Fine particles
View Patent ↗A fine particle comprising a core and a coating, wherein the coating comprises a substantially monomolecular layer of organic molecules. The fine particle being produced by a process comprising introducing a core material into a plasma stream, thereby vaporizing some or all of the core material; cooling the core material downstream from where the core material was introduced thereby creating particles of the core material; and coating the particles of the core material with organic molecules in an injection zone, wherein the injection zone is downstream of a region where the particles of core material are formed, or wherein the cooled particles of core material are coated with organic molecules in a coating chamber by applying a liquid coating material and/or a solution of coating material to the core material; where in the coating chamber is downstream of a region wherein the particles of core material are formed.
1. A process for the formation of substantially oxide-free fine particles comprising a core and a coating, wherein the coating comprises one or more polymeric compounds; the process comprising: introducing a core material into a plasma stream thereby vaporising some or all of the core material; cooling the core material downstream from where the core material was introduced, thereby creating particles of the core material; injecting the polymeric compounds into an injection zone; and coating particles of the core material with the polymeric compounds in the injection zone; wherein the polymeric compounds are injected in an inert gas stream into the injection zone at the closest proximity within the plasma stream to the point of formation of the core material where the temperature is below the decomposition/pyrolysis point of the coating material, and wherein the injection zone is downstream of a region where the particles of core material are formed.
2. A process according to claim 1 wherein coating occurs after the particles of core material have been formed.
3. A process according to claim 1 wherein the polymeric compounds are optionally heated prior to injection.
4. A process according to claim 1 wherein the coating occurs in a part of the injection zone which is at a temperature slightly below the temperature where the polymeric compounds would decompose or pyrolyse.
5. A process according to claim 1 wherein the polymeric compounds form a monolayer coating.
6. A process according to claim 1 , wherein the fine particles are less than 20 nanometers in diameter.
7. A process according to claim 1 comprising the fine particles having a surface of a single polarity.
8. A process according to claim 1 , wherein the fine particle additionally comprises argon, hydrogen or helium residue; and/or wherein the core is selected from a metal, metalloid, metal oxide or combination thereof.
9. A process according to claim 8 wherein the metal comprises a transition metal selected from the group consisting of iron, nickel, copper, zinc, palladium, silver, cadmium, gold and alloys thereof.
10. A process according to claim 1 wherein the coating is removable.
11. A process according to claim 1 , wherein the polymeric compounds comprise a pyrrolidone.