Electrode and production method thereof
View Patent ↗An electrode includes a collector formed with a conductive resin layer and an active material layer formed on the conductive resin layer. The active material layer comprises an active material and a binder polymer, and the conductive resin layer is bonded by thermal fusion bonding to the active material layer.
1. A production method of an electrode, comprising:
preparing a collector consisting of a laminated material of three or more conductive resin layers each containing a polymer material, the collector including outermost resin layers and at least one inner layer interposed between the outermost resin layers;
forming an electrode laminate by laminating an active material layer on the collector, the active material layer containing a binder polymer having a melting point, wherein the polymer material of each of the three or more conductive resin layers has a softening point lower than the melting point of the binder polymer; and wherein the polymer material of one of the outermost resin layers disposed nearer to the active material layer than the other of the outermost resin layers has a softening point lower than that of the polymer material of the at least one inner layer; and
thermal fusion bonding the conductive resin layer to the active material layer in the electrode laminate at a thermal fusion bonding temperature selected to fuse the polymer material without melting the binder polymer.
2. The production method of the electrode according to claim 1 , wherein the binder polymer is a thermoplastic polymer; and wherein the thermal fusion bonding is performed at a thermal fusion bonding temperature T satisfying: Tb−10<T<Ta where Tb is a softening point of a polymer material of the conductive resin layer and Ta is a melting point of the binder polymer.
3. The production method of the electrode according to claim 2 , wherein the active material layer is formed on the resin layer by transferring or by applying a high viscosity precursor of the active material layer onto the resin layer, the high viscosity precursor having a viscosity in the range of 100 to 100,000 cps at 30 to 40° C.
4. The production method of the electrode according to claim 1 , wherein the binder polymer is a thermosetting polymer; and wherein the thermal fusion bonding is performed at a thermal fusion bonding temperature T′ satisfying: Tb′−10<T′ where Tb′ is a softening point of a polymer material of the conductive resin layer.
5. The production method of the electrode according to claim 1 , wherein thermally bonding the collector to the active material layer is performed at the thermal fusion bonding temperature that is higher than a softening point of the at least one inner resin layer.
6. A production method of an electrode, comprising:
preparing a collector consisting of a laminated material of three or more conductive resin layers each containing a polymer material, the collector including outermost resin layers and at least one inner layer interposed between the outermost resin layers;
forming an electrode laminate by laminating an active material layer on the collector, the active material layer containing a binder polymer having a melting point, wherein the polymer material of each of the three or more conductive resin has a softening point lower than a melting point of the binder polymer; and wherein the polymer material of one of the outermost resin layers adjacent to the active material layer has a softening point lower than that of the polymer material of the at least one inner resin layer; and
thermal fusion bonding the conductive resin layer to the active material layer in the electrode laminate at a thermal fusion bonding temperature selected to fuse the polymer material without melting the binder polymer.