Method for producing syngas
View Patent ↗Process for the endothermic, catalytic gas phase oxidation of hydrocarbons with steam and carbon dioxide to hydrogen and carbon monoxide (synthesis gas), performed in 5 to 30 series-connected reaction zones under adiabatic conditions.
1. Process for preparing synthesis gas by reaction of a process gas consisting of hydrocarbons, carbon dioxide and steam in an endothermic, heterogeneously catalyzed gas phase reaction, comprising carrying out said reaction in 5 to 30 series-connected reaction zones under adiabatic conditions, said process gas being fed in only upstream of the first of said reaction zones and the process gas leaving each reaction zone is passed through a heat exchanger to heat it before entering the next reaction zone.
2. Process according to claim 1 , wherein said reaction is carried out in 7 to 20 series-connected reaction zones.
3. Process according to claim 1 , wherein the entrance temperature of the process gas entering the first reaction zone is 700 to 1000° C.
4. The process of claim 3 , wherein said entrance temperature is 800 to 950° C.
5. The process of claim 4 , wherein said entrance temperature is 850 to 900° C.
6. Process according to claim 1 , wherein the absolute pressure at the inlet of the first reaction zone is between 10 and 40 bar.
7. The process of claim 6 , wherein said absolute pressure is 20 to 35 bar.
8. Process according to claim 1 , wherein the total residence time of the process gas for all of the reaction zones is between 0.05 and 20 s.
9. The process of claim 8 , wherein said residence time is between 0.1 and 5 s.
10. Process according to claim 1 , wherein the catalysts are present in fixed bed arrangement.
11. Process according to claim 10 , wherein the catalysts are present as monoliths.
12. Process according to claim 11 , wherein the monolith comprises channels with a diameter of 0.1 to 3 mm.
13. The process of claim 12 wherein said diameter of said channels is 0.2 to 2 mm.
14. Process according to claim 1 , wherein the catalysts are present in beds of particles with mean particle sizes of 1 to 10 mm.
15. The process of claim 14 , wherein said mean particle sizes are 2 to 8 mm.
16. Process according to claim 1 , wherein between a reaction zone and a heat exchange zone there is at least one thermal insulation zone.
17. Process according to claim 16 , comprising a thermal insulation zone around each reaction zone.
18. The process of claim 1 , carried out in 10 to 15 series-connected reaction zones.