Graphene production using laser heated crystal growth
View Patent ↗Implementations and techniques for producing graphene are generally disclosed. A seed crystal may be affixed to a support substrate such that the seed crystal faces substantially downwardly and such that the formed graphene crystal hangs substantially downwardly. Feedstock may be provided adjacent to the seed crystal, and a laser beam may be applied to heat the seed crystal and the feedstock to grow a graphene crystal.
1. A method for producing graphene comprising:
affixing a seed crystal to a support substrate such that the seed crystal faces downwardly from the support substrate about a location;
providing a feedstock adjacent to the seed crystal about the location; and
applying a laser beam to heat at least a portion of the seed crystal and at least a portion of the feedstock about the location, wherein a graphene crystal is formed that hangs downwardly from a surface of the support structure.
2. The method of claim 1 , further comprising:
applying an electrostatic field to the graphene crystal, wherein the electrostatic field is effective to apply a straightening force to the downwardly hanging graphene crystal.
3. The method of claim 1 , wherein affixing the seed crystal to the support substrate comprises securing the seed crystal to the support substrate with an epoxy.
4. The method of claim 1 , wherein affixing the seed crystal to the support substrate comprises aligning a crystal growth axis of the seed crystal such that the feedstock and the laser beam are provided incident to the crystal growth axis.
5. The method of claim 1 , wherein the feedstock comprises at least one of carbon, graphite particles, an oxidizer or a reducer.
6. The method of claim 1 , wherein applying the laser beam comprises passing the laser beam through beam shaping optics.
7. The method of claim 6 , wherein the beam shaping optics comprise a reflaxicon.
8. A method for producing graphene comprising:
affixing a seed crystal to a support substrate such that the seed crystal faces downwardly from the support substrate about a starting location;
providing, by a feedstock injector, a feedstock adjacent to the seed crystal about the starting location;
applying, by a laser, a laser beam to heat at least a portion of the seed crystal and at least a portion of the feedstock about the starting location, wherein a graphene crystal is formed that hangs downwardly from a surface of the support structure; and
moving the feedstock injector and the support substrate relative to each other to continuously provide the feedstock at a position of growth of the graphene crystal.
9. The method of claim 8 , wherein moving the feedstock injector and the support substrate relative to each other comprises moving the support substrate while the feedstock injector remains stationary.
10. The method of claim 8 , further comprising:
preheating the seed crystal.
11. The method of claim 8 , wherein the support substrate comprises at least one of silicon carbide, silicon dioxide, or copper.
12. The method of claim 8 , wherein the laser comprises at least one of a CO2 laser, a Nd:YAG laser or a laser diode.
13. The method of claim 8 , wherein applying the laser beam comprises passing the laser beam through beam shaping optics that are cooperatively configured to provide multiple laser beams in a linear two dimensional array.
14. The method of claim 8 , wherein a composition of the feedstock changes during processing.
15. A method for producing graphene comprising:
affixing a seed crystal to a support substrate such that the seed crystal faces downwardly from the support substrate about a location;
providing a feedstock adjacent to the seed crystal about the location; and
applying a laser beam from a beam profiling projector to heat at least a portion of the seed crystal and at least a portion of the feedstock about the location, wherein a graphene crystal is formed that hangs downwardly from a surface of the support structure.
16. The method of claim 15 , wherein the laser beam comprises at least one of a linear shape or a rectangular shape.
17. The method of claim 15 , wherein the beam profiling projector comprises an inner mirror shaped as a wedge and an outer mirror having a larger and associated wedge shape.
18. The method of claim 15 , further comprising:
removing the graphene crystal from the support substrate.
19. The method of claim 18 , wherein removing the graphene crystal from the support substrate comprises at least one of cutting, laser cutting, removal by force, heating, or dissolving an epoxy used to affix the seed crystal to the support substrate.
20. The method of claim 18 , wherein providing the feedstock comprises providing the feedstock in a laminar flow regime.