Rubber composition for a tire containing epoxide natural rubber and a plasticizing resin
View Patent ↗The present invention relates to a rubber composition based on at least an epoxidized natural rubber (ENR), a reinforcing filler and, as plasticizing agent, an alpha-methylstyrene polymer resin. The invention also relates to the use of such a composition for the manufacture of a tire tread exhibiting an improved compromise of properties with respect to grip on wet ground and rolling resistance.
1. A rubber composition based on at least an epoxidized natural rubber (abbreviated to “ENR”), a reinforcing filler and, as plasticizing agent, an alpha-methylstyrene polymer resin having a number-average molecular weight between 400 and 2000 g/mol, a polydispersity index of less than 3, and a T g of greater than 20° C., which is miscible in the rubber composition at the content of resin and ENR present therein, and which is selected from the group consisting of homopolymers of the alpha-methylstyrene monomer and copolymers containing units derived from the alpha-methylstyrene monomer in an amount greater than 50 mol %.
2. The composition according to claim 1 , wherein the ENR content is greater than 30 phr.
3. The composition according to claim 2 , wherein the ENR content is greater than 40 phr.
4. The composition according to claim 3 , wherein the ENR content is within a range of 50 to 100 phr.
5. The composition according to claim 1 , further comprising: a diene elastomer chosen from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and mixtures of these elastomers.
6. The composition according to claim 1 , wherein the alpha-methylstyrene polymer resin has a T g of greater than 30° C.
7. The composition according to claim 1 , wherein the alpha-methylstyrene polymer resin has a number-average molecular weight between 500 and 1500 g/mol.
8. The composition according to claim 1 , wherein the alpha-methylstyrene polymer resin has a polydispersity index of less than 2.
9. The composition according to claim 1 , wherein the alpha-methylstyrene polymer resin is a homopolymer.
10. The composition according to claim 1 , wherein the alpha-methylstyrene polymer resin is a copolymer.
11. The composition according to claim 10 , wherein the resin is a copolymer of styrene and of alpha-methylstyrene.
12. The composition according to claim 1 , wherein the resin is a phenol-modified resin.
13. The composition according to claim 1 , wherein the content of alpha-methylstyrene polymer resin is within a range of 5 to 60 phr.
14. The composition according to claim 13 , wherein the content of alpha-methylstyrene polymer resin is within a range of 10 to 50 phr.
15. The composition according to claim 1 , wherein the reinforcing filler comprises carbon black and/or silica, or both.
16. The composition according to claim 1 , wherein the amount of reinforcing filler is greater than 50 phr.
17. The composition according to claim 16 , wherein the amount of reinforcing filler is between 50 and 150 phr.
18. A tire comprising: a rubber composition according to claim 1 .
19. The tire according to claim 18 , the rubber composition being present in the tread of this tire.