Coloring and perming compositions for hair
View Patent ↗The present invention is related to an aqueous composition comprising an alkalizing agent and a cationic polymer. The inventors of the present invention have surprisingly found out that a composition comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride colors and/or permanently shapes hair excellently and improves hair shine, combability and manageability and especially hair treated with such composition has less flyaway. Additionally it has been observed that hair colored and/or permanently shaped more homogeneously from root to tips. The object of the present invention is a composition for hair comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride. Cationic charge density of the polymer is preferably between 3 and 4 mEq/g and particularly 3.7 mEq/g at pH 7.0.
1. An aqueous composition for hair wherein it comprises at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride.
2. The composition according to claim 1 wherein cationic polymer is Polyquaternium-87 and it has a cationic charge density of between 3 and 4 meq/g at pH 7.0.
3. The composition according to claim 1 , wherein at least one alkalizing agent is selected from compounds according to general structure
R 1 R 2 R 3 N
wherein R 1 , R 2 and R 3 are the same or different H, straight or branched C 1 to C 6 alkyl, straight or branched C 1 to C 6 monohydroxy alkyl, straight or branched C 2 to C 6 polyhydroxyalkyl, ammonium carbonate and salts thereof, at a total concentration of 0.1 to 30% by weight calculated to total composition prior to mixing with any other composition.
4. The composition according to claim 1 , comprising at least two alkalizing agents, wherein the first alkalizing agent is at least one compound selected from ammonia, ammonium hydroxide, ammonium carbonate and salts thereof and the second alkalizing agent is selected from compounds according to the general formula above wherein at least one of the R 1 , R 2 and R 3 is not H.
5. The composition according to claim 1 , further comprising at least one oxidative dye precursor, optionally at least one coupling compound.
6. The composition according to claim 1 , further comprising at least one direct dye selected from cationic, anionic and nitro dyes.
7. The composition according to claim 1 , further comprising at least one reducing agent.
8. The composition according to claim 1 , further comprising at least one surfactant selected from non-ionic, cationic, anionic and amphoteric surfactants.
9. The composition according to claim 1 , further comprising at least one conditioning agent, preferably selected from compounds according to general formula
where R 4 is a saturated or unsaturated, branched or non-branched alkyl chain with 8-24 C atoms or
R 8 CONH(CH 2 ) n
where R 8 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0-4 or
R 9 COO(CH 2 ) n
where R 9 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0-4, and
R 5 is a hydrogen, saturated or unsaturated, branched or non-branched alkyl chain with 1-24 C atoms or
R 8 CONH(CH 2 ) n
where R 8 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0-4 or
R 9 COO(CH 2 ) n
where R 9 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0-4, and R 6 and R 7 are independent from each other H or lower alkyl chain with 1 to 4 carbon atoms which may be substituted with one or two hydroxyl groups or ethoxy or propoxy group with number of ethoxy or propoxy groups varying in the range of 0 to 4, and X is chloride, bromide or methosulfate, oils, oily substances, cationic polymers and non-ionic compounds.
10. The composition according to claim 6 , further comprising at least one fatty alcohol.
11. The composition according to claim 1 , further comprising one or more organic solvent(s).
12. The composition according to claim 1 , further comprising at least one compound according to the formula
where n is a number from 1 to 10 and/or at least one UV filter.
13. The composition according to claim 1 , further comprising at least one compound selected from protein hydrolysates, polypeptides, natural plant extracts, ceramides and/or pseudoceramides, phytosterols, and fatty acids.
14. The composition according to claim 1 , wherein it has a pH between 2 and 11.
15. A process for colouring hair, comprising the steps of
(a) applying onto hair an aqueous composition comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride, and
(b) after processing at a temperature in the range of 20 to 40° C. for 5 to 45 min, rising the composition off from hair.
16. The process according to claim 15 , wherein the aqueous composition further comprises at least one direct dye selected from cationic, anionic and nitro dyes.
17. The process according to claim 16 , further comprising the step of, prior to step (a), mixing with the aqueous composition with a second composition comprising at least one oxidizing agent.
18. The process according to claim 15 , wherein the aqueous composition further comprises at least one oxidative dye precursor and optionally at least one coupling compound, and further comprising the step of, prior to step (a), mixing the aqueous composition with an acidic composition comprising at least one oxidizing agent.
19. A process for permanent shaping of hair, comprising the steps of:
applying an aqueous composition onto shampooed and towel dried hair which is wound on curlers, the aqueous composition comprising at least one alkalizing agent and a cationic polymer consisting of a copolymer of vinylpyrrolidone and vinylimidazole and a homopolymer of dimethyl dially ammonium chloride, and at least one reducing agent, and
after processing of 1 to 25 min at a temperature in the range of 20 to 45° C., rinsing off the aqueous composition from hair, and
optionally treating the hair with an acidic composition and, without rinsing, a second composition comprising at least one oxidizing agent is applied onto hair and curlers are removed from hair, and hair is optionally rinsed off after processing of 1 to 15 min at room temperature.