IP Library Granted Patent US 8,541,507
Granted Patent B2
US 8,541,507 · App. 13/144,522 · Granted Sep 24, 2013

High flow polypropylene composition

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Quick Facts
Patent No.
US 8,541,507
App. No.
13/144,522
Granted
Sep 24, 2013
Kind
B2
Abstract

The present invention relates to a high flow polypropylene composition comprising (A) a low molecular weight propylene homopolymer fraction and (B) a high molecular weight propylene copolymer fraction, having a comonomer content of not higher than 8 wt %, wherein the ratio between the MFR 2 of fraction (A) and the MFR 2 of fraction (B) is at least 3 and wherein the MFR 2 of the entire composition is at least 5 g/10 min, the values of MFR 2 being measured according to ISO 1133 (230° C., 2.16 kg load), and to processes for producing such compositions and to articles made there from.

Claims (26)

1. A polypropylene composition comprising

(A) a low molecular weight propylene homopolymer fraction and

(B) a high molecular weight propylene copolymer fraction, having a comonomer content of not higher than 8 wt%,

wherein the ratio between the MFR 2 of fraction (A) and the MFR 2 of fraction (B) is at least 3; the MFR 2 of fraction (B) is not higher than 15 g/10 min and the MFR 2 of the entire composition is at least 50 g/10 min, the values of MFR 2 being measured according to ISO 1133 (230 ° C., 2.16 kg load).

2. The polypropylene composition according to claim 1 , wherein said MFR 2 ratio is at least 25.

3. The polypropylene composition according to claim 1 , wherein the amount of peroxides or reaction products thereof is lower than 50 ppm.

4. The polypropylene composition according to claim 1 , wherein the MFR 2 of fraction (A) is at least 40 g/10 min.

5. The polypropylene composition according to claim 1 , wherein the comonomer in the copolymer fraction (B) is ethylene or a C4 to C10 alpha-olefin or any combination of these.

6. The polypropylene composition according to claim 5 , wherein the comonomer is ethylene.

7. The polypropylene composition according to claim 5 , wherein the content of comonomer in the composition is between 0.8 and 4.0 wt %.

8. The polypropylene composition according to claim 1 , wherein the tensile modulus measured according to ISO 572-2 is at least 1500 MPa.

9. The polypropylene composition according to claim 1 comprising at least 3.0 wt % of crystal lamellae having a thickness of at least 17.7 nm as measured by stepwise isothermal segregation.

10. A process for preparing a high flow polypropylene composition, comprising the following steps:

(i) preparation of a low molecular weight propylene homopolymer with an MFR 2 of at least 40 g/10 min;

(ii) preparation of a high molecular weight propylene copolymer with an MFR 2 of not more than 15 g/10 min and having a comonomer content of not higher than 8 wt %;

and compounding the polymers to receive the final polypropylene composition having an MFR 2 of at least 50 g/10 min.

11. A process for preparing a high flow polypropylene composition, comprising the following steps in any sequence:

(i) preparation of a low molecular weight propylene homopolymer fraction with an MFR 2 of at least 100 g/10 min;

(ii) preparation of a high molecular weight propylene copolymer fraction with an MFR 2 of not more than 10 g/10 min and having a comonomer content of not higher than 8 wt %;

wherein the fractions are produced in different reactors connected in series and each fraction is produced in the presence of the product produced in the preceding reactor(s) except for the first fraction, resulting in the polypropylene composition having an MFR 2 of at least 50 g/10 min.

12. An article comprising a polypropylene composition according to claim 1 .

13. The polypropylene composition according to claim 1 , wherein the polypropylene composition comprises at least 6.5 wt % of crystal lamellae having a thickness of at least 17.7 nm as measured by stepwise isothermal segregation.

14. The polypropylene composition according to claim 1 , wherein the polypropylene composition comprises at least 7.5 wt % of crystal lamellae having a thickness of at least 17.7 nm as measured by stepwise isothermal segregation.

15. The polypropylene composition according to claim 1 , wherein the polypropylene composition comprises at least 9.5 wt % of crystal lamellae having a thickness of at least 17.7 nm as measured by stepwise isothermal segregation.

16. The polypropylene composition according to claim 1 , wherein the MFR 2 of the entire composition is at least 60 g/10 min.

17. The polypropylene composition according to claim 1 , wherein the MFR 2 of fraction (A) is at least 200 g/10 min.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 4, 2011
From: DOSHEV, PETAR; JAASKELAINEN, PIRJO; KHEIRANDISH, SAEID; LESKINEN, PAULI; JOHNSEN, GEIR KRISTIAN; DING, HAO
To: BOREALIS AG
Reel/Frame 027010/0091 →