Pretreatment of biomass with carbonaceous material
View Patent ↗A composition of matter is described herein that can be subjected to pyrolysis and converted into a bio-oil. The composition comprises an intimate mixture of a particulate solid biomass material and a carbonaceous material. The carbonaceous material acts as a reducing agent during the pyrolysis reaction. The composition of matter produces bio-oil in a greater yield than prior art processes. The bio-oil is of improved quality, as evidenced by its low TAN value.
1. A process for converting particulate solid biomass material to a bio-oil, said process comprising the steps of (i) forming a composition of matter comprising an intimate mixture of the solid particulate biomass material and a carbonaceous material; and (ii) subjecting the composition of matter of step (i) to a pyrolysis reaction.
2. The process of claim 1 wherein the pyrolysis reaction is carried out in the presence of at least one catalyst.
3. The process of claim 1 wherein the carbonaceous material acts as a reducing agent during the pyrolysis reaction.
4. The process of claim 1 wherein the carbonaceous material acts as a hydrogen donor during the pyrolysis reaction.
5. A bio-oil produced by the process of claim 1 .
6. The bio-oil of claim 5 having a total acid number (TAN) of less than 30.
7. The bio-oil of claim 5 having a total acid number (TAN) of less than 20.
8. The bio-oil of claim 5 having a total acid number (TAN) of less than 10.
9. The process of claim 1 wherein the carbonaceous material is selected from the group consisting of coal; coke; char; tar; bio-oil; municipal solid waste; synthetic polymers; rubber; hydrocarbons; carbon monoxide; and mixtures thereof.
10. The process of claim 1 wherein the carbonaceous material contains less than 10 wt % of oxygen.
11. The process of claim 1 wherein the forming of step (i) comprises mechanically treating the particulate solid biomass material in the presence of the carbonaceous material, wherein the mechanical treatment is selected from milling, grinding, kneading, comminuting, and combinations thereof.
12. The process of claim 11 wherein the solid particulate biomass material is subjected to a temperature in the range of 30° C. to 300° C. prior to and/or during the mechanical treatment.
13. The process of claim 12 wherein the temperature is in the range of from 90° C. to 200° C.
14. The process of claim 1 further comprising subjecting the solid particulate biomass material to a pretreatment prior to the forming of step (i).
15. The process of claim 2 wherein the catalyst comprises a zeolite.
16. The process of claim 1 wherein the pyrolysis reaction occurs at a temperature in the range of from 350° C. to 650° C.
17. The process of claim 1 wherein the pyrolysis reaction occurs at a temperature in the range of from 400° C. to 550° C.