Polymeric films and method of making same
View Patent ↗Provided are polymeric films that include a polyolefin and at least one cavitating agent including a poly(alkylene terephthalate) of formula (I); wherein n, representing the number of methylene segments in the repeating unit, is 3 or an integer greater than or equal to 5; p, representing the degree of polymerization, is an integer greater than 1. The polymeric film may be an opaque polymeric film. A preferred cavitating agent is poly(trimethylene terephthalate). Also provided are methods for making such polymeric films.
1. A polymeric film comprising at least one layer, said layer comprising a polyolefin and at least one cavitating agent comprising a poly(alkylene terephthalate) of formula (I):
wherein n is 3, p is an integer greater than 1, and the poly(alkylene terephthalate) has an intrinsic viscosity of less than or equal to 0.9 dl/g; wherein the cavitating agent further comprises at least one poly(alkylene terephthalate) of formula (I) wherein n is an integer in the range of 5 to 20.
2. The polymeric film of claim 1 , wherein the poly(alkylene terephthalate) has an intrinsic viscosity of less than or equal to about 0.8 dl/g.
3. The polymeric film of claim 1 , wherein the poly(alkylene terephthalate) has an intrinsic viscosity of about 0.25 to about 0.8 dl/g.
4. The polymeric film of claim 1 , wherein the cavitating agent is in an amount of about 3 to about 60 wt. %, based on the weight of said layer.
5. The polymeric film of claim 1 , wherein the polyolefin comprises at least one of polypropylene, polyethylene, ethylene-propylene copolymers, propylene-butene copolymers, ethylene-propylene-butylene terpolymers, or blends thereof.
6. The polymeric film of claim 1 , wherein the polyolefin comprises at least one of high density polyethylene, isotactic polypropylene, high crystalline polypropylene, β-nucleated polypropylene, ethylene-propylene copolymers, or blends thereof.
7. The polymeric film of claim 1 , wherein the cavitating agent has a glass transition temperature of greater than or equal to about 35° C.
8. The polymeric film of claim 1 , wherein the cavitating agent further comprises nanoparticles selected from at least one of nanoclay, rigid polymers having a high glass transition temperature of greater than or equal to about 150° C., cross-linked polymer, metal, metal complex, carbon nanotube, ceramic, ceramic complex, or blends thereof.
9. The polymeric film of claim 1 , wherein said layer comprises a polar modified polyolefin selected from at least one of acid or anhydride modified polyolefin, acid or anhydride modified polyolefin copolymers, glycidyl methacrylate modified polyolefin, glycidyl methacrylate modified polyolefin copolymer, ethylene acrylate copolymer, anhydride modified ethylene acrylate copolymer, acid terpolymers containing ester and/or acrylic functionalities, random terpolymer of ethylene, acrylic ester and glycidyl methacrylate, or blends thereof.
10. The polymeric film of claim 1 , wherein said layer comprises a chain extender selected from at least one of pyromellitic dianhydride, bisoxazolines, 1,3-phenylenebisoxazoline, 1,4-phenylenebisoxazoline, diepoxides, carbony bis(1-caprolactam), carbodiimides, or blends thereof.
11. The polymeric film of claim 1 , wherein the film is opaque.
12. An article of manufacture comprising the polymeric film of claim 1 .
13. A polymeric film comprising at least one layer, said layer comprising a polyolefin and at least one cavitating agent comprising a poly(alkylene terephthalate) of formula (I):
wherein n is 3, p is an integer greater than 1, and the poly(alkylene terephthalate) has an intrinsic viscosity of less than or equal to 0.9 dl/g; wherein said layer comprises a polar modified polyolefin selected from at least one of acid or anhydride modified polyolefin, acid or anhydride modified polyolefin copolymers, glycidyl methacrylate modified polyolefin, glycidyl methacrylate modified polyolefin copolymer, ethylene acrylate copolymer, anhydride modified ethylene acrylate copolymer, acid terpolymers containing ester and/or acrylic functionalities, random terpolymer of ethylene, acrylic ester and glycidyl methacrylate, or blends thereof.