Hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material with excellent corrosion resistance
View Patent ↗The present invention provides a Zn—Al—Mg—Cr alloy-coated steel material with excellent corrosion resistance. A molten Zn—Al—Mg—Si—Cr alloy-coated steel material which is a steel material having a Zn—Al—Mg—Cr alloy coating layer and which has an interfacial alloy layer formed of coating layer components and Fe at the coating layer-steel material interface, wherein the interfacial alloy layer has a multilayer structure consisting of an Al—Fe-based alloy layer and an Al—Fe—Si-based alloy layer and furthermore, the Al—Fe—Si-based alloy layer contains Cr.
1. A hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material having a coating layer on the surface of a steel material and having an interfacial alloy layer at the interface between said steel material and said coating layer,
wherein the average composition of the entire coating layer consisting of said coating layer and said interfacial alloy layer contains, in mass %, Al: from 25 to 75%, Mg: from 0.1 to 10%, Si: more than 1% and 7.5% or less, and Cr: from 0.05 to 5.0%, with the balance being Zn and unavoidable impurities,
wherein said interfacial alloy layer is composed of coating layer components and Fe and has a thickness of 0.05 to 10 μm or a thickness of 50% or less of the entire coating layer thickness,
wherein said interfacial alloy layer has a multilayer structure consisting of an Al—Fe-based alloy layer and an Al—Fe—Si-based alloy layer,
wherein said Al—Fe-based alloy layer contains Al, Fe, less than 2 mass % of Si and 0 mass % of Cr,
wherein said Al—Fe—Si-based alloy layer contains Al, Fe, 2 mass % or more of Si and Cr, and
wherein said Al—Fe—Si-based alloy layer consists of a layer containing Al, Fe, 2 mass % or more of Si and Cr and a layer containing Al, Fe, 2 mass % or more of Si and 0 mass % of Cr, and wherein the layer containing Al, Fe, 2 mass % or more of Si and Cr is in contact with the coating layer.
2. The hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material as claimed in claim 1 , wherein the Cr concentration in said Cr-containing Al—Fe—Si-based alloy layer is from 0.5 to 10% in terms of mass %.
3. The hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material as claimed in claim 1 , wherein said entire coating layer contains, in mass %, from 1 to 500 ppm of at least one of Sr or Ca.
4. A method for producing the hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material claimed in claim 1 , comprising steps of:
(i) dipping and then pulling a steel material in and out of a hot-dip coating bath containing, in mass %, Al: from 25 to 75%, Mg: from 0.1 to 10%, Si: more than 1% and 7.5% or less, and Cr: from 0.05 to 5.0%, with the balance being Zn, to obtain a coated steel material,
(ii) cooling the coated steel material obtained in step (i) from the coating bath temperature to the solidification temperature of the coating at a cooling rate of 10 to 18° C./sec to solidify said coating, and
(iii) cooling the coated steel material obtained in step (ii) at a cooling rate of 10 to 20° C./sec to form an Al—Fe—Si-based alloy layer containing said Cr in said interfacial alloy layer formed between said steel material and said coating layer.
5. The method according to claim 4 , wherein the cooling rate of step (ii) is 10 to 17° C./sec.
6. The method according to claim 4 , wherein the cooling rate of step (iii) is 10 to 18° C./sec.
7. The method according to claim 4 , wherein the cooling rate of step (iii) is 10 to 16° C./sec.
8. A hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material having a coating layer on the surface of a steel material and having an interfacial alloy layer at the interface between said steel material and said coating layer, wherein the average composition of the entire coating layer consisting of said coating layer and said interfacial alloy layer contains, in mass %, Al: from 25 to 75%, Mg: from 0.1 to 10%, Si: more than 1% and 7.5% or less, and Cr: from 0.05 to 5.0%, with the balance being Zn and unavoidable impurities, said interfacial alloy layer is composed of coating layer components and Fe and has a thickness of 0.05 to 10 μm or a thickness of 50% or less of the entire coating layer thickness, said interfacial alloy layer has a multilayer structure consisting of an Al—Fe-based alloy layer and an Al—Fe—Si-based alloy layer, and said Al—Fe—Si-based alloy layer contains Cr, wherein said Al—Fe-based alloy layer forms a columnar crystal and said Al—Fe—Si-based alloy layer forms a granular crystal.
9. The hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material as claimed in claim 8 , wherein the Cr concentration in said Cr-containing Al—Fe—Si-based alloy layer is from 0.5 to 10% in terms of mass %.
10. The hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material as claimed in claim 8 , wherein said entire coating layer contains, in mass %, from 1 to 500 ppm of at least one of Sr or Ca.
11. A method for producing the hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material claimed in claim 8 , comprising steps of:
(i) dipping and then pulling a steel material in and out of a hot-dip coating bath containing, in mass %, Al: from 25 to 75%, Mg: from 0.1 to 10%, Si: more than 1% and 7.5% or less, and Cr: from 0.05 to 5.0%, with the balance being Zn, to obtain a coated steel material,
(ii) cooling the coated steel material obtained in step (i) from the coating bath temperature to the solidification temperature of the coating at a cooling rate of 10 to 18° C./sec to solidify said coating, and
(iii) cooling the coated steel material obtained in step (ii) at a cooling rate of 10 to 20° C./sec to form an Al—Fe—Si-based alloy layer containing said Cr in said interfacial alloy layer formed between said steel material and said coating layer.
12. A hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material having a coating layer on the surface of a steel material and having an interfacial alloy layer at the interface between said steel material and said coating layer, wherein the average composition of the entire coating layer consisting of said coating layer and said interfacial alloy layer contains, in mass %, Al: from 25 to 75%, Mg: from 0.1 to 10%, Si: more than 1% and 7.5% or less, and Cr: from 0.05 to 5.0%, with the balance being Zn and unavoidable impurities, said interfacial alloy layer is composed of coating layer components and Fe and has a thickness of 0.05 to 10 pm or a thickness of 50% or less of the entire coating layer thickness, said interfacial alloy layer has a multilayer structure consisting of an Al—Fe-based alloy layer and an Al—Fe—Si-based alloy layer, and said Al—Fe—Si-based alloy layer contains Cr, wherein said Al—Fe-based alloy layer consists of a layer composed of Al 5 Fe 2 and a layer composed of Al 3.2 Fe.
13. The hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material as claimed in claim 12 , wherein the Cr concentration in said Cr-containing Al—Fe—Si-based alloy layer is from 0.5 to 10% in terms of mass %.
14. The hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material as claimed in claim 12 , wherein said entire coating layer contains, in mass %, from 1 to 500 ppm of at least one of Sr or Ca.
15. A method for producing the hot-dip Zn—Al—Mg—Si—Cr alloy-coated steel material claimed in claim 12 , comprising steps of:
(i) dipping and then pulling a steel material in and out of a hot-dip coating bath containing, in mass %, Al: from 25 to 75%, Mg: from 0.1 to 10%, Si: more than 1% and 7.5% or less, and Cr: from 0.05 to 5.0%, with the balance being Zn, to obtain a coated steel material,
(ii) cooling the coated steel material obtained in step (i) from the coating bath temperature to the solidification temperature of the coating at a cooling rate of 10 to 18° C./sec to solidify said coating, and
(iii) cooling the coated steel material obtained in step (ii) at a cooling rate of 10 to 20° C./sec to form an Al—Fe—Si-based alloy layer containing said Cr in said interfacial alloy layer formed between said steel material and said coating layer.