Flexible temperature sensor and sensor array
View Patent ↗Techniques described herein generally relate to methods of manufacturing devices and systems including devices including a substrate with a surface, a conductive polymer film arranged on the surface of the substrate, wherein the conductive polymer film has one or more temperature reactive characteristics, and a pair of electrodes coupled to the polymer film, wherein the pair of electrodes are configured to communicate electrical signals to the conductive polymer film effective to measure the one or more temperature reactive characteristics. The conductive polymer film may be arranged on the surface of the substrate such that a thickness and dopant ratio of the conductive polymer film on the substrate is configurable.
1. A device comprising:
a substrate including a surface;
a conductive polymer film arranged on the surface of the substrate, wherein the conductive polymer film has a resistance that changes with temperature, and wherein the conductive polymer has a thickness in a range from about 10 nm to about 150 nm;
a pair of electrodes coupled to the polymer film, wherein the pair of electrodes are configured to communicate electrical signals to the conductive polymer film effective to measure the resistance; and
a meter operatively coupled to the conductive polymer film and configured to measure the resistance of the conductive polymer film
wherein the device is configured as a temperature sensor with a substantially linear temperature sensitivity over a temperature range of about 25° C. to about 80° C.
2. The device of claim 1 , wherein the thickness of the conductive polymer film on the substrate is less than about 80 nm.
3. The device of claim 1 , wherein the conductive polymer of the conductive polymer film is doped with a dopant.
4. The device of claim 3 , wherein a ratio of the conductive polymer to the dopant is in a range of about 0.3 to about 1.
5. The device of claim 1 , wherein the substrate is flexible.
6. The device of claim 1 , wherein the substrate is selected from the group consisting of polyethylene terephthalate (PET) substrate and polyimide substrate.
7. The device of claim 1 , wherein the conductive polymer film comprises a polymer selected from the group consisting of polyaniline, polypyrrole, polythiophene, poly(p-phenylene), poly(p-phenylenevinylene), poly(2,5-thienylenevinylene) and poly(3,4-ethylenedioxythiophene).
8. The device of claim 3 , wherein the dopant is selected from the group consisting of camphor sulfonic acid (CSA) and dodecyl benzene sulfonic acid (DBSA), 2-Acrylamido-2-methylpropane sulfonic acid (AMPSA), hydrochloric acid, sulfuric acid and phosphoric acid.
9. The device of claim 1 , wherein the conductive polymer film is deposited on the substrate using a technique selected from the group consisting of spin coating technique, polymer printing technique, spray coating technique and dip coating technique.
10. The device of claim 1 , wherein the device is configured as a temperature sensor with a tunable sensitivity range of about 3 Ω/° C. to about 130 Ω/° C.
11. A method for manufacturing a device, the method comprising:
providing a substrate;
depositing a conductive polymer film on the substrate, wherein the conductive polymer film has a resistance that changes with temperature and wherein depositing further comprises:
controlling a thickness of the conductive polymer film on the substrate, wherein controlling the thickness comprises configuring the thickness to be in a range from about 10 nm to about 150 nm; and
selecting a ratio of the conductive polymer to a dopant used therewith;
coupling a pair of electrodes to the conductive polymer film, wherein the pair of electrodes are configured to communicate electrical signals to the conductive polymer film; and
operatively coupling a meter to the conductive polymer via the pair of electrodes, wherein the meter is configured to measure the resistance of the conductive polymer film
wherein the device is configured as a temperature sensor with a sensitivity within the range of about 3 Ω/° C. to about 130 Ω/° C.
12. The device manufacturing method of claim 11 , wherein depositing the conductive polymer film on the substrate comprises using a technique selected from the group consisting of spin coating the polymer film on the substrate, printing the polymer film on the substrate, spray coating the polymer film on the substrate, and dip coating the polymer film on the substrate.
13. The device manufacturing method of claim 11 , wherein the substrate is flexible.
14. The device manufacturing method of claim 11 , wherein providing the substrate comprises selecting the substrate from the group consisting of polyethylene terephthalate (PET) substrate and polyimide substrate.
15. The device manufacturing method of claim 11 , wherein depositing the conductive polymer on the substrate further comprises selecting the conductive polymer from the group consisting of polyaniline, polypyrrole, polythiophene, poly(p-phenylene), poly(p-phenylenevinylene), poly(2,5-thienylenevinylene), and poly(3,4-ethylenedioxythiophene).
16. The device manufacturing method of claim 11 , wherein depositing the conductive polymer on the substrate further comprises selecting the dopant from the group consisting of camphor sulfonic acid (CSA) and dodecyl benzene sulfonic acid (DBSA), 2-Acrylamido-2-methylpropane sulfonic acid (AMPSA), hydrochloric acid, sulfuric acid and phosphoric acid.
17. The device manufacturing method of claim 11 , wherein controlling the thickness of the conductive polymer film on the substrate comprises configuring the thickness to be less than about 80 nm.
18. The device manufacturing method of claim 11 , wherein selecting the ratio of the conductive polymer to the dopant comprises selecting the ratio in a range of about 0.3 to about 1.
19. A system comprising:
an object; and
a sensing device arranged to operatively contact the object for sensing a thermal state of the object, the sensing device comprising:
a substrate including a surface;
a conductive polymer film arranged on the surface of the substrate,
wherein the conductive polymer film has a resistance that changes with temperature, and wherein the conductive polymer has a thickness in a range from about 10 nm to about 150 nm;
a pair of electrodes coupled to the polymer film, wherein the pair of electrodes are configured to communicate electrical signals to the conductive polymer film; and
a meter operatively coupled to the conductive polymer film via the pair of electrodes and configured to measure the resistance of the conductive polymer film such that the thermal state of the object is determined
wherein the device is configured as a temperature sensor with a substantially linear temperature sensitivity over a temperature range of about 25° C. to about 80° C., and
wherein the device is configured as a temperature sensor with a sensitivity within the range of about 3 Ω/° C. to about 130 Ω/° C.
20. The system of claim 19 , further comprising a controller operatively coupled to the meter, wherein the controller is configured to receive data from the meter, and adjust a characteristic of the object in accordance with the received data, wherein the received data is related to the measured resistance of the conductive polymer film.
21. The device of claim 1 , wherein the thickness of the conductive polymer film on the substrate is less than about 60 nm.
22. The device of claim 1 , wherein the resistance of the conductive polymer film increases with temperature.
23. The device of claim 10 , where the sensitivity of the device is greater than about 20 Ω/° C.