IP Library Granted Patent US 8,618,207
Granted Patent B2
US 8,618,207 · App. 13/141,678 · Granted Dec 31, 2013

Flame retardant polymer composition with improved mechanical properties

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Quick Facts
Patent No.
US 8,618,207
App. No.
13/141,678
Granted
Dec 31, 2013
Kind
B2
Abstract

A flame retardant polymer composition comprising (A) an ethylene copolymer comprising polar comonomer units, (B) a silicone-group containing compound, (C) an inorganic filler material, and (D) an ethylene homopolymer or a copolymer of ethylene with one or more other alpha-olefin comonomer units, wherein the polymer composition has a melting enthalpy of at least 78 J/g, an article, in particular a wire or cable, comprising said composition and the use of an ethylene homo- or copolymer in a flame retardant layer of a wire or cable for improving the mechanical properties of the wire or cable.

Claims (28)

1. A flame retardant polymer composition comprising

(A) an ethylene copolymer comprising polar comonomer units,

(B) a silicone-group containing compound,

(C) an inorganic filler material, and

(D) an ethylene homopolymer or a copolymer of ethylene with one or more other alpha-olefin comonomer units,

wherein the inorganic filler material (C) is present in an amount of 20 to 45 wt % of the total composition, the ethylene homo- or copolymer (D) is present in an amount of 15 wt % or more of the total composition, and has a density of 940 to 960 kg/m 3 , determined according to ISO 1183, and

wherein the polymer composition has a melting enthalpy of at least 78 J/g.

2. Flame retardant polymer composition according to claim 1 , wherein ethylene homo- or copolymer (D) has a MFR (2.16 kg, 190° C) of 0.1 to 15.0 g/10 min, determined according to ISO 1133.

3. Flame retardant polymer composition according to claim 1 , wherein ethylene homo- or copolymer (D) is multimodal.

4. Flame retardant polymer composition according to claim 1 , wherein the amount of ethylene copolymer (A) is less than 50 wt % of the total composition.

5. Flame retardant polymer composition according to claim 1 , wherein the polar comonomer units of ethylene copolymer (A) are selected from a group comprising C 1 -C 6 alkyl acrylates, C 1 -C 6 alkyl methacrylates, acrylic acid, methacrylic acid and vinyl acetate, including ionomers thereof.

6. Flame retardant polymer composition according to claim 1 , wherein component (B) is present in an amount of 1 to 20 wt % of the total composition.

7. Flame retardant polymer composition according to claim 1 , wherein component (B) is a silicone fluid and/or gum, and/or a copolymer of ethylene and at least one comonomer which comprises a silicone group.

8. Flame retardant polymer composition according to claim 1 , wherein inorganic filler material (C) is present in an amount of 22 to 45 wt % of the total composition.

9. Flame retardant polymer composition according to claim 1 , wherein inorganic filler material (C) comprises a carbonate, oxide and/or sulphate of an element of groups 1 to 13 of the Periodic System of the Elements.

10. Flame retardant polymer composition according to claim 1 , wherein the composition further comprises carbon black in an amount of 1 to 5 wt % of the total composition.

11. Flame retardant polymer composition according to claim 1 , wherein the polymer composition has a tear strength of at least 10 N/mm determined according to BS 6469.

12. Flame retardant polymer composition according to claim 1 , wherein the polymer composition has a tensile strength of at least 9 MPa, determined according to ISO 527-2.

13. Flame retardant polymer composition according to claim 1 , wherein the polymer composition has a heat indentation of less than 14.0% in the pressure test according to IEC 60811-3-1.

14. An article comprising the flame retardant polymer composition according to claim 1 .

15. Wire or cable comprising a layer made of the flame retardant polymer composition according to claim 1 .

16. Method for producing a flame retardant layer for a wire or cable, comprising compounding:

(A) an ethylene copolymer comprising polar comonomer units,

(B) a silicone-group containing compound,

(C) an inorganic filler material, and

(D) an ethylene homopolymer or a copolymer of ethylene with one or more other alpha-olefin comonomer units,

to form a polymer composition,

wherein the inorganic filler material (C) is present in an amount of 20 to 45 wt % of the total composition, the ethylene homo- or copolymer (D) is present in an amount of 15 wt % or more of the total composition, and has a density of 940 to 960 kg/m 3 , determined according to ISO 1183, wherein the polymer composition of the flame retardant layer has a melting enthalpy of at least 78 J/g for improving the mechanical properties of the wire and cable.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2011
From: SULTAN, BERNT-AKE; LOYENS, WENDY
To: BOREALIS AG
Reel/Frame 026491/0682 →