Organic semiconductor material with neutral radical compound of a trioxotriangulene derivative as a semiconductor material
View Patent ↗An organic semiconductor device according to the present invention includes a semiconductor layer 14 interposed between two electrodes 12 and 15 , and the semiconductor layer 14 contains a trioxotriangulene (TOT) derivative, which is a neutral radical compound, as a semiconductor material. The semiconductor layer 14 acts as an n-type semiconductor and coacts with a p-type semiconductor layer 13 to exhibit a photoelectric conversion effect. The organic semiconductor device is characterized as including a semiconductor layer that has a narrow band gap, has light absorption performance in an infrared region, and is high in carrier mobility.
1. An organic semiconductor device, comprising at least one semiconductor layer, and having light absorption performance in an infrared region,
wherein the semiconductor layer contains a neutral radical compound of a trioxotriangulene (TOT) derivative that is shown in Chemical Formula (1) below as a semiconductor material:
(In the above formula, “R” indicates a monovalent group), wherein an energy gap between a singly occupied molecular orbital and a lowest unoccupied molecular orbital of the neutral radical compound of Chemical Formula (1) is in a range of 0.1 to 1.0 eV, and wherein infrared radiation passing through the semiconductor layer is absorbed and converted to an electric current,
wherein the neutral radical compound of Chemical Formula (1) has the monovalent group R being a monovalent functional group selected from the group consisting of a proton, a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a t-butyl group, a cyclohexyl group, a 2,2,2-trifluoroethyl group, a pentafluoroethyl group, a heptafluoroisopropyl group, a phenyl group, a 4-methoxyphenyl group, a pentafluorophenyl group, a naphthyl group, a benzyl group, a methoxy group, an ethoxy group, an n-butoxy group, a t-butoxy group, a phenyloxy group, an amino group, a dimethylamino group, a diethylamino group, an isopropylamino group, a carboxyl group, a methoxycarbonyl group, an ethoxycarbonyl group, an isopropoxycarbonyl group, a t-butoxycarbonyl group, a trifluoromethoxycarbonyl group, a cyano group, a nitrile group, and halogens.
2. The organic semiconductor device according to claim 1 , wherein the neutral radical compound of Chemical Formula (1) is layered in a columnar form in a crystalline arrangement in the semiconductor layer.
3. The organic semiconductor device according to claim 1 , wherein the organic semiconductor device is an organic thin-film solar cell.
4. The organic semiconductor device according to claim 3 , wherein the semiconductor layer is an n-type semiconductor layer that forms a p-n junction with a p-type organic semiconductor material.
5. The organic semiconductor device according to claim 3 , wherein the organic thin-film solar cell is a hybrid solar cell combined with a silicon-based solar cell.
6. The organic semiconductor device according to claim 1 , wherein the semiconductor layer has a carrier mobility of 0.01 to 20 cm2/Vs.
7. The organic semiconductor device according to claim 1 , wherein the semiconductor layer is obtained by forming the neutral radical compound of Chemical Formula (1) into a film by a coating process.