Organic photoelectric conversion element and organic photoelectric conversion element manufacturing method
View Patent ↗Provided is an organic photoelectric conversion element having a high photoelectric conversion ratio. Provided is also a method for manufacturing an organic photoelectric conversion element which can significantly reduce the manufacturing cost by forming a transparent electrode and an organic generation layer portion by coating a material. The organic photoelectric conversion element includes on a transparent substrate, a first electrode unit having a transparent conductive layer, an organic generation unit, and a second electrode unit which are successively arranged in this order when viewed from the transparent substrate. The transparent conductive layer constituting the first electrode unit contains conductive fiber and transparent conductive material.
1. An organic photoelectric conversion element comprising a transparent substrate, a first electrode unit, an organic power generation layer unit, and a second electrode unit; the first electrode unit, the organic power generation layer unit, and the second electrode unit are successively arranged on the transparent substrate with the first electrode unit nearest to the transparent substrate; wherein the first electrode unit comprises at least two layers each containing a metal nanowire and a transparent electro-conductive material, and among the at least two layers containing a metal nanowire in the first electrode unit, the layer located nearest the transparent substrate has an average haze value of EH1, and the layer located nearest the organic power generation layer unit has an average haze value of EH2, wherein the average haze values satisfy the relationship of EH1 <EH2.
2. The organic photoelectric conversion element of claim 1 ,
wherein the first electrode unit comprises a first transparent resin component, and a second transparent resin component which has a higher refractive index than the first electrode unit comprising two regions wherein the first transparent resin component is contained with a higher content in the region nearest the transparent substrate; and the second transparent resin component and the metal nanowire are contained with a higher content in the region nearest the organic power generation layer unit.
3. The organic photoelectric conversion element of claim 2 ,
wherein the second transparent resin component is a transparent conductive polymer.
4. The organic photoelectric conversion element of claim 1 ,
wherein the first electrode unit comprises a first transparent resin component, and a transparent inorganic component which has a higher refractive index than the first transparent resin component; the first electrode unit comprising two regions wherein the first transparent resin component is contained with a higher content in the region nearest the transparent substrate; and the transparent inorganic component and the metal nanowire are contained with a higher content in the region nearest the organic power generation layer unit.
5. The organic photoelectric conversion element of claim 4 ,
wherein the transparent inorganic component is a transparent conductive metal oxide.
6. The organic photoelectric conversion element of claim 2 ,
wherein a particle co-exists in a region where the first transparent resin component is located.
7. The organic photoelectric conversion element of claim 1 ,
wherein the second electrode unit contains a metal compound as a constituting component of the second electrode unit.