Fusible bicomponent spandex
Included are multiple component elastic fibers prepared by a solution-spinning process such as dry spinning or wet spinner of spandex fibers including polyurethaneurea and polyurethane compositions. These fibers have a cross-section including at least two separate regions with definable boundaries wherein at least one region defined by the boundaries of the cross-section includes a polyurethaneurea or polyurethane composition. One region of the fiber includes a fusibility improvement additive to enhance adhesion to itself or to a substrate.
1. A fiber comprising an elastic, multiple component fiber having discernable regions in a sheath-core configuration along a cross-section, said fiber spun from first and second polymer solutions , wherein at least a first region of said cross-section is the core spun from a first polymer solution comprising an elastomeric polyurethaneurea with a melting point greater than 240° C.; and including a second region said second region being the sheath spun from a second polymer solution comprising an elastomeric polyurethane, or a polyurethaneurea, or a mixture thereof with a melting point of 190-250° C. and at least one fusibility improvement additive, wherein said first and second regions have different compositions and are continuous along the fiber length; wherein said fusibility improvement additive includes at least one low temperature melting polyurethane with melting point less than 180° C.; and wherein said fiber exhibits a tenacity at break of at least 1 cN/dtex, a break elongation of at least 400%, an M200 of at least 0.2 cN/dtex and increased steam efficiency and fusing strength and decreased laddering after puncture as compared to a fiber prepared from a first polymer solution comprising an elastomeric polyurethaneurea with a melting point greater than 240° C.
2. The fiber of claim 1 , wherein the fiber includes a monofilament structure or a multiple filament structure.
3. The fiber of claim 1 , wherein said low temperature melting polyurethane has a melting point from about 50° C. to about 150° C.
4. The fiber of claim 1 , wherein said low temperature melting polyurethane has a melting point below about 120° C.
5. The fiber of claim 1 , wherein said second region is adjacent to or at least partially surrounds the first region.
6. The fiber of claim 5 , wherein the second region comprises about 11% to about 60% by weight of the fiber.
7. The fiber of claim 5 , wherein the second region comprises about 5% to about 30% by weight of the fiber.
8. The fiber of claim 1 , wherein said elastic multiple component solution-spun fiber has a fusing strength greater than 0.15 cN/dtex.
9. A fabric comprising an elastic, multiple component, fiber having discernable regions in a sheath-core configuration along a cross-section, said fiber spun from first and second polymer solutions , wherein at least a first region of said cross-section is the core spun from a first polymer solution comprising an elastomeric polyurethaneurea with a melting point greater than 240° C.; and including a second region said second region being the sheath spun from a second polymer solution comprising an elastomeric polyurethane, or a polyurethaneurea, or a mixture thereof with a melting point of 190-250° C. and at least one fusibility improvement additive, wherein said first and second regions have different compositions and are continuous along the fiber length; wherein said fusibility improvement additive includes at least one low temperature melting polyurethane with melting point less than 180° C.; and wherein said fiber exhibits a tenacity at break of at least 1 cN/dtex, a break elongation of at least 400%, an M200 of at least 0.2 cN/dtex and increased steam efficiency and fusing strength and decreased laddering after puncture as compared to a fiber prepared from a first polymer solution comprising an elastomeric polyurethaneurea with a melting point greater than 240° C.
10. The fabric of claim 9 , wherein said low temperature melting polyurethane fusibility improvement additive has a melting point from about 50° C. to about 150° C.
11. The fabric of claim 9 , wherein said low temperature melting polyurethane fusibility improvement additive has a melting point below about 120° C.
12. The fabric of claim 9 , wherein said second region is adjacent to or at least partially surrounds the first region.
13. The fabric of claim 9 , wherein said elastic multiple component solution-spun fiber is covered.
14. The fabric of claim 13 , wherein said elastic multiple component solution-spun fiber is covered with polyamide (nylon), cotton, polyester, or combinations thereof.
15. The fabric of claim 9 , wherein said elastic multiple component solution-spun fiber is fusible.
16. The fabric of claim 9 , wherein the fabric includes a knit, woven, or non-woven construction.
17. The fabric of claim 9 , wherein said fabric comprises hosiery, leg wear, shirting, intimate apparel, swim wear, bottoms, and non-woven hygiene structures.
18. A process for preparing a the fusible, elastic, multiple component, solution-spun fiber of claim 1 comprising:(a) providing first and second polymer solutions;(b) combining the solutions through distribution plates and orifices to form filaments having a cross-section;(c) extruding the filaments through a common capillary; and(d) removing solvent from said filaments; wherein said cross-section includes a boundary between said polymer solutions; wherein each of said first and second polymer solutions independently includes an elastomeric polyurethane, a polyurethaneurea, or mixtures thereof; and wherein the second polymer solutions includes a fusibility improvement additive; wherein the fusible, elastic, multiple component, solution-spun fiber includes a multiple region cross-section with the first polymer solution corresponding to a first region of said cross-section and the second polymer solution corresponding to a second region of said cross-section.