Hydrogenated styrenic block copolymers blends with polypropylene
View Patent ↗The present invention comprises a molding composition comprising at least about 70% wt. polypropylene or polypropylene random copolymer; up to about 30 wt. % of a block copolymer composition comprising at least one selectively hydrogenated block copolymer which substantially matches the index of refraction of the polypropylene or polypropylene random copolymer, and up to about 0.70% by wt. of a clarifying agent, wherein the weight % of the total blend is 100%. The present invention also may be a molded article produced from the molding composition. A molded article formed from such a composition at a thickness of 0.125 inches will have a haze of less than about 50% and an instrumented impact toughness of at least 100 inch-lbs at −20° C. to −30° C.
1. A molding composition of at least the following 3 components, comprising:
at least about 70% by weight of a polypropylene or polypropylene random copolymer; up to 30% by weight of a block copolymer composition comprising at least one selectively hydrogenated styrene diene block copolymer having the general formula of S-HD-S or (S-HD) x -Z, where S is polymerized block of monoalkenyl aromatic hydrocarbon monomers, HD is a hydrogenated block of polymerized conjugated diene monomer or monomers, and Z is a coupling agent, and x is the number of arms which can vary from 1 to 20, and at least 2500 ppm of a clarifying agent conforming to the structure of Formula (I)
wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 are each independently selected from the group consisting of hydrogen, alkyl groups, alkoxy groups, alkenyl groups, aryl groups, carboxyl groups, and halogens; and R 11 is a hydroxyalkyl group selected from the group consisting of —CH 2 OH and —CHOHCH 2 OH, wherein said block copolymer composition has a refractive index that substantially matches said polypropylene or polypropylene random copolymer (+/−0.008 refractive index units) and the glass transition temperature of the HD block is about −50° C. to −55° C. as measured by DSC.
2. The molding composition of claim 1 , wherein the HD block is a hydrogenated block of polymerized 1,3-butadiene having a butylene content of about 40 wt % and the S block is a polystyrene block.
3. The molding composition of claim 1 , wherein said polypropylene random copolymer includes up to 6% by weight randomly copolymerized monomer selected from the group consisting of ethylene, butylene, hexene, and octene, based on the weight of said polypropylene random copolymer.
4. The molding composition of claim 1 , wherein said block copolymer composition has a refractive index of about 1.503.
5. The molding composition of claim 1 , wherein said clarifying agent is present in the composition in an amount that includes the amount of clarifying agent normally incorporated in the polypropylene or polypropylene random copolymer and an added amount of at least 500 ppm, and wherein the total amount of clarifying agent present in the composition is from 2500 ppm to about 7000 ppm of said molding composition.
6. The molding composition of claim 1 , wherein a 0.125 inch thick injection molded disk of said composition has an instrumented impact strength of at least 100 inch-lbs at about −20° C. to −30° C.
7. The molding composition of claim 1 , wherein said composition has no more than 50% haze in a 0.125 inch thick injection molded disk.
8. The molding composition of claim 1 , wherein said R 1 , R 4 , R 5 , R 6 , R 7 , and R 10 are each hydrogen, R 2 , R 3 , R 8 , and R 9 are each methyl groups, and R 11 is —CHOHCH 2 OH.
9. The molding composition of claim 1 , wherein said block copolymer composition is a mixture of two or more selectively hydrogenated styrene diene block copolymers having different refractive indicies where the mixture has an average index of refraction that substantially matches the refractive index of said polypropylene or polypropylene random copolymer.
10. The molding composition of claim 9 , wherein said mixture contains selectively hydrogenated block copolymers each having from about 10 to about 35% by weight polystyrene and where the average styrene content of the mixture is about 23-26% wt based on the weight of said selectively hydrogenated block copolymer.
11. The molding composition of claim 1 , wherein said block copolymer composition comprises a mixture in which the selectively hydrogenated block copolymer is replaced by up to 50% of a polyethylene copolymer that substantially matches the refractive index of the polypropylene or random polypropylene copolymer.
12. The molding composition of claim 11 , wherein said polyethylene copolymer has a density of about 0.9 g/cm 3 .
13. A molded article produced from a composition having at least the following 3 components, comprising:
at least about 80% by weight of a polypropylene or polypropylene random copolymer, up to 20% by weight of a block copolymer composition comprising at least one selectively hydrogenated block copolymer having the general formula S-HD-S or (S-HD) x -Z, where S is a block of polymerized monoalkenyl aromatic hydrocarbon monomer, HD is a block of hydrogenated polymerized conjugated diene monomer or monomers, and Z is a coupling agent, and x is the number of arms which can vary from 1 to 20; and at least 2500 ppm of a clarifying agent conforming to the structure of Formula (I)
wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 are each independently selected from the group consisting of hydrogen, alkyl groups, alkoxy groups, alkenyl groups, aryl groups, carboxyl groups, and halogens; and R 11 is a hydroxyalkyl group selected from the group consisting of —CH 2 OH and —CHOHCH 2 OH, wherein said selectively hydrogenated block copolymers have a refractive index that substantially matches said polypropylene or polypropylene random copolymer (within +/−0.008 refractive index units).
14. The molded article of claim 13 , wherein said article is a freezer food container.
15. The molded article of claim 13 , having no more than 50% haze and an instrumented impact strength of at least about 100 inch-lbs at −20° C. to −30° C. as determined on an injection molded disk with a thickness of about 0.125 inch.
16. The molded article of claim 13 , wherein R 1 , R 4 , R 5 , R 6 , R 7 , and R 10 are each hydrogen, R 2 , R 3 , R 8 , and R 9 are each methyl groups, and R 11 is —CHOHCH 2 OH.
17. The molded article of claim 13 , wherein said S-HD-S or (S-HD) x -Z can be a mixture of such selectively hydrogenated block copolymers having different refractive indicies, but an average index of refraction that substantially matches the refractive index of said polypropylene or polypropylene random copolymer (+/−0.008 refractive index units).
18. The molded article of claim 13 , wherein said clarifying agent is present in the composition in an amount that includes the amount of clarifying agent normally incorporated in the polypropylene or polypropylene random copolymer and an additional amount such that the total amount of clarifying agent present in the composition is from 2500 ppm to about 7000 ppm of said composition.