Spark plug for internal combustion engine
Provided is a spark plug which allows a predetermined resistance to be imparted to a resistor with restraint of variation in resistance of the resistor and in turn, enables enhancement of yield. The spark plug includes a ceramic insulator having an axial hole extending in the direction of an axis CL 1 , a center electrode, and a terminal electrode. A resistor is provided in the axial hole through sintering of a resistor composition which contains a conductive material such as carbon black, glass powder, and ceramic particles other than glass. As viewed on a section of the resistor taken along a direction orthogonal to the axis CL 1 , 50% or more of sintered glass powder formed through sintering of the glass powder has a circularity of 0.8 or greater.
1. A spark plug for an internal combustion engine comprising:
a substantially tubular insulator having an axial hole extending therethrough in a direction of an axis;
a center electrode inserted into one end portion of the axial hole;
a terminal electrode inserted into the other end portion of the axial hole;
a substantially tubular metallic shell provided externally of an outer circumference of the insulator; and
a resistor formed in the axial hole through sintering of a resistor composition containing a conductive material, glass powder, and ceramic particles other than glass, and electrically connecting the center electrode and the terminal electrode;
characterized in that, as viewed on a section of the resistor taken along a direction orthogonal to the axis, 50% or more of sintered glass powder formed through sintering of the glass powder has a circularity of 0.8 or greater.
2. A spark plug for an internal combustion engine according to claim 1 , wherein the sintered glass powder is formed such that 60% or more thereof has a circularity of 0.8 or greater as viewed on the section of the resistor taken along a direction orthogonal to the axis.
3. A spark plug for an internal combustion engine according to claim 1 , wherein the sintered glass powder contains one glass material selected from the group consisting of B 2 O 3 —SiO 2 -based, BaO—B 2 O 3 -based, SiO 2 —B 2 O 3 —BaO-based, and SiO 2 —ZnO—B 2 O 3 -based glass materials.
4. A spark plug for an internal combustion engine comprising:
a substantially tubular insulator having an axial hole extending therethrough in a direction of an axis;
a center electrode inserted into one end portion of the axial hole;
terminal electrode inserted into the other end portion of the axial hole;
a substantially tubular metallic shell provided externally of an outer circumference of the insulator; and
a resistor formed in the axial hole through sintering of a resistor composition containing a conductive material, glass powder, and ceramic particles other than glass, and electrically connecting the center electrode and the terminal electrode;
the resistor containing the conductive material in an amount of 0.5% by mass to 10% by mass inclusive, glass in an amount of 60% by mass to 90% by mass inclusive, and the ceramic particles in an amount of 5% by mass to 30% by mass inclusive; and
the glass powder having an average particle size of 50 μm to 500 μm inclusive;
characterized in that 50% by mass or more of the glass powder contained in the resistor composition is spherical.
5. A spark plug for an internal combustion engine according to claim 4 , wherein the glass powder is formed such that 80% by mass or more thereof is spherical.
6. A spark plug for an internal combustion engine according to claim 4 , wherein the glass powder has an average particle size of 50 μm to 200 μm inclusive.
7. A spark plug for an internal combustion engine according to claim 4 , wherein the glass powder contains one glass material selected from the group consisting of B 2 O 3 —SiO 2 -based, BaO—B 2 O 3 -based, SiO 2 —B 2 O 3 —BaO-based, and SiO 2 —ZnO—B 2 O 3 -based glass materials.
8. A spark plug for an internal combustion engine according to claim 2 , wherein the sintered glass powder contains one glass material selected from the group consisting of B 2 O 3 —SiO 2 -based, BaO—B 2 O 3 -based, SiO 2 —B 2 O 3 —BaO-based, and SiO 2 —ZnO—B 2 O 3 -based glass materials.
9. A spark plug for an internal combustion engine according to claim 5 , wherein the glass powder has an average particle size of 50 μm to 200 μm inclusive.
10. A spark plug for an internal combustion engine according to claim 5 , wherein the glass powder contains one glass material selected from the group consisting of B 2 O 3 —SiO 2 -based, BaO—B 2 O 3 -based, SiO 2 —B 2 O 3 —BaO-based, and SiO 2 —ZnO—B 2 O 3 -based glass materials.
11. A spark plug for an internal combustion engine according to claim 6 , wherein the glass powder contains one glass material selected from the group consisting of B 2 O 3 —SiO 2 -based, BaO—B 2 O 3 -based, SiO 2 —B 2 O 3 —BaO-based, and SiO 2 —ZnO—B 2 O 3 -based glass materials.