Powder to hydrophobise and its use
View Patent ↗The present invention relates to the use of a solid comprising at least one organosilane and a carrier material to hydrophobise mortars, wherein the organosilane has the formula R 1 Si(OR′) 3 or R 1 R 2 Si(OR′) 2 wherein R 1 and R 2 are the same or different and are a linear or branched C 1 - to C 4 -alkyl and/or alkenyl group, OR′ is an acetoxy, a C 1 - to C 4 -alkoxy and/or a C 2 - to C 6 -methoxyalkoxy and/or ethoxyalkoxy group, and the carrier material is a solid at room temperature. The amount of cement in the final formulation is zero or less than 5 wt.-%, based on the total weight of the final formulation in the dry and uncured form. Claimed are also a powder comprising the silane and a carrier with the carrier being a water-soluble polymer, dry mortar formulations containing no or less than 5 wt.-% cement, based on the dry weight of the uncured mortar formulation, as well as processes to manufacture the formulations and/or compounds.
1. A process to hydrophobise a mortar formulation, the process comprising:
mixing a solid with the mortar formulation, the solid comprising at least one organosilane and a carrier material, wherein
a) the organosilane has the formula
R 1 Si(OR′) 3 (I)
or
R 1 R 2 Si(OR′) 2 (II)
wherein R 1 and R 2 are the same or different and are a linear or branched C 1 - to C 4 -alkyl and/or alkenyl group, OR′ is an acetoxy, a C 1 - to C 4 -alkoxy and/or a C 2 - to C 6 -methoxyalkoxy and/or ethoxyalkoxy group, and
b) the carrier material is solid at room temperature, and
wherein the weight ratio of the organosilane to the carrier material is between 70:30 and 1:99; the solid is in the form of a powder, a granulate and/or a flake; and the amount of cement in the final mortar formulation is zero or less than 5 wt.-%, based on the total weight of the final mortar formulation in the dry and uncured form.
2. The process according to claim 1 , wherein the final mortar formulation containing zero or less than 5 wt.-% cement is a gypsum-based or a gypsum-free mortar.
3. The process according to claim 1 , wherein R 1 is selected from the group consisting of methyl, ethyl, n-propyl, i-propyl, n-butyl, sec-butyl, i-butyl, t-butyl, vinyl and allyl; and wherein R 2 is selected from the group consisting of methyl, ethyl, n-propyl, i-propyl, n-butyl, sec-butyl, i-butyl, t-butyl, vinyl and allyl.
4. The process according to claim 1 , wherein the alkoxy group is selected from the group consisting of methoxy, ethoxy, n-propoxy, i-propoxy, n-butoxy, sec-butoxy, i-butoxy and t-butoxy.
5. The process according to claim 1 , wherein the carrier material is selected from the group consisting of a water-soluble polymer, a combination of a water-soluble and a water-insoluble polymer, a water-dispersible polymer, an inorganic material, and combinations thereof.
6. The process according to claim 1 , wherein the solid further comprises a catalyst to catalyze the hydrolysis of Si—OR′ bonds to form Si—OH groups and/or to catalyze the condensation of Si—OH groups to form Si—O—Si bonds.
7. The process according to claim 6 , wherein the catalyst is selected from the group consisting of a base, an amine, a metal salt, a metal complex, and combinations thereof; and wherein the catalyst is in the form of a powder, a granulate or a flake.
8. The process powder according to claim 2 , wherein R 1 is selected from the group consisting of methyl, ethyl, n-propyl, i-propyl, n-butyl, sec-butyl, i-butyl, t-butyl, vinyl and allyl; and wherein R 2 is selected from the group consisting of methyl, ethyl, n-propyl, i-propyl, n-butyl, sec-butyl, i-butyl, t-butyl, vinyl and allyl.
9. The process according to claim 3 , wherein the alkoxy group is selected from the group consisting of methoxy, ethoxy, n-propoxy, i-propoxy, n-butoxy, sec-butoxy, i-butoxy and t-butoxy.
10. The process according to claim 3 , wherein the carrier material is selected from the group consisting of a water-soluble polymer, a combination of a water-soluble and a water-insoluble polymer, a water-dispersible polymer, an inorganic material, and combinations thereof.
11. The process according to claim 4 , wherein the solid further comprises a catalyst to catalyze the hydrolysis of Si—OR′ bonds to form Si—OH groups and/or to catalyze the condensation of Si—OH groups to form Si—O—Si bonds.
12. The process according to claim 7 , wherein the metal is a transition metal.
13. A powder comprising at least one organosilane and a carrier material, wherein
c) the organosilane has the formula
R 1 Si(OR′) 3 (I)
or
R 1 R 2 Si(OH) 2 (II)
wherein R 1 and R 2 are the same or different and are a linear or branched C 1 - to C 4 -alkyl and/or alkenyl group, OR′ is an acetoxy, a C 1 - to C 4 -alkoxy and/or a C 2 - to C 6 -methoxyalkoxy and/or ethoxyalkoxy group, and
c) the carrier material is at least one water-soluble polymer which is solid at room temperature, and
wherein the weight ratio of the organosilane to the carrier material is between 70:30 and 1:99.
14. A process to manufacture a dry mortar formulation containing zero or less than 5 wt.-% cement, based on the total weight of the dry and uncured mortar formulation, the process comprising:
dry mixing the mortar components with the powder according to claim 13 .
15. The process according to claim 14 , wherein the powder is mixed with the dry mortar components in such an amount that the amount of organosilane is 1.0 wt.-% or lower, based on the dry weight of the formulation.
16. A dry mortar formulation containing the powder of claim 13 , and zero or less than 5 wt.-% cement, based on the total weight of the dry and uncured mortar formulation.
17. The dry mortar formulation according to claim 16 , wherein the powder is present in such an amount that the amount of organosilane is 1.0 wt.-% or lower, based on the dry weight of the formulation.
18. The process according to claim 14 , wherein the powder is mixed with the dry mortar components in such an amount that the amount of organosilane is 0.2 wt.-% or lower, based on the dry weight of the formulation.
19. The dry mortar formulation according to claim 16 , wherein the powder is present in such an amount that the amount of organosilane is 0.5 wt.-% or lower, based on the dry weight of the formulation.
20. The dry mortar formulation according to claim 16 , wherein the powder is present in such an amount that the amount of organosilane is 0.2 wt.-% or lower, based on the dry weight of the formulation.