Thermoplastic polyolefin compounds with decreased flaming sensitivity
View Patent ↗Thermoplastic polyolefin compounds for the production of injection molded, paintable and flame pre-treatable articles comprising A) 50 wt % to 90 wt % of a propylene homo- or copolymer matrix phase (M) and B) 10 wt % to 50 wt % of a first elastomer comprising an ethylene-C 3 -C 6 -alpha olefin copolymer rubber C) 0 wt % to 20 wt %, based on the total weight of A and B, of a second elastomer, component B) and C) forming a disperse phase (E) and D) >30 wt % up to 60 wt %, based on the total weight of components A, B and C, of an inorganic filler, if the intrinsic viscosity of the disperse phase (E) is <2.2 dl/g according to ISO 1628 (with decalin as solvent) or 0 wt % to <30 wt % based on the total weight of components A, B and C, of an inorganic filler, if the intrinsic viscosity of the disperse phase (E) is ≧2.2 dl/g according to ISO 1628 (with decalin as solvent).
1. Thermoplastic polyolefin compounds for the production of injection moulded, paintable and flame pre-treatable articles comprising
A) 50 wt % to 90 wt %, based on the total amount of thermoplastic polyolefins, of a propylene homo- or copolymer matrix phase (M), and
B) 10 wt % to 50 wt %, based on the total amount of thermoplastic polyolefins, of a first elastomer comprising an ethylene-C 3 -C 8 -alpha olefin copolymer rubber,
C) 2 wt % to 10 wt %, based on the total weight of A and B, of a second elastomer, which is an ethylene-1-octene copolymer rubber, component B) and C) forming a disperse phase (E) with an intrinsic viscosity of ≧2.2 dl/g according to ISO 1628 (with decalin as solvent), and
D) 10 wt % to 30 wt % based on the total weight of components A, B and C of an inorganic filler which in combination with the intrinsic viscosity is effective for increased thermal conductivity effective to provide decreased flaming sensitivity or no flaming sensitivity during flame pre-treatment of the article prior to painting,
wherein a MFR 2 of the matrix phase (M) is 40 to 200 g/10 min (measured under a load of 2.16 kg at 230° C. according to ISO 1133),
wherein the component C) is different from component B).
2. Thermoplastic polyolefin compounds according to claim 1 , wherein the matrix phase (M) is a propylene homopolymer.
3. Thermoplastic polyolefin compounds according to claim 1 , wherein the ethylene-C 3 -C 8 -alpha olefin copolymer rubber B) is an ethylene-propylene or ethylene-1-octene copolymer rubber.
4. Thermoplastic polyolefin compounds according to claim 1 , wherein the elastomer (C) comprises ethylene and up to 45 wt % of 1-octene.
5. Thermoplastic polyolefin compounds according to claim 1 , wherein the inorganic filler is selected from the group consisting of talc, wollastonite, mica and chalk and has a mean particle size d50 between 0.5 to 40 μm.
6. Thermoplastic polyolefin compounds according to claim 5 , wherein the inorganic filler is talc having a mean particle size d50 between 0.7 to 20 μm.
7. Thermoplastic polyolefin compounds according to claim 1 , wherein the thermoplastic polyolefin compounds have an intrinsic viscosity of the disperse phase (E) ≧2.5 dl/g.
8. Thermoplastic polyolefin compounds according to claim 1 , wherein the thermoplastic polyolefin compounds contain as an additional polymer a high melt flow rate polypropylene homopolymer with an MFR above 50 g/10 min according to ISO 1 133 (2.16 kg; 230 C) in an amount up to 30 wt %, based on the total weight of components A, B and C.
9. Thermoplastic polyolefin compounds according to claim 1 , wherein the thermoplastic polyolefin compounds form injection moulded, paintable and flame pre-treatable articles.
10. Process for making injection moulded, paintable and flame pre-treatable articles comprising
providing thermoplastic polyolefin compounds comprising
A) 50 wt % to 90 wt %, based on the total amount of thermoplastic polyolefins, of a propylene homo- or copolymer matrix phase (M), and
B) 10 wt % to 50 wt %, based on the total amount of thermoplastic polyolefins, of a first elastomer comprising an ethylene-C 3 -C 8 -alpha olefin copolymer rubber,
C) 2 wt % to 10 wt %, based on the total weight of A and B, of a second elastomer, which is an ethylene-1-octene copolymer rubber, component B) and C) forming a disperse phase (E) with an intrinsic viscosity of ≧2.2 dl/g according to ISO 1628 (with decalin as solvent), and
D) greater than 10 wt % up to 30 wt % based on the total weight of components A, B and C of an inorganic filler which in combination with the intrinsic viscosity is effective for increased thermal conductivity effective to provide decreased flaming sensitivity or no flaming sensitivity during flame pre-treatment of the article prior to painting,
wherein a MFR 2 of the matrix phase (M) is 40 to 200 g/10 min (measured under a load of 2.16 kg at 230° C. according to ISO 1133),
wherein the component C) is different from component B);
producing said injection moulded articles using said thermoplastic polyolefin compounds.