Polymer light-emitting material, method for producing the same, and organic electroluminescent device
View Patent ↗Disclosed is a polymer light-emitting material for an organic electroluminescent device that displays excellent light-emitting performance and is applicable to a wet process. The polymer light-emitting material for an organic electroluminescent device is obtained by subjecting a thermoplastic resin having an Mw of 2,000-1,000,000 and containing a functional group in a unit constituting the backbone and a metal-containing phosphorescent dopant compound containing a reactive group capable of reacting with the said functional group to a polymer reaction so as to link a phosphorescent dopant moiety derived from the metal-containing phosphorescent dopant compound to the unit constituting the backbone of the thermoplastic resin. The content of the metal derived from the metal containing phosphorescent dopant compound in the said polymer light-emitting material is 0.001-20 wt %.
1. A method for producing a polymer light-emitting material for an organic electroluminescent device which comprises:
mixing a thermoplastic resin having a weight average molecular weight of 2,000-1,000,000 and containing a reactive functional group in a unit constituting the backbone and a metal-containing phosphorescent dopant compound comprising an organic metal complex containing at least one metal selected from ruthenium, rhodium, palladium, silver, rhenium, osmium, iridium, platinum, and gold and containing a reactive group capable of reacting with the said functional group to form a linkage and
allowing the said functional group to react with the said reactive group so as to link a phosphorescent dopant moiety derived from the metal-containing phosphorescent dopant compound to the unit constituting the backbone of the thermoplastic resin;
wherein the content of the metal in the said polymer light-emitting material is 0.001-20 wt %; and
wherein the thermoplastic resin is a polyhaloalkylaromatic vinyl resin and the reactive functional group is a haloalkyl group.
2. A method for producing a polymer light-emitting material which comprises:
first allowing a thermoplastic resin having a weight average molecular weight of 2,000-1,000,000 and containing a reactive functional group in a unit constituting the backbone to react first partly with a metal-containing phosphorescent dopant compound comprising an organic metal complex containing at least one metal selected from ruthenium, rhodium, palladium, silver, rhenium, osmium, iridium, platinum, and gold and containing a reactive group capable of reacting with the said functional group to form a linkage and then with a carrier-transporting compound containing a reactive group capable of reacting with the said functional group to form a linkage so as to link a phosphorescent dopant moiety derived from the metal-containing phosphorescent dopant compound and a carrier-transporting compound moiety derived from the carrier-transporting compound to the unit constituting the backbone of the thermoplastic resin;
wherein the content of the metal in the said polymer light-emitting material is 0.001-20 wt %; and
wherein the thermoplastic resin is a polyhaloalkylaromatic vinyl resin and the reactive functional group is a haloalkyl group.
3. The method for producing a polymer light-emitting material described in claim 1 , wherein the polyhaloalkylaromatic vinyl resin is a polychloromethyl styrene resin.
4. The method for producing a polymer light-emitting material described in claim 1 , wherein the metal-containing phosphorescent dopant compound is an organic metal complex containing iridium.
5. The method for producing a polymer light-emitting material described in claim 1 , wherein the reactive group of the metal-containing phosphorescent dopant compound is a hydroxyl group or an alkoxide group.