Transparent adhesive sheet and image display device
View Patent ↗Provided is a novel transparent adhesive sheet with which the cut edge is not sticky over time when a laminated body that has been bonded via the adhesive sheet is cut, which can be adhered without generating residual air bubbles, even when the surface of an adherend is uneven, and which can be adhered without foaming, even when the adherend is a material such as plastic that can generate outgas. Suggested is an adhesive sheet that has one or more layers of a first adhesive layer and one or more layer of a second adhesive layer that exhibit different viscoelastic behaviors, and has an integrated structure whereby these layers are laminated, with a dynamic shear storage modulus G′ of 2×10 4 to 5×10 5 Pa for G′(20° C.) and 1×10 4 to 1×10 5 Pa for G′(150° C.) when measured with a 1 Hz frequency temperature dispersion.
1. A laminate, comprising:
a protective panel body;
a transparent adhesive sheet laminated on to a back surface of the protective panel body; and
a touch panel laminated on to a back surface of the transparent adhesive sheet;
wherein:
the protective panel body has a thickness of greater than 0.8 mm;
the protective panel body comprises glass;
the transparent adhesive sheet comprises:
one or more layers of a first adhesive layer; and
one or more layers of a second adhesive layer;
the first adhesive layer and the second adhesive layer are arranged so that no outgas barrier layer is provided between the first adhesive layer and the second adhesive layer;
the first and second adhesive layers exhibit different viscoelastic behaviors;
the first and second adhesive layers are integrally laminated;
either the first adhesive layer or the second adhesive layer comprises a composition comprising an acrylic acid ester polymer, a multifunctional (meth)acrylate cross-linking agent having more than two(meth) acryloyl groups and a reaction initiator; and
a dynamic shear storage modulus G′ of the transparent adhesive sheet is within the ranges below when measured with a 1 Hz frequency temperature dispersion:
G′(20° C.) is 2×10 4 to 5×10 5 Pa; and
G′(150° C.) is 1×10 4 to 1×10 5 Pa.
2. The laminate according to claim 1 , wherein:
the second adhesive layer is laminated on to the back surface of the protective panel body; and
a dynamic shear storage modulus G′ of the first adhesive layer is within the ranges below when measured with a 1 Hz frequency temperature dispersion:
G′(20° C.) is 2×10 4 to 5×10 5 Pa; and
G′(150° C.) is 1×10 4 to 1×10 5 Pa.
3. The laminate according to claim 1 , wherein:
dynamic shear storage moduli G′ of the first adhesive layer and the second adhesive layer are within the ranges below when measured with a 1 Hz frequency temperature dispersion:
G′(20° C.) of the first adhesive layer is 2×10 4 to 5×10 5 Pa;
G′(150° C.) of the first adhesive layer is 1×10 4 to 1×10 5 Pa;
G′(20° C.) of the second adhesive layer is 2×10 5 to 5×10 6 Pa; and
G′(150° C.) of the second adhesive layer is 5×10 4 to 5×10 5 Pa.
4. The laminate according to claim 2 , wherein:
dynamic shear storage moduli G′ of the first adhesive layer and the second adhesive layer are within the ranges below when measured with a 1 Hz frequency temperature dispersion:
G′(20° C.) of the first adhesive layer is 2×10 4 to 5×10 5 Pa;
G′(150° C.) of the first adhesive layer is 1×10 4 to 1×10 5 Pa;
G′(20° C.) of the second adhesive layer is 2×10 5 to 5×10 6 Pa; and
G′(150° C.) of the second adhesive layer is 5×10 4 to 5×10 5 Pa.
5. The laminate according to claim 1 , wherein the protective panel body has a print unevenness on the back surface.
6. The laminate according to claim 1 , wherein at least one of the one or more layers of the first adhesive layer is in contact with at least one of the one or more layers of the second adhesive layer.
7. The laminate according to claim 1 , wherein:
the first adhesive layer comprises a composition comprising an acrylic acid ester polymer having a glass transition temperature of less than −10° C., a multifunctional (meth)acrylate cross-linking agent having more than two(meth) acryloyl groups, and a cross-linking initiator; and
the second adhesive layer comprises a composition comprising an acrylic acid ester polymer having a glass transition temperature of at least −10° C., a multifunctional (meth)acrylate cross-linking agent having more than two(meth) acryloyl groups, and a cross-linking initiator.