbon atom adjacent to a carbonyl group; and/or
(B-2) a carboxylate metal salt including a quaternary carbon atom adjacent to a carbonyl group.
11. The curable composition according to claim 10 ,
wherein the carboxylate metal salt (B-2) including a quaternary carbon atom adjacent to a carbonyl group is a tin carboxylate.
12. The curable composition according to claim 1 ,
wherein the amine compound (C) is a diamine.
13. The curable composition according to claim 1 ,
wherein the amine compound (C) has one primary amino group and one tertiary amino group in one molecule.
14. A one-pack sealant, which comprises the curable composition according to claim 1 .
15. A one-pack adhesive, which comprises the curable composition according to claim 1 .
16. A one-pack floor finishing adhesive, which comprises the curable composition according to claim 1 .
17. A cured product, which is produced by curing the curable composition according to claim 1 .