IP Library Granted Patent US 8,742,163
Granted Patent B2
US 8,742,163 · App. 13/122,810 · Granted Jun 3, 2014

Method for producing methacrylated benzophenones

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Quick Facts
Patent No.
US 8,742,163
App. No.
13/122,810
Granted
Jun 3, 2014
Kind
B2
Abstract

The invention relates to a method for producing methacrylated benzophenones and to the uses thereof.

Claims (7)

1. Process for preparing benzophenone (meth)acrylates, comprising reacting hydroxybenzophenones and (meth)acrylic anhydride in the presence of catalytic amounts of acid, neutralizing said catalyst, and subsequently purifying a crude monomer

wherein said acid is at least one acid selected from the group consisting of concentrated sulphuric acid, of an alkylsulphonic acid and an arylsulphonic acid.

2. Process according to claim 1 , wherein 4-hydroxybenzophenone and (meth)acrylic anhydride are reacted in the presence of catalytic amounts of acid, which are then neutralized with aqueous bases, and subsequently the soluble impurities in a [(meth)acryloyloxy]benzophenone melt are dissolved by addition of water.

3. Process according to claim 1 , wherein neutralization is carried out with at least one base selected from the group consisting of aqueous alkali metal hydroxide solution or ammonia solution.

4. Process according to claim 1 , wherein said reaction takes place over 4-8 hours at 50 to 120° C.

5. Process according to claim 1 , further comprising precipitating a [(meth)acryloyloxy]benzophenone by addition of excess water to the reaction mixture and isolating in solid form by filtration.

6. Process according to claim 1 , further comprising adding a liquid (meth)acrylic ester or styrene into the reaction mixture to form a solution.

Assignments (5)
CHANGE OF NAME Recorded Mar 20, 2020
From: EVONIK RÖHM GMBH
To: RÖHM GMBH
Reel/Frame 052194/0462 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 20, 2020
From: RÖHM GMBH
To: EVONIK OIL ADDITIVES GMBH
Reel/Frame 052194/0550 →
MERGER Recorded Mar 20, 2020
From: EVONIK OIL ADDITIVES GMBH
To: EVONIK DEGUSSA GMBH
Reel/Frame 052195/0001 →
CHANGE OF NAME Recorded Mar 20, 2020
From: EVONIK DEGUSSA GMBH
To: EVONIK OPERATIONS GMBH
Reel/Frame 052195/0226 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2011
From: KNEBEL, JOACHIM; KLESSE, WOLFGANG; BREINER, CHRISTINE MARIA; SCHMITT, GEROLD
To: EVONIK ROEHM GMBH
Reel/Frame 026095/0799 →