Flow enhanced thermoplastic compositions and methods for enhancing the flow of thermoplastic compositions
View Patent ↗A composition that contains from 30 to 95 wt. %, based on the total weight of the composition, of a thermoplastic component and an effective amount of a flow-enhancing component. The effective amount of the flow-enhancing component reduces the viscosity of the composition by at least 10% compared to the viscosity of a composition comprising the thermoplastic component, but not an effective amount of the flow-enhancing component. The thermoplastic component is selected from the group consisting of polycarbonates, polyesters, and combinations thereof. The flow-enhancing component comprises b1) a component selected from the group consisting of metal oxides, metalloid oxides, metal alkoxides, metalloid alkoxides, and combinations thereof and b2) a mineral filler component. The weight ratio of component b1) to component b2) ranges from 1:25 to 25:1. A method for enhancing the flow of compositions comprising thermoplastic components is also disclosed.
1. A composition comprising:
a) from 30 to 95 wt. %, based on the total weight of the composition, of a thermoplastic polymer component selected from the group consisting of polycarbonates, polyesters, and combinations thereof, and
b) an effective amount of a flow-enhancing component comprising:
b1) a component selected from the group consisting of metal oxides, metalloid oxides, metal alkoxides, metalloid alkoxides, and combinations thereof, and
b2) a mineral filler component,
wherein the weight ratio of component b1) to component b2) ranges from 1:25 to 25:1, and
wherein the effective amount of the flow-enhancing component is sufficient to reduce the viscosity of the composition by at least 10% compared to the viscosity of the same composition comprising component a), but not comprising an effective amount of component b).
2. The composition according to claim 1 , comprising from 1 to 15 wt. %, based on the total weight of the composition, of component b1), and from 3 to 25 wt. %, based on the total weight of the composition, of component b2).
3. The composition according to claim 1 , wherein the thermoplastic component is a combination of at least one polycarbonate and at least one polyester, and wherein the weight percentage of polycarbonate, based on the total weight of the thermoplastic component, is greater than 50%.
4. The composition according to claim 1 , wherein the metal of the metal oxide and the metal of the metal alkoxide are the same or different, and are transition metals selected from the group consisting of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium, zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, rutherfordium, dubnium, seaborgium, bohrium, hassium, meitnerium, ununnilium, unununium, ununbium, and combinations thereof.
5. The composition according to claim 1 , wherein the metalloid of the metalloid oxide and the metalloid of the metalloid alkoxide are the same or different, and are selected from the group consisting of boron, silicon, germanium, arsenic, antimony, tellurium, polonium, and combinations thereof.
6. The composition of claim 1 , wherein the metalloid oxide is selected from the group consisting of sodium antimony oxides, sodium boron oxides, and combinations thereof.
7. The composition according to claim 1 , wherein the composition further comprises from 0.01 to 40 wt. %, based on the total weight of the composition, of an at least partially brominated polymer.
8. The composition according to claim 1 , wherein the composition further comprises from 3 to 20 wt. %, based on the total weight of the composition, of an impact modifier.
9. The composition according to claim 1 , wherein the composition further comprises an effective amount of an additive selected from the group consisting of acid quenchers, anti-dripping agents, anti-oxidants, flow modifiers, release agents, UV stabilizers, and combinations thereof.
10. The composition according to claim 1 , wherein the mineral filler component comprises a mineral filler selected from the group consisting of aluminum silicate, calcium carbonate, calcium sulfate dihydrate, calcium sulfate hemihydrate, calcinated clay, calcium silicate, clay, crushed quartz, diatomaceous earth, fly ash, kaolin, limestone, mica, silicates, talc, titanium dioxide, wollastonite, zirconium oxide, zirconium silicate, and combinations thereof.
11. The composition according to claim 10 , wherein the mineral filler component comprises talc.
12. A method for enhancing the flow of a composition comprising from 30 to 95 wt. %, based on the total weight of the composition, of a thermoplastic component selected from the group consisting of polycarbonates, polyesters, and combinations thereof,
the method comprising: adding an effective amount of a flow-enhancing component to the composition, wherein the flow-enhancing component comprises:
i) a component selected from the group consisting of metal oxides, metalloid oxides, metal alkoxides, metalloid oxides, and combinations thereof, and
ii) a mineral filler component,
wherein the weight ratio of component i) to component ii) ranges from 1:25 to 25:1, and
wherein the method reduces the viscosity of the composition by at least 10%.