IP Library Granted Patent US 10,170,783
Granted Patent B2
US 10,170,783 · App. 13/145,626 · Granted Jan 1, 2019

Manufacture of a fuel cell with liquid electrolyte migration prevention

Inventors: Sridhar V. Kanuri (Milford, CT); Richard D. Breault (North Kingstown, RI); Kishore Kumar Tenneti (Vernon, CT); Ned E. Cipollini (Enfield, CT); Frank E. Kenney, III (Tolland, CT)
Assignee: DOOSAN FUEL CELL AMERICA, INC.
H01M8/086H01M8/0284H01M8/0286H01M8/0228Y02P70/56
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Quick Facts
Patent No.
US 10,170,783
App. No.
13/145,626
Granted
Jan 1, 2019
Kind
B2
Abstract

A stack ( 10 ) of fuel cells ( 11 ) is manufactured with barriers ( 32 ) to prevent migration of a liquid electrolyte (such as phosphoric acid) out of the cells ( 11 ). The barrier ( 32 ) is secured within a step ( 34 ) formed within a land region ( 28 ) of a separator plate assembly ( 18 ) and extends from an edge ( 30 ) of the separator plate assembly ( 18 ) all or a portion of a distance between the edge ( 30 ) and a flow channel ( 24 ) defined within the separator plate assembly ( 18 ). The barrier ( 32 ) also extends away from the edge ( 30 ) a distance of between 0.051 and about 2.0 millimeters (about 2 and about 80 mils. The barrier ( 32 ) includes a hydrophobic, polymeric film ( 36 ), a pressure sensitive adhesive ( 38 ) as an assembly aid, and a fluoroelastomer bonding agent ( 40 ).

Claims (33)

1. A method of manufacturing a stack of liquid electrolyte fuel cells having a barrier configured to prevent migration of the liquid electrolyte between the fuel cells, the method comprising:

securing the barrier configured to prevent migration of the liquid electrolyte between the fuel cells to a land region of a separator plate assembly of at least one of the fuel cells, wherein the land region extends from an edge of the separator plate assembly toward an adjacent flow channel defined within the separator plate assembly;

securing the barrier adjacent the land region so that a first portion of the barrier extends across at least a portion of the land region and a second portion of the barrier extends outwardly and away from the edge of the separator plate assembly, wherein the first portion of the barrier directly contacts the electrode; and

securing the separator plate assembly adjacent an electrode of the at least one of the fuel cells so that the flow channel is adjacent the electrode and the second portion of the barrier extends outwardly and beyond an edge of the electrode that is aligned with the edge of the separator plate assembly.

2. A method according to claim 1 , wherein the barrier comprises a hydrophobic film which extends away from the edge of the separator plate assembly between about 0.051 and about 2.0 millimeters (about 2 and about 80 mils).

3. A method according to claim 1 , wherein the barrier comprises a hydrophobic film which is between about 0.05 mm and 0.127 mm (about 2 mils and about 5 mils) thick.

4. A method according to claim 1 , wherein the barrier comprises a hydrophobic polymer film that is distinct from the material of the separator plate assembly.

5. A method according to claim 4 , wherein said hydrophobic polymer film is selected from polytetrafluroethylene, fluorinated ethylene propylene and polyfluoroaloxy copolymer resin.

6. A method according to claim 1 , comprising

defining a step within the land region of the separator plate assembly; and

securing the first portion of the barrier within the step and wherein the step and the first portion of the barrier extend all of a distance between the edge of the separator plate assembly and the flow channel.

7. A method according to claim 1 , comprising

defining a step within the land region of the separator plate assembly; and

securing the first portion of the barrier within the step and wherein the step and the first portion of the barrier extend only a portion of a distance between the edge of the separator plate assembly and the flow channel.

8. A method according to claim 1 , comprising bonding the barrier to a step formed in the land region.

9. A method according to claim 8 , comprising bonding the barrier to the step with a fluoroelastomer.

10. A method according to claim 9 , wherein the fluoroelastomer has a fluorine content greater than about 68% by weight.

11. A method according to claim 8 , comprising bonding the barrier to the step during the manufacturing process, prior to assembly of fuel cells into the stack.

12. A method according to claim 1 , comprising bonding the first portion of the barrier to a section of the land region in situ within the stack during initial heating up of the stack.

13. A method according to claim 1 , wherein the barrier comprises a hydrophobic polymer film coated with pressure sensitive adhesive on a surface of the polymer film.

14. A method according to claim 13 , wherein the pressure sensitive adhesive is selected from an acrylic adhesive and a silicone adhesive.

15. A method according to claim 1 , comprising securing a second barrier to a second land region of the separator plate assembly, the second barrier extending from a second edge of the assembly all or a portion of a distance between the second edge and a second flow channel, said second barrier configured to extend away from the second edge of the separator plate assembly in a direction away from the second flow channel.

16. A method according to claim 1 , comprising securing a barrier of hydrophobic polymer film to the land region while compressing the hydrophobic polymer film toward the adjacent land region.

17. A method according to claim 16 , comprising compressing the hydrophobic polymer film toward the adjacent land region by an axial force of at least 345 kPa (50 psi).

18. A method according to claim 1 , wherein the land region includes a step having a depth that is about equal to a thickness of the barrier.

19. A method according to claim 18 , wherein the depth is between about 80% and about 120% of the thickness of the barrier.

20. A method according to claim 1 , comprising aligning the edge of the electrode and the edge of the separator plate assembly to be coplanar.

21. A method of making a stack of liquid electrolyte fuel cells having a barrier configured to prevent migration of the liquid electrolyte between the fuel cells, the method comprising:

situating a plurality of fuel cells adjacent each other, the fuel cells respectively having electrodes;

situating a separator plate between one of the electrodes of one of the fuel cells and an adjacent one of the electrodes of an adjacent one of the fuel cells, the separator plate having outside edges aligned with outside edges of the electrodes; and

securing the barrier configured to prevent migration of the liquid electrolyte between the fuel cells to a land region of the separator plate, the barrier comprising at least one piece of material that is distinct from the material of the separator plate assembly, the barrier having a first portion that extends across at least a portion of the land region and a second portion that extends outwardly beyond and away from the edge of the separator plate, wherein the first portion of the barrier directly contacts at least the portion of the land region and the one of the electrodes of the one of the fuel cells.

22. The method of claim 21 , wherein the first portion of the barrier is received against at least the portion of the land region and the one of the electrodes of the one of the fuel cells.

23. The method of claim 1 , wherein the first portion of the barrier is received against the electrode.

Assignments (6)
CORRECTIVE ASSIGNMENT TO CORRECT THE THE ASSIGNEE ADDRESS PREVIOUSLY RECORDED AT REEL: 059364 FRAME: 0046. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 13, 2022
From: DOOSAN FUEL CELL AMERICA, INC.
To: HYAXIOM, INC.
Reel/Frame 060062/0957 →
CHANGE OF NAME Recorded Mar 14, 2022
From: DOOSAN FUEL CELL AMERICA, INC.
To: HYAXIOM, INC.
Reel/Frame 059364/0046 →
CERTIFICATE OF CONVERSION Recorded Aug 16, 2016
From: CLEAREDGE POWER CORPORATION
To: CLEAREDGE POWER, LLC
Reel/Frame 039696/0953 →
CHANGE OF NAME Recorded Aug 16, 2016
From: UTC POWER CORPORATION
To: CLEAREDGE POWER CORPORATION
Reel/Frame 039696/0973 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 4, 2016
From: KANURI, SRIDHAR V.; BREAULT, RICHARD D.; TENNETI, KISHORE KUMAR; CIPOLLINI, NED E.; KENNEY, FRANK E., III
To: UTC POWER CORPORATION
Reel/Frame 039338/0987 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2014
From: CLEAREDGE POWER, INC., CLEAREDGE POWER, LLC, CLEAREDGE POWER INTERNATIONAL SERVICE, LLC
To: DOOSAN FUEL CELL AMERICA, INC.
Reel/Frame 033472/0094 →
Continuity (2)
Provisional Application 61214130 · Apr 20, 2009
Related Publication 20120028172A1 · Feb 2, 2012