Solid oxide fuel cell or solid oxide fuel cell sub-component and methods of preparing same
View Patent ↗A solid oxide fuel cell (SOFC) or SOFC sub-component comprising a YSZ solid oxide electrolyte layer ( 10 ), a LSCF cathode layer ( 14 ) and a mixed phase layer ( 18 ) comprising at least zirconia and ceria between the electrolyte layer and the cathode layer, with the cathode layer in direct contact with the mixed phase layer, that is with no ceria, other than in the mixed phase layer, between the cathode layer and the electrolyte layer. One method of forming the SOFC or sub-component comprises applying a layer of ceria on the electrolyte layer ( 10 ), heating the electrolyte and ceria layers to form the mixed phase layer ( 18 ), and removing excess ceria from the surface of the mixed phase layer before applying the cathode layer ( 14 ).
1. A method of preparing a solid oxide fuel cell sub-component comprising a layer of YSZ solid oxide electrolyte material having a first side suitable for
receiving a cathode material thereon and a second side opposite the first side, the method comprising the steps of:
providing a layer of ceria on the first side of the layer of electrolyte material;
heating the electrolyte material having the ceria thereon at a temperature in the range of 1150° C. to 1450° C. to form a mixed phase layer comprising a mixed phase of at least zirconia and ceria on the first side of the layer of electrolyte material and excess ceria on the mixed phase layer; and
removing the excess ceria.
2. A method according to claim 1 , wherein the heating is performed concurrently with the layer of ceria being applied to the first side of the electrolyte material.
3. A method according to claim 1 , wherein the heating is performed subsequent to the layer of ceria being applied to the first side of the electrolyte material.
4. A method according to claim 1 , wherein the heating to form the mixed phase layer is to a temperature of at least about 1400° C.
5. A method according to claim 1 , wherein the layer of electrolyte material has a layer of anode material on the second side thereof.
6. A method according to claim 5 , wherein the heating to form the mixed phase layer is at a temperature in the range of about 1300° C. to 1450° C.
7. A method according to claim 1 , wherein removing the excess ceria comprises mechanically scraping or abrading the surface of the mixed phase layer.
8. A method according to claim 1 , wherein the method further comprises, after removing the excess ceria, the step of depositing a layer of cathode material onto the mixed phase layer to form a solid oxide fuel cell or solid oxide fuel cell sub-component in which the cathode material is in direct contact with the mixed phase layer.
9. A solid oxide fuel cell or solid oxide fuel cell sub-component comprising a YSZ solid oxide electrolyte layer and a cathode layer, wherein:
the electrolyte layer has a first side and second side opposite the first side;
a mixed phase layer comprising a mixed phase of at least zirconia and ceria formed by heating a layer of free ceria on the first side of the electrolyte is provided on the first side of the electrolyte layer; and
the cathode layer is provided on and in direct contact with the mixed phase layer with no free ceria therebetween;
and wherein the proportion of Zr in the mixed phase layer decreases through the thickness of the mixed phase layer from the electrolyte layer to a surface of the mixed phase layer remote from the electrolyte layer.
10. A solid oxide fuel cell or solid oxide fuel cell sub-component according to claim 9 , wherein the thickness of the mixed phase layer is in the range of about 1 to about 5 μm.
11. A solid oxide fuel cell or solid oxide fuel cell sub-component according to claim 9 , wherein a mole fraction of zirconium at a surface of the mixed phase layer remote from the electrolyte layer is in the range of from about 0 to about 0.26.
12. A solid oxide fuel cell or solid oxide fuel cell sub-component according to claim 9 , wherein a mole ratio of Zr:Ce in the mixed phase layer is in the range of from about 0.3:1 to about 0.55:1 at a depth from a surface of the mixed phase layer remote from the electrolyte layer of from about 0.05 to about 0.2 μm.
13. A solid oxide fuel cell or solid oxide fuel cell sub-component according to claim 9 , wherein a mole ratio of Zr:Ce in the mixed phase layer is in the range of from about 2:1 to about 3:1 at a depth from a surface of the mixed phase layer remote from the electrolyte layer of from about 0.7 to about 0.9 μm.
14. A solid oxide fuel cell or solid oxide fuel cell sub-component according to claim 9 , wherein the ceria in the mixed phase layer is doped with one or more of Y, Sm, Gd, Nd, Pr, La and Tb.