Use of a polyethylene-based film in a photovoltaic module
View Patent ↗The invention relates to the use in a photovoltaic module of a film of a composition as a backsheet or as an encapsulant, this composition comprising, with respect to the total weight of the composition: from 1 to 99% of a polyethylene having an ethylene whose level by weight is greater than or equal to 80% chosen from the homopolymers of ethylene and the copolymers of ethylene and another alpha-olefin; from 99 to 1% of a polyolefin B, other than A, carrying a reactive functional group X chosen from the anhydride carboxylic acids and epoxides. The invention also relates to, the composition additionally comprises a polyolefin C, other than B, which carries a functional group Y capable of reacting with the functional group X. The invention further relates to a photovoltaic module comprising the film which is used of the composition and also a process for the manufacture of this module.
1. A film composition for use in a photovoltaic module as a backsheet or as an encapsulant, said composition comprising, with respect to the total weight of the composition:
from 10 to 90 wt % of a polyethylene A, wherein polyethylene A is a homopolymer or copolymer consisting of ethylene monomer units at greater than or equal to 80% by weight and optionally one or more other alpha olefin monomer units selected from the group consisting of propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 4-methyl-1-pentene, 3-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-hexacosene, 1-octacosene and 1;
from 5 to 85 wt % of a polyolefin B, other than polyethylene A, carrying a reactive functional group X chosen from the anhydride carboxylic acids and epoxides;
from 5 to 85% of polyolefin C, other than polyethylene A and polyolefin B, carrying a functional group Y capable of reacting with the functional group X.
2. The composition according to claim 1 , wherein the other alpha-olefin of the polyethylene A is chosen from propylene, 1-butene, 1-hexene, 1-octene or 1-decene.
3. The composition according to claim 1 , wherein said composition comprises from 10 to 75% by weight of polyethylene A, with respect to the total weight of the composition.
4. The composition according to claim 1 , wherein the functional group X is a carboxylic acid anhydride functional group.
5. The composition according to claim 1 , wherein the functional group X is an epoxide functional group.
6. The composition according to claim 1 , wherein the polyethylene A comprises a level by weight of ethylene of greater than or equal to 90%.
7. The composition according to claim 1 , wherein the polyethylene A has a density greater than 0.92.
8. The composition according to claim 1 , wherein the functional group X/functional group Y molar ratio is within the range extending from 0.3 to 4.5.
9. The composition according to claim 1 , wherein the polyethylene A and/or the polyolefin B and/or the polyolefin C comprises ethylene.
10. The composition according to claim 9 , wherein the polyolefin B carrying the functional group X is an ethylene-alkyl (meth)acrylate-maleic anhydride copolymer.
11. The composition according to claim 1 , wherein said composition additionally comprises at least one of the additives selected from the group consisting of coupling agents, crosslinking agents, UV absorbents, inorganic fillers, plasticizers, colouring materials, optical brighteners and flame retardants.
12. Photovoltaic module comprising the film composition of claim 1 .
13. Process for the manufacture of a module according to claim 12 , comprising the steps of:
manufacturing the film composition of claim 1 ;
optionally assembling the various constituents of the module with the said manufactured film as encapsulant and/or backsheet;
optionally curing the module tinder pressure.
14. Process according to claim 13 , wherein:
the stage of manufacturing the film is carried out by extrusion at a temperature ranging from 115 to 140° C.;
the curing stage is carried out at a temperature ranging from 140 to 200° C.
15. Use of the module according to claim 12 for producing electricity.
16. The composition according to claim 4 , wherein the functional group X is a maleic anhydride functional group.
17. The composition according to claim 5 , wherein the functional group X is glycidyl methacrylate.
18. The composition according to claim 7 , wherein said polyethylene A has a density of greater than 0.93.
19. The composition according to claim 1 comprising:
from 20 to 55 wt % of a polyethylene A wherein polyethylene A is a homopolymer or copolymer consisting of ethylene monomer units at greater than or equal to 80% by weight and optionally one or more other alpha olefin monomer units selected from the group consisting of propylene, 1-butene, 1-pentene, 3-methyl-1-butene, 1-hexene, 4-methyl-1-pentene, 3-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-hexacosene, 1-octacosene and 1;
from 5 to 60 wt % of a polyolefin B, other than polyethylene A, carrying a reactive functional group X chosen from the anhydride carboxylic acids and epoxides;
from 5 to 60% of polyolefin C, other than polyethylene A and polyolefin B, carrying a functional group Y capable of reacting with the functional group X, wherein said functional group Y is selected from the group consisting of epoxide, carboxylic acid anhydride, and amine.