Liquid photoinitiator blend
View Patent ↗The present invention relates to a homogenous liquid blend comprising a photoinitiator and an alkoxylate surfactant for incorporation into aqueous based and solvent based radiation curable systems. In particular the invention relates to a homogenous liquid blend which is liquid at room temperature comprising at least 30% by weight with regard to the whole blend of a solid photoinitiator of the radical type and 1-70% by weight of at least one alkoxylated liquid surface active agent and optionally an organic diluent.
1. A homogenous liquid blend which is liquid at room temperature comprising:
at least 65% by weight with regard to the whole blend of a solid photoinitiator of the radical type and
1-70% by weight of at least one alkoxylated liquid surface active agent and
optionally an organic diluent.
2. A homogenous liquid blend according to claim 1 wherein the surface active agent is selected from alkoxylated compounds based on adducts with ethylene oxide and/or propylene oxide.
3. A homogenous liquid blend according to claim 1 wherein the surface active agent is selected from alcohol alkoxylates (glycolethers), fatty acid alkoxylates, fatty amine alkoxylates, or fatty amide alkoxylates, alkoxylates of phenols or alkylsubstituted phenols, block copolymers or random copolymers of ethylene oxide and propylene oxide, alkoxylates of alkine-alcohols or alkine-diols, alkoxylates of castor oil, alkoxylates of sorbitan fatty acid esters and mixtures thereof.
4. A homogenous liquid blend according to claim 1 wherein the diluent is present.
5. A homogenous liquid blend according to claim 1 wherein the photoinitiator is selected from benzophenones, aromatic α-hydroxyketones, benzilketals, aromatic α-aminoketones, phenylglyoxalic acid esters, mono-acylphosphinoxides, bis-acylphosphinoxides, tris-acylphosphinoxides and oximesters derived from aromatic ketones.
6. A homogenous liquid blend according to claim 1 wherein the photoinitiator is selected from benzophenone, benzildimethylketal, 1-hydroxy-cyclohexyl-phenyl-ketone, 1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propan-1one, 2-hydroxy-1-{4-[4-(2-hydroxy-2-methyl-propionyl)-benzyl]-phenyl}-2-methyl-propan-1-one, (4-methylthiobenzoyl)-1-methyl-1-morpholinoethane, (4-morpholinobenzoyl)-1-benzyl-1-dimethylaminopropane, (4-morpholinobenzoyl)-1-(4-methylbenzyl)-1-dimethylaminopropane, (2,4,6-trimethylbenzoyl)diphenylphosphine oxide, bis(2,6-dimethoxy-benzoyl)-(2,4,4-trimethyl-pentyl)phosphine oxide, bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide and 2-hydroxy-1-{1-[4-(2-hydroxy-2-methyl-propionyl)-phenyl]-1,3,3-trimethyl-indan-5-yl}-2-methyl-propan-1-one, 1,2-octanedione, 1-[4-(phenylthio)phenyl]-,2-(O-benzyloxime).
7. A homogenous liquid blend according to claim 6 wherein the photoinitiator is selected from 1-hydroxy-cyclohexyl-phenyl-ketone, 2-hydroxy-1-{1-[4-(2-hydroxy-2-methylpropionyl)-phenyl]-1,3,3-trimethyl-indan-5-yl}-2-methyl-propan-1-one, bis(2,6-dimethoxy-benzoyl)-(2,4,4-trimethyl-pentyl)phosphine oxide, bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide, 1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propan-1-one.
8. A process for the preparation of a homogenous liquid blend as defined in claim 1 comprising the steps of
heating at least 65% by weight of a photoinitiator to a temperature above its melting point
adding 1-70% by weight of at least one alkoxylated liquid surface active agent and optionally adding a diluent
cooling to room temperature to obtain a homogeneous liquid blend.
9. A photopolymerisable composition comprising
(A) at least one ethylenically unsaturated photopolymerisable compound and
(B) at least a homogenous liquid blend according to claim 1 .
10. The use of a homogeneous liquid blend according to claim 1 in the production of solvent-free, solvent- and water-based surface coatings, printing inks, screen-printing inks, offset-printing inks, flexographic-printing inks, resist materials or image-recording material.