IP Library Granted Patent US 8,507,057
Granted Patent B2
US 8,507,057 · App. 13/133,003 · Granted Aug 13, 2013

Heat-shrinkable polyester film and preparation method thereof

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Quick Facts
Patent No.
US 8,507,057
App. No.
13/133,003
Granted
Aug 13, 2013
Kind
B2
Abstract

A heat-shrinkable polyester film having a thermal shrinkage ratio of 15% or more in the longitudinal direction when treated at 100° C. for 10 seconds, a tensile strength at rupture in the longitudinal direction of 7 kgf/mm 2 or more, and a difference between elongations at the hardening and yield points in the longitudinal direction of 15% or more exhibits superior properties, such as high tensile strength and crack-resistance in the longitudinal direction, suitable for labeling or shrink-wrapping containers.

Claims (15)

1. A heat-shrinkable polyester film having a thermal shrinkage ratio of 15% or more in the longitudinal direction when treated at 100° C. for 10 seconds, a tensile strength at rupture in the longitudinal direction of 7 kgf/mm 2 or more, and a difference between elongations (%) at the hardening and yield points in the longitudinal direction of 15% or more.

2. The film of claim 1 , which is a uni-directionally shrinkable film.

3. The film of claim 1 , which is drawn in the longitudinal direction at a total drawing ratio of 1.2 to 7.

4. The film of claim 1 , which is composed of a polyester resin which comprises

60 to 97% by mole of ethylene terephthalate repeating unit; and

3 to 40% by mole of a repeating unit obtained by copolymerization of a component selected from the group consisting of terephthalic acid, dimethyl terephthalate, naphthalenedicarboxylic acid and a mixture thereof with a branched alkylene glycol component having a carbon number of 3 or more.

5. The film of claim 4 , wherein the polyester resin further comprises 20% or less by mole of a repeating unit obtained by copolymerization of a component selected from the group consisting of terephthalic acid, dimethyl terephthalate, naphthalenedicarboxylic acid and a mixture thereof with a linear alkylene glycol component having a carbon number of 3 or more.

6. The film of claim 5 , wherein the linear alkylene glycol component is selected from the group consisting of 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol and a mixture thereof.

7. The film of claim 4 , wherein the branched alkylene glycol component is selected from the group consisting of 1,2-octanediol, 1,3-octanediol, 2,3-butanediol, 1,3-butanediol, 2,2-dimethyl-1,3-propanediol, 2-butyl-2-ethyl-1,3-propanediol, 2,2-diethyl-1,5-petanediol, 2,4-diethyl-1,5-pentanediol, 3-methyl-1,5-pentanediol, 1,1-dimethyl-1,5-pentanediol and a mixture thereof.

8. A method for preparing the heat-shrinkable polyester film according to claim 1 , comprising the steps of:

i) melt-extruding a polyester resin at 200 to 300° C.;

ii) casting the extruded resin with cooling, to produce an undrawn sheet; and

iii) drawing the undrawn sheet in the longitudinal direction at a total drawing ratio of 1.2 to 7.

9. The method of claim 8 , wherein the drawing is conducted using at least two rolls having different peripheral velocities, the peripheral velocity ratio of the rear drawing roll to the front drawing roll being 1.1 to 6.5.

10. A wrapping material comprising the heat-shrinkable polyester film according to claim 1 .

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 13, 2026
From: SK MICROWORKS CO. LTD.
To: MICROWORKS CO. LTD.
Reel/Frame 074306/0727 →
CORRECTIVE ASSIGNMENT TO CORRECT THE THE ASSIGNMENT DOCUMENT PREVIOUSLY RECORDED AT REEL: 063240 FRAME: 0192. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 8, 2023
From: SKC CO., LTD.
To: SK MICROWORKS CO., LTD.
Reel/Frame 065841/0822 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2023
From: SKC CO., LTD.
To: SK MICROWORKS CO., LTD.
Reel/Frame 063240/0192 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 7, 2011
From: KIM, SEONG-DO; JEONG, TAEHOUNG; OH, TAE-BYOUNG
To: SKC CO., LTD.
Reel/Frame 026399/0812 →