Environmental barrier for a refractory substrate containing silicon
View Patent ↗In order to protect a substrate having at least a portion adjacent to a surface that is made of a refractory material containing silicon, while the substrate is in use at high temperature in a medium that is oxidizing and wet, there is formed on the surface of the substrate an environmental barrier that contains no boron and that has at least one layer that is essentially constituted by a system of oxides formed by at least one rare earth oxide, silica, and alumina, and that is capable of self-healing by maintaining the presence of at least one solid phase in a temperature range extending up to at least 1400° C. approximately.
1. A part comprising:
a substrate, the substrate being a ceramic matrix composite material containing silicon, and the substrate having at least a portion that is adjacent to a surface of the substrate that is made of a refractory material containing silicon, and an environmental barrier that does not contain boron formed on the surface of the substrate and capable of protecting the substrate during use at high temperature in a medium that is oxidizing and wet,
wherein the environmental barrier has at least one layer that is constituted essentially by a system of oxides formed by at least one rare earth oxide, silica, and alumina, which system conserves a majority solid phase up to at least 1400° C. approximately and presents a liquid phase at a temperature equal to or greater than 1400° C. approximately, said liquid phase representing in the range 5 mol % to 40 mol % of the total composition of said layer, such that said layer is capable of self-healing while maintaining the presence of at least one solid phase in a temperature range extending up to at least 1400° C., approximately,
and wherein the environmental barrier further includes an underlayer interposed between the surface of the substrate and the self-healing layer, the underlayer being in contact with the substrate and being constituted essentially by silicate of at least one rare earth;
wherein the silicate of at least one rare earth is present in the underlayer in a molar fraction greater than or equal to 70%.
2. A part according to claim 1 , wherein the self-healing layer essentially represents a mixture of rare earth silicate RE 2 Si 2 O 7 , where RE is a rare earth, and of mullite (3Al 2 O 3 .2SiO 2 ).
3. A part according to claim 1 , wherein the self-healing layer essentially represents a mixture of rare earth aluminate RE 4 Al 2 O 9 , where RE is a rare earth, and of silica SiO 2 .
4. A part according to claim 1 , wherein the rare earth is at least one selected from yttrium, scandium, and the lanthanides.
5. A part according claim 1 , wherein the substrate is made of a composite material comprising fiber reinforcement and a matrix, the matrix including at least one phase of silicon carbide SiC adjacent to the surface of the substrate.
6. A part according to claim 1 , wherein the rare earth of the underlayer is identical to the rare earth of the self-healing layer.
7. A part according to claim 1 , wherein the self-healing layer is in contact with the underlayer.
8. A part according to claim 1 , wherein the silicate of at least one rare earth is present in the underlayer in a molar fraction greater than or equal to 90%.