Sodium chloride production process
View Patent ↗The present invention pertains to a process for producing sodium chloride comprising the steps of: (i) preparing a brine having a sodium chloride concentration which is higher than the sodium chloride concentration of the eutectic point but lower than the sodium chloride concentration of a saturated brine by dissolving a sodium chloride source in water; (ii) cooling the resulting brine by indirect cooling in a self-cleaning fluidized bed heat exchanger/crystallizer to a temperature lower than 0° C. but higher than the eutectic temperature of the resulting brine, thereby forming a slurry comprising sodium chloride dihydrate and a mother liquor; (iii) feeding the sodium chloride dihydrate to a recrystallizer to form sodium chloride and a mother liquor, and (iv) recycling at least part of the mother liquor obtained in step (ii) and/or step (iii) to step (i).
1. A process for producing sodium chloride comprising the steps of:
(i) preparing, in a brine production cavern, a brine having a sodium chloride concentration which is higher than the sodium chloride concentration of the eutectic point but lower than the sodium chloride concentration of a saturated brine by dissolving a sodium chloride source in water;
(ii) cooling the resulting brine by indirect cooling in a self-cleaning fluidized bed heat exchanger/crystallizer to a temperature lower than 0° C. but higher than the eutectic temperature of the resulting brine, thereby forming a slurry comprising sodium chloride dihydrate and a first mother liquor;
(iii) feeding the sodium chloride dihydrate to a recrystallizer to form sodium chloride and a second mother liquor, and
(iv) recycling at least part of the first mother liquor and/or the second mother liquor to step (i).
2. The process according to claim 1 wherein the brine prepared in step (i) has a sodium chloride concentration which is at least 0.01% by weight more concentrated in sodium chloride than the eutectic concentration.
3. The process according to claim 1 , wherein the brine prepared in step (i) has a sodium chloride concentration corresponding to the sodium chloride concentration obtained by dilution of said brine when being saturated in sodium chloride with at least 0.5% by weight of water, based on the total weight of the brine.
4. The process according to claim 1 , wherein in step (ii) the resulting brine is cooled to a temperature in the range of from 0.1° C. above the eutectic temperature of the resulting brine to 14° C. above the eutectic temperature of the resulting brine.
5. The process according to claim 1 , wherein in step (ii) the resulting brine is cooled to a temperature in the range of from 1° C. above the eutectic temperature of the resulting brine to 7° C. above the eutectic temperature of the resulting brine.
6. The process according to claim 1 , wherein the indirect cooling is achieved by means of a closed circuit, wherein the resulting brine is physically totally separated from a cooling medium selected from the group consisting of ammonia, butane, carbon dioxide, Freon, ethylene glycol/water mixture, a calcium chloride/water mixture, a potassium formate/water mixture, alkyl substituted aromatics, and polydimethyl-siloxane by a solid wall.
7. The process according to claim 1 , wherein the indirect cooling is achieved via an evaporating falling film of a cooling medium selected from the group consisting of ammonia, butane, carbon dioxide and Freon.
8. The process according to claim 1 , wherein the slurry formed in step (ii) further comprises Glauber salt, and said slurry is fed to a hydrocyclone to produce a sodium chloride dihydrate-rich stream and a Glauber salt-rich stream, with said sodium chloride dihydrate-rich stream being subjected to step (iii).
9. The process according to claim 8 , wherein the Glauber salt-rich stream is at least in part recycled to step (i).
10. The process according to claim 1 wherein the brine prepared in step (i) has a sodium chloride concentration which is at least 1% by weight more concentrated in sodium chloride than the eutectic concentration.
11. The process according to claim 2 , wherein the brine prepared in step (i) has a sodium chloride concentration corresponding to the sodium chloride concentration obtained by dilution of said brine when being saturated in sodium chloride with at least 0.5% by weight of water, based on the total weight of the brine.
12. The process according to claim 2 , wherein in step (ii) the resulting brine is cooled to a temperature in the range of from 0.1° C. above the eutectic temperature of the resulting brine to 14° C. above the eutectic temperature of the resulting brine.
13. The process according to claim 2 , wherein in step (ii) the resulting brine is cooled to a temperature in the range of from 1° C. above the eutectic temperature of the resulting brine to 7° C. above the eutectic temperature of the resulting brine.
14. The process according to claim 3 , wherein in step (ii) the resulting brine is cooled to a temperature in the range of from 1° C. above the eutectic temperature of the resulting brine to 7° C. above the eutectic temperature of the resulting brine.
15. The process according to claim 3 , wherein the indirect cooling is achieved by means of a closed circuit, wherein the resulting brine is physically totally separated from a cooling medium selected from the group consisting of ammonia, butane, carbon dioxide, Freon, ethylene glycol/water mixture, a calcium chloride/water mixture, a potassium formate/water mixture, alkyl substituted aromatics, and polydimethyl-siloxane by a solid wall.
16. The process according to claim 5 , wherein the indirect cooling is achieved by means of a closed circuit, wherein the resulting brine is physically totally separated from a cooling medium selected from the group consisting of ammonia, butane, carbon dioxide, Freon, ethylene glycol/water mixture, a calcium chloride/water mixture, a potassium formate/water mixture, alkyl substituted aromatics, and polydimethyl-siloxane by a solid wall.
17. The process according to claim 2 , wherein the indirect cooling is achieved via an evaporating falling film of a cooling medium selected from the group consisting of ammonia, butane, carbon dioxide and Freon.
18. The process according to claim 4 , wherein the indirect cooling is achieved via an evaporating falling film of a cooling medium selected from the group consisting of ammonia, butane, carbon dioxide and Freon.
19. The process according to claim 5 , wherein the slurry formed in step (ii) further comprises Glauber salt, and said slurry is fed to a hydrocyclone to produce a sodium chloride dihydrate-rich stream and a Glauber salt-rich stream, with said sodium chloride dihydrate-rich stream being subjected to step (iii).
20. The process according to claim 7 , wherein the slurry formed in step (ii) further comprises Glauber salt, and said slurry is fed to a hydrocyclone to produce a sodium chloride dihydrate-rich stream and a Glauber salt-rich stream, with said sodium chloride dihydrate-rich stream being subjected to step (iii).